• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Reaction mechanism of halogen-free epoxy reaction by use of environment-friendly powder reaction

Research Project

Project/Area Number 24550175
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental chemistry
Research InstitutionOsaka University

Principal Investigator

Ichihara Junko  大阪大学, 産業科学研究所, 助教 (60110772)

Co-Investigator(Kenkyū-buntansha) YAMAGUCHI Shunro  大阪大学, 産業科学研究所, 助教 (40167698)
SAKAMOTO Kiyoko  大阪産業大学, 教養部, 教授 (50268249)
Project Period (FY) 2012-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsハロゲンフリー / エポキシ化 / 過酸化水素 / ポリ酸触媒 / アパタイト / 環境調和型反応 / 粉体系反応
Outline of Final Research Achievements

We have developed a green powder-phase epoxidation reaction (Nonhalite method) to synthesize halogen-free epoxy compounds efficiently. The reaction is performed with the powder state comprising of a polyacid catalyst dispersed on apatite powder, and the added liquid reactants, an organic compound and aqueous hydrogen peroxide. The method is an innovative technology using the surface of apatite powder as the special reaction media, and the reaction depends on the properties and forms of apatite powder.
We synthesized some series of apatite which are changed by a parameter of the physical chemical properties and the forms, and investigated the influence of them on the epoxidation. We have found that for chemical compositions carbonated apatite and fluorinated apatite are more suitable for the powder state epoxidation than hydroxyapatite and that the crystallinity of apatite is more important than the forms of apatite powder such as particle size and particle size distribution.

Report

(5 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (28 results)

All 2016 2015 2014 2013 2012

All Journal Article (6 results) (of which Peer Reviewed: 4 results) Presentation (6 results) Patent(Industrial Property Rights) (16 results) (of which Overseas: 14 results)

  • [Journal Article] DABCO- and DBU-intercalated a-zirconium phosphate as latent thermal catalysts in the copolymerization of glycidyl phenyl ether (GPE) and hexahydro-4-methylphthalic anhydride (MHHPA)2016

    • Author(s)
      Shimomura, Osamu; Nishisako, Takatoshi; Yamaguchi, Shunro; Ichihara, Junko; Kirino, Manabu; Ohtaka, Atsushi; Nomura, Ryoki
    • Journal Title

      Journal of Molecular Catalysis A: Chemical

      Volume: 411 Pages: 230-238

    • DOI

      10.1016/j.molcata.2015.10.035

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Decarboxylation and simultaneous reduction of silver(I) ss-ketocarboxylates with three types of coordination2015

    • Author(s)
      Hatamura, Mariko; Yamaguchi, Shunro; Takane, Shin-ya; Chen, Yu; Suganuma, Katsuaki
    • Journal Title

      Dalton Transactions

      Volume: 2015 Issue: 19 Pages: 8993-9003

    • DOI

      10.1039/c5dt00773a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Alkylamines-intercalated α-zirconium phosphate as latent thermal anionic initiators2014

    • Author(s)
      Shimomura, Osamu; Maeno, Keisuke; Ohtaka, Atsushi; Yamaguchi, Shunro; Ichihara, Junko; Sakamoto, Kiyoko; Nomura, Ryoki
    • Journal Title

      Journal of Polymer Science, Part A: Polymer Chemistry

      Volume: 52 Issue: 13 Pages: 1854-1861

    • DOI

      10.1002/pola.27191

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] ノンハライトシステムによるハロゲンフリーエポキシ樹脂原料の製造2014

    • Author(s)
      市原潤子
    • Journal Title

      プラスチックス

      Volume: 2014 Pages: 62-65

    • Related Report
      2013 Research-status Report
  • [Journal Article] Bone cements based on ground β-tricalcium phosphate with sufficient compressive strengths and short hardening time2013

    • Author(s)
      Kiyoko SAKAMOTO, Takuya NOMOTO,* Shunro YAMAGUCHI,* Ichiro FUJIHARA, Katsuhiko SATOH, Junko ICHIHARA,* Takayoshi KIMURA** and Yoshiaki TSUNAWAKI***
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 121 Issue: 1416 Pages: 714-722

    • DOI

      10.2109/jcersj2.121.714

    • NAID

      130004480169

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] ハロゲンフリー高純度エポキシ化合物の量産技術2013

    • Author(s)
      柿木 里美、市原 潤子
    • Journal Title

      化学装置

      Volume: 55 Pages: 37-40

    • Related Report
      2013 Research-status Report
  • [Presentation] DBU-intercalated α-zirconium phosphate as a latent thermal catalyst for reaction of hexamethylene diisocyanate and phenol2016

    • Author(s)
      SHIMOMURA, Osamu; ○KUSU, Hideki; BABA, Kazuma; YAMAGUCHI, Shunro; ICHIHARA, Junko; OHTAKA, Atsushi; NOMURA, Ryoki
    • Organizer
      日本化学会第96春期年会2016
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] イミダゾール類をインターカレートしたαリン酸ジルコニウムを熱潜在性触媒として用いるエポキシ樹脂の反応挙動2015

