Synthesis of new intermediate by reductive umpolung reaction using metallic strontium
| Project/Area Number |
24550056
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | The University of Tokushima |
|---|
Principal Investigator |
MIYOSHI Norikazu 徳島大学, 大学院ソシオ・アーツ・アンド・サイエンス研究部, 教授 (40219829)
|
|---|
| Project Period (FY) |
2012-04-01 – 2015-03-31
|
| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
|---|
| Keywords | ストロンチウム / メタラサクル / 極性転換 / アゾベンゼン / 二酸化炭素固定 / 還元的極性変換 / メタラサイクル中間体 / アルキル化反応 / シリルエーテル / Grignard試薬 / シリルクロリド / 合成有機化学 / メタラサイクル |
|---|
| Outline of Final Research Achievements |
1,4-Diphenyl-1,3-butadiene reacted with metallic strontium to afford metalocycle intermediate, followed by reaction under carbon dioxide to obtain the dicarboxylate adducts in good yield. The reaction of azobenzene with metallic strontium proceeded smoothly to give new metalocyclic intermediate, which reacted with alkyl halides to afford the dialkylated diphenylhydrazines in good yields.
|
Report
(4 results)
Research Products
(19 results)
