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Increasing the Energy Density of Electrochemical Capacitors Using Metal Nanorods as an Electrode

Research Project

Project/Area Number 24710128
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials/Nanobioscience
Research InstitutionKyoto Institute of Technology

Principal Investigator

NAKANISHI Hideyuki  京都工芸繊維大学, 工芸科学研究科, 助教 (20619655)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords電気化学キャパシタ / 疑似キャパシタ / 電気二重層 / ナノロッド / ナノ材料化学 / ナノワイヤー / 陽極酸化アルミナ / ナノ材料科学
Outline of Final Research Achievements

Electrochemical capacitors, ECs, store energy via the formation of electric double layers at the interface of porous electrode and electrolyte. High-surface-area granular materials such as activated carbon have been used for the electrode of ECs. Internal resistance of ECs have, however, been an issue in increasing the energy density of ECs since it dissipates stored energy as heat during discharge. In the present work, we focused on reducing the internal resistance by creating vertically-aligned, monolithic nanorod arrays as a electrode, and on increasing the energy density of ECs. Cyclic voltammetry, galvanostatic charge/discharge measurement, and impedance spectroscopy showed that the nanorod electrodes store a large amount of energy even at fast charge/discharge rates, and moreover defects of the nanorods greatly influence the device performance.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (17 results)

All 2015 2014 2013 2012 Other

All Presentation (17 results) (of which Invited: 8 results)

  • [Presentation] Synthesis of Nanostructured Electrodes for Electrochemical Energy Storage Applications2015

    • Author(s)
      Hideyuki Nakanishi
    • Organizer
      EMN meeting
    • Place of Presentation
      Chengdu, China
    • Year and Date
      2015-09-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ポリピロールを用いたコアシェルナノワイヤー電極の合成と疑似容量の速度特性2015

    • Author(s)
      川端友人・菊田郁夫・瀬川浩代・中西英行・則末智久・宮田貴章
    • Organizer
      第61回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館
    • Year and Date
      2015-07-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 速い電荷輸送を目指したコアシェル型ナノワイヤー電極の創製と疑似キャパシタへの応用2015

    • Author(s)
      中西英行・川端友人・菊田郁夫・瀬川浩代・則末智久・宮田貴章
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金ナノ粒子に吸着する有機分子の結合定数と粒径依存性2015

    • Author(s)
      内藤康彬・松本郁子・中西英行・則末智久・宮田貴章
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nanostructured Materials for Energy Storage and Transfer Applications2015

    • Author(s)
      Hideyuki Nakanishi
    • Organizer
      EMN meeting
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2015-05-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 金ナノ粒子表面に吸着する有機分子の結合定数2015

    • Author(s)
      松本郁子・内藤康彬・中西英行・則末智久・宮田貴章
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fast Ion and Electron Transport in Supercapacitor Based on Monolithic Nanowire Array Prepared from Defect-free Anodic Aluminum Oxide Mold2015

    • Author(s)
      Hideyuki Nakanishi
    • Organizer
      The Third KIT International Workshop on Advanced Polymer Materials and Fiber Science
    • Place of Presentation
      KIT
    • Year and Date
      2015-02-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Nanostructured Materials for Energy Application2014

    • Author(s)
      Hideyuki Nakanishi
    • Organizer
      The 2nd International Symposium on Polymer Science
    • Place of Presentation
      Ho Chi Minh, Vietnam
    • Year and Date
      2014-11-08
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Vertically Oriented Nanowires for electrochemical energy storage2014

    • Author(s)
      Hideyuki Nakanishi
    • Organizer
      EMN Open Access Week Meeting
    • Place of Presentation
      Chengdu, China
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Supercapacitors Based on Vertically Oriented Metal Nanowire Electrodes2014

    • Author(s)
      Hideyuki Nakanishi
    • Organizer
      7th International Workshop on Advanced Materials Science and Nanotechnology
    • Place of Presentation
      Ha Long City, Vietnam
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 垂直配向した金属ナノワイヤーの合成と電気化学キャパシタへの応用2013

    • Author(s)
      中西英行
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス
    • Related Report
      2012 Research-status Report
  • [Presentation] Nanostructured Metallic Materials for Electronic Applications2012

    • Author(s)
      中西英行
    • Organizer
      NIMS Conference 2012
    • Place of Presentation
      Tsukuba International Congress Center
    • Related Report
      2012 Research-status Report
  • [Presentation] Design and Applications of Nanostructured Materials2012

    • Author(s)
      中西英行
    • Organizer
      The 4th GREEN Symposium
    • Place of Presentation
      NIMS
    • Related Report
      2012 Research-status Report
  • [Presentation] 金属ナノワイヤー電極から成るスーパーキャパシタの特性

    • Author(s)
      中西英行・菊田郁夫・瀬川浩代・則末智久・宮田貴章
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 規則的に配列したナノワイヤー電極から成るスーパーキャパシタのエネルギー貯蔵特性

    • Author(s)
      菊田郁夫・中西英行・瀬川浩代・則末智久・宮田貴章
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] 機能性貴金属ナノ粒子及びナノワイヤーの構築と特性評価

    • Author(s)
      中西英行
    • Organizer
      第18回バイオベースマテリアル学セミナー(日本材料学会高分子材料部門委員会)
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 貴金属ナノ材料の表面構造設計と材料特性

    • Author(s)
      中西英行
    • Organizer
      第5回京都市産業技術研究所/京都工芸繊維大学研究交流会
    • Place of Presentation
      京都工芸繊維大学
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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