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Functional control by formation control of organic nanocrystals and device development

Research Project

Project/Area Number 24550204
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional materials/Devices
Research InstitutionHokkaido University

Principal Investigator

HASEGAWA Hiroyuki  北海道大学, 理学(系)研究科(研究院), 特任助教 (10399537)

Co-Investigator(Kenkyū-buntansha) MATSUDA Masaki  熊本大学, 大学院自然科学研究科, 准教授 (80376649)
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsナノ電解法 / 電解結晶成長法 / 有機導電体 / ナノ単結晶 / ナノワイヤ / 電解結晶成長
Outline of Final Research Achievements

In this research, we tried to find novel functions and to fabricate devices using our original method, the nanoscale electrocrystallization, and materials. In a case of electronic devices, we succeeded to fabricate organic nanocrystal based novel field-effect transistors using various materials. We also observed unusual characteristics whose mechanism have to be clarified continuously. In another case of magnetic devices, we first observed negative giant magnetoresistance in a nanocrystal. In the other case of photonics devices, we found a phenomenon of a crystal growth of a charge transfer complex by photoirradiation only. Our results will lead to a eco-friendly nanodevice fabrication in the future.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (29 results)

All 2015 2014 2013 2012 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 3 results,  Open Access: 3 results) Presentation (20 results) (of which Invited: 2 results)

  • [Journal Article] Crystal structure of bis(tetraphenyl- phosphonium) bis(cyanido-jC)- (29H,31H-tetrabenzo[b,g,l,q]porphinato- j4N29,N30,N31,N32)ferrate(II) acetone disolvate2015

    • Author(s)
      Miki Nishi, Masaki Matsuda, Norihisa Hoshino, Tomoyuki Akutagawa
    • Journal Title

      Acta Crystallographica

      Volume: E71 Issue: 2 Pages: m48-m49

    • DOI

      10.1107/s2056989015001735

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Comparison of Structural and Electrical Characteristics between Tetrabenzoporphyrin- and Phthalocyanine-Based Charge Transfer Complexes2015

    • Author(s)
      Miki, Nishi, Masaki, Matsuda, Norihisa, Hoshino, Tomoyuki Akutagawa
    • Journal Title

      Chem. Lett.

      Volume: 14 Issue: 3 Pages: 390-392

    • DOI

      10.1246/cl.141123

    • NAID

      130004868392

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Fabrication and measurement of electroluminescence and electrical properties of organic light-emitting diodes containing Mott insulator nanocrystals2015

    • Author(s)
      Soichiro Nozoe, Nobuaki Kinoshita, Masaki Matsuda
    • Journal Title

      Journal of Nanoscinece and Nanotechnology

      Volume: 未定

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Site-selective Electrochemical Fabrication of Lithium Phthalocyanine Nanocrystals2014

    • Author(s)
      Hiroyuki Hasegawa
    • Journal Title

      Science of Advanced Materials

      Volume: 6 Issue: 7 Pages: 1548-1552

    • DOI

      10.1166/sam.2014.1802

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] New Method for the Fabrication of a Charge Transfer Complex by Photoirradiation2014

    • Author(s)
      Masaki Matsuda, Miki Nishi, Shoko Koga, Mika Fujishima, Norihisa Hoshino, Tomoyuki Akutagawa, Hiroyuki Hasegawa
    • Journal Title

      Chemistry A European Journal

      Volume: 20 Issue: 36 Pages: 11318-11321

    • DOI

      10.1002/chem.201402644

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Site-selectively Fabricated Phthalocyanine Neutral Radical Nanocrystals: Structure and Electrical Properties2013

    • Author(s)
      Hiroyuki Hasegawa
    • Journal Title

      Journal of Materials Chemistry C (RSC publishing)

      Volume: 1 Issue: 47 Pages: 7890-7895

    • DOI

      10.1039/c3tc31690d

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Giant Negative Magnetoresistance in an Organic Nanocrystal: Site-selective Device Fabrication by Nanoscale Electrocrystallization2013

    • Author(s)
      Hiroyuki Hasegawa, Masaki Matsuda, Hiroyuki Tajima
    • Journal Title

      Journal of Materials Chemistry C (RSC publishing)

      Volume: 1 Issue: 39 Pages: 6416-6421

    • DOI

      10.1039/c3tc30991f

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Sodium Phthalocyanine Nanocrystals Using Nanoscale Electrocrystallization2013

    • Author(s)
      Hiroyuki Hasegawa
    • Journal Title

      New Journal of Chemistry (RSC publishing)

      Volume: 37 Issue: 8 Pages: 2271-2274

    • DOI

      10.1039/c3nj00416c

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrochemically Fabricated Phthalocyanine-Based Molecular Conductor Films and Their Potential Use in Organic Electronic Devices2013

    • Author(s)
      M. Matsuda, N. Kinoshita, M. Fujishima, S. Tanaka, H. Tajima, and H. Hasegawa
    • Journal Title

      Appl. Phys. Express

      Volume: 6 Issue: 2 Pages: 21602-21602

    • DOI

      10.7567/apex.6.021602

    • NAID

      10031152675

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 新規π-d系鉄(III)テトラベンゾポルフィリンを用いた分子性導電体の開発2015

    • Author(s)
      西美樹, 松田真生, 池田光雄, 花咲徳亮, 星野哲久, 芥川智行
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ電解法による位置選択的ナノ単結晶作製 ~有機アクセプタ分子への展開~2015

    • Author(s)
      長谷川裕之
    • Organizer
      応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県平塚市)
    • Year and Date
      2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Site-selective Fabrication of Nanocrystalline Electromagnetic Devices Using Nanoscale Electrocrystallization2014

