Relation between Iron Related Oxides Formation and Color Tone on Metallic Luster Patterns on Traditional Japanese Ceramics

• Project/Area Number: 24550240
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Kurashiki University of Science and the Arts
• Principal Investigator: KUSANO Yoshihiro 倉敷芸術科学大学, 芸術学部, 教授 (40279039)
• Co-Investigator(Kenkyū-buntansha): FUKUHARA Minoru 岡山理科大学, 工学部, 教授 (20150815) ; TAKADA Jun 岡山大学, 自然科学研究科, 特任教授 (60093259)
• Co-Investigator(Renkei-kenkyūsha): OKADA Teruo 倉敷芸術科学大学, 芸術学部, 教授 (20289226)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
• Keywords: セラミックス / 備前焼 / 酸化鉄 / 陶磁器 / スピネル / 微構造 / 色調

Outline of Final Research Achievements

Formation phase and microstructure of metallic luster color pattern on traditional Japanese unglazed Bizen stoneware and glazed earthenware were studied. Well-oriented hematite (alpha-Fe2O3) particles with ~100nm in thickness were formed in metallic luster pattern on Bizen stoneware. Hematite particles with ~60nm in thickness were also formed on the surface of the metallic luster glassy phase. The reduced atmosphere on cooling process after heating in air and cooling rate were found to be important factors for the formation of metallic luster color pattern on traditional Japanese ceramics.

