| Budget Amount *help |
¥126,620,000 (Direct Cost: ¥97,400,000、Indirect Cost: ¥29,220,000)
Fiscal Year 2017: ¥14,430,000 (Direct Cost: ¥11,100,000、Indirect Cost: ¥3,330,000)
Fiscal Year 2016: ¥14,300,000 (Direct Cost: ¥11,000,000、Indirect Cost: ¥3,300,000)
Fiscal Year 2015: ¥15,340,000 (Direct Cost: ¥11,800,000、Indirect Cost: ¥3,540,000)
Fiscal Year 2014: ¥15,340,000 (Direct Cost: ¥11,800,000、Indirect Cost: ¥3,540,000)
Fiscal Year 2013: ¥67,210,000 (Direct Cost: ¥51,700,000、Indirect Cost: ¥15,510,000)
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| Outline of Final Research Achievements |
We have explored novel porphyrinoids with intriguing structures and properties for long time. Representative achievements in this period are 1) synthesis of fully conjugated porphyrin-hexaphyrin hybrid tape, 2) improvement of the synthetic protocol of subporphyrins, 3) synthesis of subporphyrin tape with a remarkable curvature, 4) discovery of the world largest Huckel aromatic expanded porphyrin, 5) exploration of Mobius aromatic expanded porphyrins, 6) synthesis and characterization of peripherally functionalized porphyrins, and 7) development of stable porphyrinoid radicals.
These results may provoke a range of new research fields such as novel NIR absorbing dyes, excited-state aromaticity, and spin materials based on the stable porphyrinoid radicals.
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