Synthesis and Reactivity of Diruthenium Complexes Containing a Bridging Tin Ligand
| Project/Area Number |
24550083
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
TAKEMOTO Shin 大阪府立大学, 理学(系)研究科(研究院), 准教授 (20347511)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | スタンニレン錯体 / スタンニリン錯体 / ルテニウム錯体 / スズ配位子 / 異種金属錯体 / Ru-Sn触媒 / スタンニレン / スタンニリン / 多核錯体 / RuSn合金 / 高周期元素化合物 / 低配位化合物 / スタニレン（スタンニレン） / スタニリン（スタンニリン） / 合金触媒 / 高周期元素 |
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| Outline of Final Research Achievements |
Bimetallic complexes containing ruthenium and tin are of great scientific interest because of their potential application as new homogeneous catalysts and as molecular models of industrially important heterogeneous Ru-Sn catalysts. In this research, a novel method for the introduction of a stannylene unit (SnX2) into a coordinatively unsaturated diruthenium has been developed and used to synthesize a series of diruthenium complexes containing a bimetallic Ru2Sn core structure. Catalytic activity as well as some interesting stoichiometric reactivity of the resulting Ru2Sn complexes have been revealed.
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Report
(4 results)
Research Products
(7 results)