    • Author(s)
      下村修, 時實健祐, 西迫孝俊, 山口俊郎, 市原潤子, 大高敦, 野村良紀
    • Organizer
      第53回日本接着学会年次大会
    • Place of Presentation
      愛知工業大学
    • Year and Date
      2015-06-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] ベンジルアミン誘導体をインターカレートしたリン酸ジルコ ニウムの熱潜在性触媒としての応用2015

    • Author(s)
      下村 修○西迫孝 俊・山口俊郎・市原潤子・大高 敦・野村良紀
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日本大学 理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 3級アミン類をインターカレートしたリン酸ジルコニウムを熱潜在性触媒として用いるエポキシ樹脂の硬化反応2014

    • Author(s)
      下村 修1,西迫 孝俊1,山口 俊郎2,市原潤子2,大高 敦1,野村 良紀1
    • Organizer
      第24回無機リン化学討論会
    • Place of Presentation
      高知会館(高知県高知市)
    • Year and Date
      2014-09-24 – 2014-09-25
    • Related Report
      2014 Research-status Report
  • [Presentation] DABCO- and DBU-intercalated a-zirconium phosphates as latent thermal catalysts2014

    • Author(s)
      Shimomura, Osamu; Nishisako, Takatoshi; Maeno, Keisuke; Ohtaka, Atsushi; Yamaguchi, Shunro; Ichihara, Junko; Nomura, Ryoki
    • Organizer
      248th ACS National Meeting & Exposition
    • Place of Presentation
      San Francisco, CA, United States
    • Year and Date
      2014-08-10 – 2014-08-14
    • Related Report
      2014 Research-status Report
  • [Presentation] β 型リン酸三カルシウムを主成分とする骨セメントの硬化反応2013

    • Author(s)
      坂本 清子 1,山口 俊郎 2,藤原 一朗 1,佐藤 克彦 1,市原 潤子 2,木村 隆良
    • Organizer
      第23回無機リン化学討論会
    • Place of Presentation
      島根 松江テルサ
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 固相系酸化反応法を用いた有機化合物の製造方法並びにその装置2015

    • Inventor(s)
      市原潤子、山口俊郎ほか
    • Industrial Property Rights Holder
      大阪大学・大川原製作所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-508592
    • Filing Date
      2015-08-05
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] Method for producing epoxy compound2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al
    • Industrial Property Rights Holder
      Osaka Univ/JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-20
    • Acquisition Date
      2015-11-17
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing alicyclic diepoxy compound2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al
    • Industrial Property Rights Holder
      Osaka Univ/JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-20
    • Acquisition Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing epoxy compound2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al
    • Industrial Property Rights Holder
      Osaka Univ/JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-20
    • Acquisition Date
      2016-02-23
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] Process for producing organic compound with solid-phase oxidation method and its apparatus2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al.
    • Industrial Property Rights Holder
      Osaka Univ/ Okawara
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-10-12
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing epoxy compound2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al.
    • Industrial Property Rights Holder
      Osaka Univ /JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-20
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing epoxy compound2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al.
    • Industrial Property Rights Holder
      Osaka Univ /JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-20
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing epoxy compound2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al.
    • Industrial Property Rights Holder
      Osaka Univ /JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-20
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing alicyclic diepoxy compound2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al.
    • Industrial Property Rights Holder
      Osaka Univ /JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-20
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 固体触媒を用いたエポキシ化合物の製造方法2014

    • Inventor(s)
      Ichihara, J; Yamaguchi, S et al.
    • Industrial Property Rights Holder
      Osaka Univ /JX NOEC
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-17
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing epoxy compound2013

    • Inventor(s)
      Ichihara,J.; Yamaguchi,S. et al.
    • Industrial Property Rights Holder
      大阪大学・JX日鉱日石エネルギー
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-26
    • Related Report
      2013 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Manufacture of epoxides in the presence of solid carriers, solid catalysts, and organic solvents2013

    • Inventor(s)
      Ichihara,J.; Yamaguchi,S. et al.
    • Industrial Property Rights Holder
      大阪大学・JX日鉱日石エネルギー
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-26
    • Related Report
      2013 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Manufacture of alicyclic diepoxides by epoxidizing alicyclic olefins in the presence of solid carriers and solid catalysts2013

    • Inventor(s)
      Ichihara,J.; Yamaguchi,S. et al.
    • Industrial Property Rights Holder
      大阪大学・JX日鉱日石エネルギー
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-26
    • Related Report
      2013 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Method for producing epoxy compound2013

    • Inventor(s)
      Ichihara,J.; Yamaguchi,S. et al.
    • Industrial Property Rights Holder
      大阪大学・JX日鉱日石エネルギー
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-26
    • Related Report
      2013 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] Preparation of alicyclic N-oxyl compounds by oxidizing alicyclic secondary amines in hydrotalcite2013

    • Inventor(s)
      Ichihara, Junko
    • Industrial Property Rights Holder
      大阪大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-06-27
    • Related Report
      2013 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 脂環式N-オキシル化合物の製造方法2012

    • Inventor(s)
      市原潤子
    • Industrial Property Rights Holder
      国立大学法人大阪大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2012-148302
    • Filing Date
      2012-07-02
    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi