• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Synthesis and Reactivity of Diruthenium Complexes Containing a Bridging Tin Ligand

Research Project

Project/Area Number 24550083
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionOsaka Prefecture University

Principal Investigator

TAKEMOTO Shin  大阪府立大学, 理学(系)研究科(研究院), 准教授 (20347511)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsスタンニレン錯体 / スタンニリン錯体 / ルテニウム錯体 / スズ配位子 / 異種金属錯体 / Ru-Sn触媒 / スタンニレン / スタンニリン / 多核錯体 / RuSn合金 / 高周期元素化合物 / 低配位化合物 / スタニレン(スタンニレン) / スタニリン(スタンニリン) / 合金触媒 / 高周期元素
Outline of Final Research Achievements

Bimetallic complexes containing ruthenium and tin are of great scientific interest because of their potential application as new homogeneous catalysts and as molecular models of industrially important heterogeneous Ru-Sn catalysts. In this research, a novel method for the introduction of a stannylene unit (SnX2) into a coordinatively unsaturated diruthenium has been developed and used to synthesize a series of diruthenium complexes containing a bimetallic Ru2Sn core structure. Catalytic activity as well as some interesting stoichiometric reactivity of the resulting Ru2Sn complexes have been revealed.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (7 results)

All 2014 2013 2012

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (6 results)

  • [Journal Article] Synthesis and N-H Reductive Elimination Study of Dinuclear Ruthenium Imido Dihydride Complexes2012

    • Author(s)
      Takemoto, S; Yamazaki, Y.; Yamano, T.; Mashima, D.; Matsuzaka, H.
    • Journal Title

      Journal of the American Chemical Society

      Volume: 134 Issue: 41 Pages: 17027-17035

    • DOI

      10.1021/ja3005682

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 架橋プルンビレン配位子を有する二核ルテニウム錯体の合成と反応性2014

    • Author(s)
      山野高広・竹本真・松坂裕之
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 二核ルテニウムスタニリン錯体の合成とSn-Sn結合形成反応2013

    • Author(s)
      山野高広・吉井要・竹本真・松坂裕之
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 2核Ruイミド・スタニレン錯体の合成と反応性および触媒作用2013

    • Author(s)
      山野高広・吉井要・山崎祐亮・西森里絵・竹本真・松坂裕之
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ジクロロスタニレンおよびクロロスタニリン配位子を有する2核Ru錯体の合成と反応性2013

    • Author(s)
      山野高広、竹本真、松坂裕之
    • Organizer
      日本化学会 第93春季年会
    • Place of Presentation
      立命館大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 低配位スズ中心を有するRu2Sn多核錯体の合成と性質2012

    • Author(s)
      竹本真、吉井要、山野高広、柴田恵里、松坂裕之
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山大学
    • Related Report
      2012 Research-status Report
  • [Presentation] Ru2Sn多核錯体における配位子置換および脱離反応2012

    • Author(s)
      吉井要、山野高広、竹本真、松坂裕之
    • Organizer
      第59回有機金属化学討論会
    • Place of Presentation
      大阪大学
    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi