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CONSTRUCTION OF COMPREHENSIVE REACTION MODEL FOR PREDICTION OF HYDROGEN EXPLOSION AND ESTABLISHMENT OF EXPERIMENTAL TECHNIQUE FOR HIGH-PRESSURE CHEMICAL KINETICS

Research Project

Project/Area Number 24510232
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Social systems engineering/Safety system
Research InstitutionSophia University

Principal Investigator

TAKAHASHI Kazuo  上智大学, 理工学部, 准教授 (10241019)

Co-Investigator(Kenkyū-buntansha) KUZE Nobuhiko  上智大学, 理工学部, 准教授 (80286757)
MURAKAMI Yoshinori  長岡工業高等専門学校, 物質工学科, 教授 (70293256)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2012: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords水素爆発 / 酸水素反応モデル / 高圧衝撃波管 / 急速圧縮機 / 高圧着火特性 / 着火誘導期 / 水素 / 炭化水素 / 水素着火 / 酸水素モデル / メタン / エタン
Outline of Final Research Achievements

To construct the comprehensive reaction model that can predict hydrogen explosion and ignition, ignition induction periods were measured in a high-pressure shock tube and a rapid compression machine. Based on these experimental data, the reaction model for the hydrogen explosion and ignition was optimized in the wide pressure and temperature ranges. The additive effects of hydrocarbons, such as methane and ethane, on hydrogen ignition were investigated in the shock tube. These hydrocarbons inhibited the hydrogen ignition, because they captured the hydrogen atoms that were important chain carriers in the hydrogen oxidation reactions.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (27 results)

All 2015 2014 2013 2012 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (24 results) (of which Invited: 1 results)

  • [Journal Article] Molecular Structure and Internal Rotation of CF3 Group of Methyl Trifluoroacetate: Gas Electron Diffraction, Microwave Spectroscopy, and Quantum Chemical Calculation Studies2015

    • Author(s)
      Nobuhiko Kuze, Atsushi Ishikawa, Maho Kono, Takayuki Kobayashi, Noriyuki Fuchisawa, Takemasa Tsuji, Hiroshi Takeuchi
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 119 Issue: 9 Pages: 1774-1786

    • DOI

      10.1021/jp508447b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Microwave spectroscopy of AgCCH and AuCCH in the X 1Sigma+ states2013

    • Author(s)
      T. Okabayashi, H. Kubota, M. Araki, N. Kuze
    • Journal Title

      Chem. Phys. Lett.

      Volume: 577 Pages: 11-15

    • DOI

      10.1016/j.cplett.2013.05.027

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Radio Search forH2CCC toward HD 183143 as aCandidate for a Diffuse Interstellar BandCarrier2012

    • Author(s)
      Mitsunori Araki, Shuro Takano,Hiromichi Yamabe, Koichi Tsukiyama,and Nobuhiko Kuze
    • Journal Title

      Astrophysical Journal Letters

      Volume: 753:L11 Issue: 1 Pages: 1-3

    • DOI

      10.1088/2041-8205/753/1/l11

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] フランおよびフラン誘導体と酸素原子との高温反応2015

    • Author(s)
      長島広貴, 吉澤春香, 山田将大, 高橋和夫
    • Organizer
      平成26年度衝撃波シンポジウム
    • Place of Presentation
      伊香保温泉ホテル天坊 (渋川)
    • Year and Date
      2015-03-09 – 2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] ガソリンサロゲート燃料の高圧着火特性評価2014

    • Author(s)
      穂谷野恵三, 高橋和夫
    • Organizer
      第52回燃焼シンポジウム
    • Place of Presentation
      岡山コンベンションセンター (岡山)
    • Year and Date
      2014-12-03 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 大気圧高温反応流通管-レーザー光イオン化TOFMASを用いたPAH生成経路の探究2014

    • Author(s)
      山田将大, 高橋和夫
    • Organizer
      第52回燃焼シンポジウム
    • Place of Presentation
      岡山コンベンションセンター (岡山)
    • Year and Date
      2014-12-03 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] DETECTABILITY OF PROLATE SYMMETRIC-TOP MOLECULES IN DIFFUSE CLOUDS BY A “HOT-AXIS EFFECT”2014

    • Author(s)
      Mitsunori Araki, Shuro Takano, Nobuhiko Kuze, Takahiro Oyama, Koichi Tsukiyama
    • Organizer
      Workshop on Interstellar Matter
    • Place of Presentation
      Hokkaido University (Sapporo)
    • Year and Date
      2014-10-16 – 2014-10-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] トリメチル酢酸メチルのtert-ブチル基大振幅振動における分子構造への影響2014

    • Author(s)
      石川敦士, 久世信彦, 國井清美, 辻武正, 竹内浩, 小中重弘
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学東広島キャンパス (広島)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高圧衝撃波管着火実験のための計算モデルの検討

    • Author(s)
      高橋和夫 他
    • Organizer
      第51回燃焼シンポジウム
    • Place of Presentation
      大田区産業プラザ(東京)
    • Related Report
      2013 Research-status Report
  • [Presentation] PM形成メカニズムに及ぼす芳香族炭化水素のアルキル側鎖の影響

