Syntheses of functional molecules through direc arylation by photoactive metal catalysts
| Project/Area Number |
24550071
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
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| Keywords | 有機金属触媒 / 光化学 / 可視光増感 / 分子変換 / 光励起状態 / 光増感性錯体 / パラジウム / 触媒的光反応 / 触媒反応 |
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| Outline of Final Research Achievements |
In order to investigate various molecular transformations by visible light, we focused on synthesizing photoactive complexes composed of visible-light sensitizer and a reactive metal center linked by a bridging ligand. We focused on applying the photocatalysis to cross-coupling reactions and polymerization. The photoactive catalysts such as Ru(II)-polypyridyl-Pd monoacetato and -Pd monomethyl complexes were developed and applyed to cross-coupling reaction of cinnamyl alcohol with arenes and styrene polymerization, respectively. We studied the plausible reaction mechanism together with the basic photochemical properties of the photosensitizers and the photocatalysts.
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Report
(4 results)
Research Products
(45 results)
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[Journal Article] Synthesis of (imido)vanadium(V) complexes containing 8-(2,6-dimethylanilide)-5,6,7-trihydroquinoline ligands: Highly active catalyst precursors for ethylene dimerization2014
Author(s)
X.-Y. Tang, A. Igarashi, W.-H. Sun, A. Inagaki, J. Liu, W. Zhang, Y.-S. Li, and K. Nomura
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Journal Title
Organometallics
Volume: 33
Issue: 4
Pages: 1053-1060
DOI
Related Report
Peer Reviewed
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[Journal Article] Manganese(II) Semiquinonato and Manganese(III) Catecholato Complexes with Tridentate Ligand: Modeling the Substrate-Binding State of Manganese-Dependent Catechol Dioxygenase and Reactivity with Molecular Oxygen2013
Author(s)
Komatsuzaki, Hidehito; Shiota, Akihiko; Hazawa, Shogo; Itoh, Muneaki; Miyamura, Noriko; Miki, Nahomi; Takano, Yoichi; Nakazawa, Jun; Inagaki, Akiko; Akita, Munetaka; Hikichi, Shiro
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Journal Title
Chemistry- An Asian Journal
Volume: 8
Issue: 6
Pages: 1115-1119
DOI
Related Report
Peer Reviewed
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