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Development of a monolithic power generation cell for reverse electrodialysis systems

Research Project

Project/Area Number 25281064
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionYamaguchi University

Principal Investigator

Mitsuru Higa  山口大学, 理工学研究科, 教授 (30241251)

Co-Investigator(Kenkyū-buntansha) ENDO Nobutaka  山口大学, 理工学研究科, 講師 (40314819)
垣花 百合子  神戸大学, 工学(系)研究科(研究院), 研究員 (90592014)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2015: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords濃度差エネルギー / ポリビニルアルコール / ブロック共重合体 / イオン交換膜 / モノリシック / 逆電気透析 / 動的輸率 / 膜抵抗 / ファウリング / イオン交換容量 / イオン選択性
Outline of Final Research Achievements

Novel ion-exchange membranes for monolithic power generation cell consisting of a reverse electrodialysis(RED) system were prepared from poly(vinyl alcohol) based block copolymers. The membranes had lower membrane resistance and higher ionic selectivity than commercial ion-exchange membranes.
A large RED power generation system based on a commercial electrodialysis stack was built. The system had 200 pairs of cation- and anion-exchange membranes whose effective membrane area was 1000 cm2. The performance test of the RED system was performed with model seawater (0.5 M NaCl) and model fresh water (various concentrations of NaCl). The power density and gross power output of the system had a maximum value of 0.45 W/m2 and 17.8 W, respectively, using 0.02 M and 0.5 M NaCl solutions. The calculated pumping energy was 2.76 W; hence, the net power of the system was 15.1 W. Hence, an RED system has potential application to a renewable energy source.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (47 results)

All 2016 2015 2014 2013

All Journal Article (9 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results,  Open Access: 2 results) Presentation (38 results) (of which Int'l Joint Research: 2 results,  Invited: 6 results)

  • [Journal Article] Fouling Evaluation of Anion-exchange Membranes in Electrodialysis Systems2016

    • Author(s)
      Mitsuru HIGA, Ryosuke HIRONAGA, Keita TAKAMURA and Masanao CHINEN
    • Journal Title

      Bulletin of the Society of Sea Water Science, Japan

      Volume: 70 Pages: 116-117

    • NAID

      130006101474

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Power Generation of a Large Reverse Electrodialysis( RED) System Based on a Commercial ED stack2016

    • Author(s)
      Mitsuru HIGA, Tomoyuki SAKURADA and Hitoshi TAKEMURA
    • Journal Title

      Bulletin of the Society of Sea Water Science, Japan

      Volume: 70 Pages: 118-119

    • NAID

      130006101475

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrodialytic properties of aromatic and aliphatic type hydrocarbon-based anion-exchange membranes with various anion-exchange groups2014

    • Author(s)
      Mitsuru Higa, Nobuyuki Tanaka, Minami Nagase, Kazuhiro Yutani, Tomokazu Kameyama, Keita Takamura, Yuriko Kakihana
    • Journal Title

      Polymer

      Volume: 55 Issue: 16 Pages: 3951-3960

    • DOI

      10.1016/j.polymer.2014.06.072

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Characterization of cation-exchange membranes prepared from a graft-copolymer consisting of a polysulfone main chain and styrene sulfonic acid side chains2014

    • Author(s)
      Yuriko Kakihana, Yoshiaki Ogawa, Keita Takamura, Naoki Kawamura, Ryosuke Hara, Mitsuru Higa
    • Journal Title

      Electrochimica Acta

      Volume: 129 Pages: 120-126

    • DOI

      10.1016/j.electacta.2014.02.036

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 逆電気透析発電の技術開発動向2014

    • Author(s)
      比嘉 充,渋谷 真史
    • Journal Title

      日本海水学会誌

      Volume: 68 Pages: 293-297

    • NAID

      130005097751

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 塩分濃度差発電とは2014

    • Author(s)
      比嘉 充
    • Journal Title

      電気計算

      Volume: 82 Pages: 33-38

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Charge mosaic membranes with semi-interpenetrating network structures prepared from a polymer blend of poly(vinyl alcohol) and polyelectrolytes2013

    • Author(s)
      Mitsuru Higa, Mayumi Kobayashi, Yuriko Kakihana, Atsushi Jikihara, Naoki Fujiwara
    • Journal Title