    • Author(s)
      Hiroyuki Hasegawa
    • Organizer
      The 11th International Conference on Nano-Molecular Electronics (ICNME2014)
    • Place of Presentation
      神戸国際会議場(兵庫県神戸市)
    • Year and Date
      2014-12-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Constructing a molecular conductor composed of dicyano iron(III) tetrabenzoporphyrin with exploring the giant magnetoresistance effect2014

    • Author(s)
      Miki Nishi, Masaki Matsuda, Norihisa Hoshino, Tomoyuki Akutagawa, Mitsuo Ikeda, Noriaki Hanasaki
    • Organizer
      5th International Meeting on Spin in Organic Semiconductors
    • Place of Presentation
      イーグレ姫路(兵庫県姫路市)
    • Year and Date
      2014-10-13 – 2014-10-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジシアノ鉄(III)テトラベンゾポルフィリンからなる分子性導電体の作製2014

    • Author(s)
      西美樹, 松田真生, 池田光雄, 花咲徳亮, 星野哲久, 芥川智行
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学(広島県東広島市)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ電解法による位置選択的ナノ単結晶作製 ~有機ドナー分子への展開~2014

    • Author(s)
      長谷川裕之
    • Organizer
      応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 光照射を用いた電荷移動錯体単結晶の新規作製法2014

    • Author(s)
      西美樹, 古賀翔子, 藤嶋美加, 松田真生, 星野哲久, 芥川智行, 長谷川裕之
    • Organizer
      第23回有機結晶シンポジウム
    • Place of Presentation
      東邦大学習志野キャンパス(千葉県船橋市)
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electromagnetic Device Fabrication Using Nanoscale Electrocrystallization2014

    • Author(s)
      Hiroyuki Hasegawa
    • Organizer
      The 7th International Meeting on Molecular Electronics (ElecMol’14)
    • Place of Presentation
      ストラスブール(フランス)
    • Year and Date
      2014-08-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] New π-d system based on a low-spin iron(III) macrocyclic complex2014

    • Author(s)
      Masaki Matsuda, Miki Nishi, Mitsuo Ikeda, Noriaki Hanasaki, Norihisa Hoshino, Tomoyuki Akutagawa
    • Organizer
      International conference on science and technology of synthetic metals (ICSM2014)
    • Place of Presentation
      トゥルク(フィンランド)
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of a novel single crystal fabrication method for a molecular conductor: Crystal growth by photoirradiation2014

    • Author(s)
      Miki Nishi, Shoko Koga, Mika Fujishima, Masaki Matsuda, Norihisa Hoshino, Tomoyuki Akutagawa, Hiroyuki Hasegawa
    • Organizer
      International conference on science and technology of synthetic metals (ICSM2014)
    • Place of Presentation
      トゥルク(フィンランド)
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Site-selective Fabrication and Electrical Properties of Planar Phthalocyanine Nanocrystal Using the Nanoscale-electrocrystallization2012

    • Author(s)
      Hiroyuki HASEGAWA
    • Organizer
      1st International Conference on Emerging Advanced Nanomaterials
    • Place of Presentation
      Mercure Hotel, Brisbane (Australia)
    • Related Report
      2012 Research-status Report
  • [Presentation] Preparation of Phthalocyanine Mott Insulator Nano-Crystals and its Current-Voltage Characteristics2012

    • Author(s)
      Nobuaki Kinoshita, Masaki Matsuda
    • Organizer
      1st International Conference on Emerging Advanced Nanomaterials
    • Place of Presentation
      Mercure Hotel, Brisbane (Australia)
    • Related Report
      2012 Research-status Report
  • [Presentation] Site-selective Fabrication and Electrical Properties of Sodium Phthalocyanine Nanocrystal Using the Nanoscale Electrocrystallization2012

    • Author(s)
      Hiroyuki HASEGAWA
    • Organizer
      10th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      淡路国際会議場(淡路市,兵庫県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Nanocrystals of Phthalocyanine-based Mott Insulator and their Electrical Characteristics2012

    • Author(s)
      Nobuaki Kinoshita, Masaki Matsuda
    • Organizer
      10th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      淡路国際会議場(淡路市,兵庫県)
    • Related Report
      2012 Research-status Report
  • [Presentation] Nanoscale Electrocrystallization; a Site-selective Fabrication of Organic Nanocrystalline Devices

    • Author(s)
      Hiroyuki Hasegawa
    • Organizer
      The 3rd Philippine Materials Science Conference
    • Place of Presentation
      De La Salle University(フィリピン)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Coordination Compounds in Molecular Electronics

    • Author(s)
      Masaki Matsuda
    • Organizer
      The 5th International Symosium on Nano and Supramolecular Chemistry
    • Place of Presentation
      Grand Dafam Hotel(インドネシア)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ナノ電解法による磁場応答デバイス作製と電子特性

    • Author(s)
      長谷川裕之,松田真生,田島裕之
    • Organizer
      応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京田辺市)
    • Related Report
      2013 Research-status Report
  • [Presentation] ナノ電解法による位置選択的有機ナノ単結晶作製技術とそのデバイス化

    • Author(s)
      長谷川裕之
    • Organizer
      薄膜材料デバイス研究会
    • Place of Presentation
      龍谷大学 アバンティ響都(きょうと)ホール(京都府)
    • Related Report
      2013 Research-status Report
  • [Presentation] ナノ電解法によるフタロシアニン中性ラジカルナノ単結晶の作製と電子特性

    • Author(s)
      長谷川裕之
    • Organizer
      応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学相模原キャンパス(相模原市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 電荷移動錯体単結晶の新規作製法創出

    • Author(s)
      西美樹,古賀翔子,藤嶋美加,松田真生,星野哲久,芥川智行,長谷川裕之
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都テルサ(京都府)
    • Related Report
      2013 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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