| Budget Amount *help |
¥26,520,000 (Direct Cost: ¥20,400,000、Indirect Cost: ¥6,120,000)
Fiscal Year 2014: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2013: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Fiscal Year 2012: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Outline of Final Research Achievements |
Montmorillonite-supported cationic Si was found to be an active catalyst for allylsilylation of alkenes. The catalytic activity significantly enhanced by the addition of a small amount of water to the reaction mixture. The montmorillonite catalyst was also effective for the cyanation of alkenes using nitromethane as a CN source.
Bifunctional catalytic surface containing metal complex and organic amine was prepared by silane-coupling reaction. The Pd-complex-tertiary amine catalyst showed higher activity for the allylation of nucleophiles compared with only Pd complex-immobilized catalyst. Additionally, CuH-bisphosphine complex catalyst was prepared from hydrosilane, Cu salt, and bisphosphine ligand. The CuH complex exhibited excellent catalytic performances for reductive transformation of CO2.
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