      Journal of Membrane Science

      Volume: 428 Pages: 267-274

    • DOI

      10.1016/j.memsci.2012.10.034

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrodialytic Transport Properties of Anion-Exchange Membranes Prepared from Poly(vinyl alcohol) and Poly(vinyl alcohol-co-methacryloyl aminopropyl trimethyl ammonium chloride)2013

    • Author(s)
      Atsushi Jikihara, Reina Ohashi, Yuriko Kakihana, Mitsuru Higa, Kenichi Kobayashi
    • Journal Title

      Membranes

      Volume: 3 Issue: 1 Pages: 1-15

    • DOI

      10.3390/membranes3010001

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 膜電位の測定~基本概念から応用例まで~2013

    • Author(s)
      比嘉 充、藤井 将矢
    • Journal Title

      技術情報協会

      Volume: 第1節 [5] Pages: 115-118

    • Related Report
      2013 Annual Research Report
  • [Presentation] 分離膜を用いた塩分濃度差エネルギー回収技術の原理と技術動向2016

    • Author(s)
      比嘉充
    • Organizer
      海水資源・環境シンポジウム
    • Place of Presentation
      千葉工業大学(千葉、志野市)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Characterization of ion exchange membranes prepared from poly (vinyl alcohol) based block copolymers2015

    • Author(s)
      M. Anno, T. Mizuno, M. Higa
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawaii Convention Center(Honolulu (USA))
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 逆電気透析(RED)における線速度と正味出力の関係2015

    • Author(s)
      櫻田朋之、久野雅弥、比嘉 充
    • Organizer
      膜シンポジウム2015
    • Place of Presentation
      神戸大学(兵庫、神戸市)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新規PVA系ブロック共重合体を用いた陽イオン交換膜:イオン交換基の構造と膜特性の関係2015

    • Author(s)
      阿武真梨香・水野泰子・比嘉充
    • Organizer
      膜シンポジウム2015
    • Place of Presentation
      神戸大学(兵庫、神戸市)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 電気透析における陰イオン交換膜の膜構造がファウリングに与える影響2015

    • Author(s)
      廣永亮介、阿武真梨香、比嘉 充
    • Organizer
      膜シンポジウム2015
    • Place of Presentation
      神戸大学(兵庫、神戸市)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 世界における逆電気透析(RED)発電の開発状況2015

    • Author(s)
      比嘉充
    • Organizer
      第32回ニューメンブレンテクノロジーシンポジウム
    • Place of Presentation
      三田NNホール(東京、港区)
    • Year and Date
      2015-11-18
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 安全な水やクリーンエネルギーを造る分離膜2015

    • Author(s)
      比嘉充
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京、江戸川区)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Characterization of anion exchange membranes prepared from poly (vinyl alcohol) based block copolymers2015

    • Author(s)
      M. Anno, T. Mizuno, M. Higa
    • Organizer
      The 9th Conference of Aseanian Membrane Society (AMS9)
    • Place of Presentation
      Howard Civil International House(台北 (台湾))
    • Year and Date
      2015-07-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 新規PVA系ブロック共重合体を用いた陰イオン交換膜の作製と膜特性評価2015

    • Author(s)
      水野泰子
    • Organizer
      日本海水学会若手会第6回学生研究発表会
    • Place of Presentation
      登別グランドホテル(登別市)
    • Year and Date
      2015-03-09 – 2015-03-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電気透析におけるPVA系陰イオン交換膜のファウリング挙動の解析2014

    • Author(s)
      阿武 真梨香
    • Organizer
      第52回高分子と水に関する討論会
    • Place of Presentation
      東京工業大学(目黒区)
    • Year and Date
      2014-12-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] OptimizationofOperatingConditionsinaLargeReverseElectrodialysisSystem2014

    • Author(s)
      竹村 仁
    • Organizer
      第10回分離技術国際会議
    • Place of Presentation
      奈良県新公会堂(奈良市)
    • Year and Date
      2014-10-30 – 2014-11-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] PreparationandCharacterizationofCation-ExchangeMembranesfromPoly(VinylAlcohol) BasedBlockCopolymers2014