Research Products

• [Journal Article] Preparation of Yellowish-Red Al-Substituted a-Fe2O3 Powders and Their Thermostability in Color (2014)
  • Author(s): H.Hashimoto, M.Nakanishi, H.Asaoka, T. Tomoaki, Y.Kusano, T.Fujii, J.Takada
  • Journal Title: ACS Appl. Mater. Interfaces Volume: 6 Issue: 22 Pages: 20282-20289
  • DOI: 10.1021/am505820b
  • Peer Reviewed
• [Journal Article] 前焼模様の微構造と形成過程 (2014)
  • Author(s): 草野圭弘, 福原 実
  • Journal Title: 日本結晶学会誌 Volume: 56 Pages: 179-185
  • Peer Reviewed
• [Journal Article] Valence Transitions in Negative Thermal Expansion Material SrCu3Fe4O12 (2014)
  • Author(s): I.Yamada, K.Shiro, H.Etani, S.Marukawa, N.Hayashi, M.Mizumaki, Y.Kusano, S.Ueda, H.Abe, T.Irifune
  • Journal Title: Inorg., Chem. Volume: 53 Issue: 19 Pages: 10563-10569
  • DOI: 10.1021/ic501665c
  • Peer Reviewed
• [Journal Article] Nano-icro-architectural composites with acid properties: Magnetic iron oxides/amorphous silicate prepared from iron oxide produced by iron-oxidizing bacterium, Leptothrix ochracea (2013)
  • Author(s): H. Hashimoto
  • Journal Title: Materials Research Bulletin Volume: 48 Issue: 3 Pages: 1174-1177
  • DOI: 10.1016/j.materresbull.2012.12.022
  • Peer Reviewed
• [Journal Article] B-site deficiencies in A-site-ordered perovskite LaCu3Pt3.75O12 (2013)
  • Author(s): Ochi,M., Yamada, I., Ohgushi, K., Kusano, Y., Mizumaki, Takahashi, R., Nishiyama, N., Inoue, T., Irifune, T.
  • Journal Title: Inorg. Chem. Volume: 52 Issue: 7 Pages: 3985-3989
  • DOI: 10.1021/ic302809v
  • Peer Reviewed
• [Journal Article] Suppression of Intersite Charge Transfer in Charge-Disproportionated Perovskite YCu3Fe4O12 (2013)
  • Author(s): Etani, H., Yamada, I., Ohgushi, K., Hayashi, N., Kusano, Y., Mizumaki, M., Kim, J., Tsuji, N., Takahashi, R., Nishiyama, N., Inoue, T., Irifune, T., Takano, M.
  • Journal Title: Journal of the American Chemical Society Volume: 52 Issue: 16 Pages: 3985-3989
  • DOI: 10.1021/ja312015j
  • Peer Reviewed
• [Journal Article] Characterization of Ancient Red Iron Oxides Excavated from the Shimo-ohgibaru Archaeological Site in Kumamoto, Japan (2013)
  • Author(s): 辻 広美, 村上 隆, 宮崎敬士, 橋本英樹, 團野瑛章, 草野圭弘, 菊地孝宏, 中西 真, 藤井 達生, 高田 潤
  • Journal Title: Journal of the Japan Society of Powder and Powder Metallurgy Volume: 60 Issue: 4 Pages: 146-153
  • DOI: 10.2497/jjspm.60.146
  • NAID: 10031171515
  • ISSN: 0532-8799, 1880-9014
  • Peer Reviewed
• [Journal Article] Nano–Micrometer-Architectural Acidic Silica Prepared from Iron Oxide of Leptothrix ochracea Origin (2013)
  • Author(s): H.Hashimoto, A.Itadani, T.Kudoh, S.Fukui, Y.Kuroda, M.Seno, Y.Kusano, Y.Ikeda, Y.Benino, T.Nanba, M.Nakanishi, T.Fujii, J.Takada
  • Journal Title: ACS Applied Materials & Interfaces Volume: 5 Issue: 11 Pages: 5194-5200
  • DOI: 10.1021/am401029r
  • Peer Reviewed
• [Journal Article] Challenge to the Synthesis of α''-Fe_<16>N_2 Compound Nanoparticle with High Saturation Magnetization for Rare Earth Free New Permanent Magnetic Material (2013)
  • Author(s): T. Ogawa, Y. Ogata, R. Gallage, N. Kobayashi, N. Hayashi, Y. Kusano, S. Yamamoto, K. Kohara, M. Doi, M. Takano and M. Takahashi
  • Journal Title: Applied Physics Express Volume: 6(7) Issue: 7 Pages: 73007-73007
  • DOI: 10.7567/apex.6.073007
  • NAID: 10031187898
  • Peer Reviewed
• [Journal Article] Quantitative understanding of thermal stability of α"-Fe_<16>N_2 (2013)
  • Author(s): S. Yamamoto, R. Gallage, Y. Ogata, Y. Kusano, N. Kobayashi, T. Ogawa, N. Hayashi, K. Kohara, M. Takahashi, and M. Takano
  • Journal Title: Chem. Commun Volume: 49(70) Issue: 70 Pages: 7708-7710
  • DOI: 10.1039/c3cc43590c
  • Peer Reviewed
• [Journal Article] Crystal Structure of b-Fe2O3 and Topotactic Phase Transformation to a-Fe2O3 (2013)
  • Author(s): T.Danno, D.Nakatsuka, Y. Kusano, H.Asaoka, M.Nakanishi, T.Fujii, Y.Ikeda, J.Takada
  • Journal Title: Crystal Growth & Design Volume: 13 Issue: 2 Pages: 770-774
  • DOI: 10.1021/cg301493a
  • Peer Reviewed
• [Presentation] 175細菌が作る鉄酸化物構造体を前駆体として作製した多孔質シリカチューブの特徴 (2014)
  • Author(s): 橋本英樹, 板谷篤司, 工藤孝幸, 黒田泰重, 妹尾昌治, 草野圭弘, 池田靖訓, 中西 真, 藤井達生, 高田 潤
  • Organizer: 粉体粉末冶金協会平成26年度秋季大会
  • Place of Presentation: 早稲田大学(東京都新宿区)
  • Year and Date: 2014-06-03
• [Presentation] Epitaxial growth of epsilon iron oxide on mullite found through studies on traditional Japanese stoneware (2013)
  • Author(s): Y.Kusano, M.Fukuhara, T.Fujii, J.Takada, Y.Ikeda, M.Takano
  • Organizer: 13th Conference of the European Ceramic Society (ECERS XIII)
  • Place of Presentation: リモージュ/フランス
• [Presentation] Preparation, microstructure, and colour tone of microtubule material composed of hematite/amorphous-silicate nanocomposite from iron oxide of bacterial origin (2013)
  • Author(s): H.Hashimoto, H.Asaoka, T.Nakano, Y.Kusano, H.Ishihara, Y.Ikeda, M.Nakanishi, T.Fujii, T.Yokoyama, N.Horiishi, T.Nanba, J.Takada
  • Organizer: 13th Conference of the European Ceramic Society (ECERS XIII)
  • Place of Presentation: リモージュ/フランス
• [Presentation] 細菌由来酸化鉄を前駆体として作製した多孔質酸性非晶質シリカの特徴 (2013)
  • Author(s): 橋本英樹, 板谷篤司, 工藤孝幸, 黒田泰重, 妹尾昌治, 草野圭弘, 池田靖訓, 中西 真, 藤井達生, 高田 潤
  • Organizer: 粉体粉末冶金協会平成25年度秋季大会
  • Place of Presentation: 名古屋国際会議場
• [Presentation] Microstructure and Formation Conditions of Brownish Color Pattern on Traditional Japanese Stoneware (2012)
  • Author(s): Y.Oomori, Y.Kusano, M.Nakanishi, T.Fujii, M.Fukuhara, J.Takada
  • Organizer: Powser Metallurgy Worl Congress & Exhibition(PM2012)
  • Place of Presentation: Pacifico Yokohama
• [Book] French-Japanese Workshop Science for Conservation of Cultural Heritage, pp.29-37 (2012)
  • Author(s): Y.Kusano, M.Takano
  • Total Pages: 164
  • Publisher: Editeurs Hermann