    • Author(s)
      高橋和夫 他
    • Organizer
      第51回燃焼シンポジウム
    • Place of Presentation
      大田区産業プラザ(東京)
    • Related Report
      2013 Research-status Report
  • [Presentation] 軽油・ガソリンサロゲート燃料の予混合着火に及ぼすETBEの混合効果

    • Author(s)
      高橋和夫 他
    • Organizer
      平成25年度衝撃波シンポジウム
    • Place of Presentation
      青山学院大学(相模原)
    • Related Report
      2013 Research-status Report
  • [Presentation] フラン及びチオフェンと酸素原子との高温反応

    • Author(s)
      高橋和夫 他
    • Organizer
      平成25年度衝撃波シンポジウム
    • Place of Presentation
      青山学院大学(相模原)
    • Related Report
      2013 Research-status Report
  • [Presentation] トリフルオロ酢酸メチルのCF3基大振幅振動における分子振動の非調和性の影響

    • Author(s)
      久世信彦 他
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都府民総合交流プラザ(京都)
    • Related Report
      2013 Research-status Report
  • [Presentation] THREE TOPICS IN GAS-PHASE STRUCTURES OF MALTOL, DIACETYLENE AND ETHYLENE: GAS ELECTRON DIFFRACTION, IR AND MD STUDIES

    • Author(s)
      Nobuhiko Kuze et al.
    • Organizer
      25th Austin Symposium on Molecular Structure and Dynamics @ Dallas
    • Place of Presentation
      Dallas (USA)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] MOLECULAR STRUCTURES OF METHYL TRIMETHYLACETATE AND METHYL TRIFLUOROACETATE BY GAS-PHASE ELECTRON DIFFRACTION AND QUANTUM CHEMICAL CALCULATION

    • Author(s)
      Nobuhiko Kuze et al.
    • Organizer
      25th Austin Symposium on Molecular Structure and Dynamics @ Dallas
    • Place of Presentation
      Dallas (USA)
    • Related Report
      2013 Research-status Report
  • [Presentation] LARGE-AMPLITUDE MOTIONS FOR METHYL TRIFLUOROACETATE AND 2, 5-DIMETHYLFURAN BY GED, MW AND QUANTUM CHEMICAL CALCULATION

    • Author(s)
      Nobuhiko Kuze et al.
    • Organizer
      15th European Symposium on Gas Electron Diffraction
    • Place of Presentation
      Frauenchiemsee (Germany)
    • Related Report
      2013 Research-status Report
  • [Presentation] 高圧衝撃波管による酸水素の着火特性評価

    • Author(s)
      高橋和夫 他
    • Organizer
      平成24年度衝撃波シンポジウム
    • Place of Presentation
      北九州国際会議場(北九州)
    • Related Report
      2012 Research-status Report
  • [Presentation] 衝撃波管を用いたヘプタン/ETBE混合燃料に関する化学反応モデルの検討

    • Author(s)
      高橋和夫 他
    • Organizer
      平成24年度衝撃波シンポジウム
    • Place of Presentation
      北九州国際会議場(北九州)
    • Related Report
      2012 Research-status Report
  • [Presentation] プロピルベンゼンおよびトリメチルベンゼンと酸素原子との高温反応

    • Author(s)
      高橋和夫 他
    • Organizer
      平成24年度衝撃波シンポジウム
    • Place of Presentation
      北九州国際会議場(北九州)
    • Related Report
      2012 Research-status Report
  • [Presentation] ヘプタン/ETBE混合燃料の高圧着火特性

    • Author(s)
      高橋和夫 他
    • Organizer
      第50回燃焼シンポジウム
    • Place of Presentation
      愛知県産業労働センター(名古屋)
    • Related Report
      2012 Research-status Report
  • [Presentation] 貨幣金属モノアセチリド(AgCCH, AuCCH)のマイクロ波分光

    • Author(s)
      久世信彦 他
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] 直線炭素鎖アルコールHC4OHのマイクロ波分光

    • Author(s)
      久世信彦 他
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] 熱励起直線三原子分子の軟X 線内殻光電子分光

    • Author(s)
      久世信彦 他
    • Organizer
      第12回分子分光研究会
    • Place of Presentation
      上智大学(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] 貨幣金属モノアセチリド(AgCCH, AuCCH)のFTMW分光

    • Author(s)
      久世信彦 他
    • Organizer
      第12回分子分光研究会
    • Place of Presentation
      上智大学(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] HD183143におけるDiffuse Interstellar Bands候補H2CCCの電波観測による検証

    • Author(s)
      久世信彦 他
    • Organizer
      第12回分子分光研究会
    • Place of Presentation
      上智大学(東京)
    • Related Report
      2012 Research-status Report
  • [Presentation] RADIO SEARCH FOR H2CCC TOWARD HD 183143 AS A CANDIDATE FOR A DIUSE INTERSTELLAR BAND CARRIER

    • Author(s)
      Nobuhiko Kuze et al.
    • Organizer
      The 22nd International Conference on High Resolution Molecular Spectroscopy
    • Place of Presentation
      Praha (Czech Republic)
    • Related Report
      2012 Research-status Report
  • [Presentation] MICROWAVE SPECTRA OF THE LINEAR CARBON-CHAIN ALCOHOL HC4OH

    • Author(s)
      Nobuhiko Kuze et al.
    • Organizer
      The 22nd International Conference on High Resolution Molecular Spectroscopy
    • Place of Presentation
      Praha (Czech Republic)
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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