    • Author(s)
      阿武 真梨香
    • Organizer
      第10回分離技術国際会議
    • Place of Presentation
      奈良県新公会堂(奈良市)
    • Year and Date
      2014-10-30 – 2014-11-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 逆電気透析発電の技術開発動向2014

    • Author(s)
      比嘉充
    • Organizer
      日本海水学会第65年会シンポジウム
    • Place of Presentation
      沖縄県男女共同参画センター「てぃるる」(那覇市)
    • Year and Date
      2014-06-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 逆電気透析における一体型スペーサーの開発と発電特性評価2014

    • Author(s)
      竹村 仁
    • Organizer
      日本海水学会第65年会
    • Place of Presentation
      沖縄県男女共同参画センター「てぃるる」(那覇市)
    • Year and Date
      2014-06-18 – 2014-06-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 逆電気透析システムのシミュレーション:正味出力密度におけるPRO との比較2014

    • Author(s)
      阿武 真梨香
    • Organizer
      日本海水学会第65年会
    • Place of Presentation
      沖縄県男女共同参画センター「てぃるる」(那覇市)
    • Year and Date
      2014-06-18 – 2014-06-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 新規ポリビニルアルコール系ブロック共重合体を用いたイオン交換膜の作製と特性評価2014

    • Author(s)
      阿武 真梨香
    • Organizer
      平成26年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(江戸川区)
    • Year and Date
      2014-06-11 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電気透析における一価陰イオン選択透過性の評価2014

    • Author(s)
      廣永亮介・河村直樹・高村啓太・比嘉 充
    • Organizer
      第16回化学工学会学生発表会
    • Place of Presentation
      大阪府立大学(堺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 新規PVA系ブロック共重合体を用いたイオン交換膜の作製と特性評価2014

    • Author(s)
      阿武真梨香・竹村 仁・藤井将矢・比嘉 充
    • Organizer
      第16回化学工学会学生発表会
    • Place of Presentation
      大阪府立大学(堺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 逆電気浸透発電(RED)の原理と技術動向2014

    • Author(s)
      比嘉 充
    • Organizer
      日本海水学会 電気透析および膜技術研究会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 種々のイオン交換膜における酸または塩基の膜透過機構の解析2013

    • Author(s)
      髙村啓太・垣花百合子・比嘉 充
    • Organizer
      日本膜学会第34年会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 膜マトリクスの膜構造および親水性度がイオン選択透過性に及ぼす影響の評価2013

    • Author(s)
      河村直樹・高村啓太・比嘉充・田中伸幸
    • Organizer
      日本海水学会第64年会
    • Place of Presentation
      山梨県立図書館(甲府市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 逆電気透析システムにおける線速度変化と発電特性の関係2013

    • Author(s)
      竹村 仁・藤井将矢・比嘉 充
    • Organizer
      日本海水学会第64年会
    • Place of Presentation
      山梨県立図書館(甲府市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 逆電気透析用新規イオン交換膜の設計とその評価2013

    • Author(s)
      藤井将矢・竹村 仁・比嘉 充
    • Organizer
      第2回JACI/GSCシンポジウム
    • Place of Presentation
      メルパルク大阪(大阪市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 新規な PVA系共重合体を用いたイオン交換膜の作製とその特性評価2013

    • Author(s)
      鵜飼晃平・金輪龍太郎・垣花百合子・比嘉充
    • Organizer
      繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] PVA系モザイク荷電膜の正・負電荷構造と電解質選択透過性との関係2013

    • Author(s)
      重田尚紀・金輪龍太郎・垣花百合子・比嘉充
    • Organizer
      繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 逆電気透析(RED)装置の最適運転条件の検討2013

    • Author(s)
      竹村 仁・阿武真梨香・藤井将矢・比嘉 充
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 電気透析における種々の同符号イオン間選択透過性の評価2013

    • Author(s)
      河村直樹・高村啓太・田中伸幸・比嘉 充
    • Organizer
      第50回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Power generation of reverse electrodialysis: comparison between simulations and experiments2013

    • Author(s)
      Shoya Fujii, Hitoshi Takemura, Mitsuru Higa
    • Organizer
      The 8th Conference of Aseanian Membrane Society(AMS8)
    • Place of Presentation
      西安(中国)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Evaluation of permselectivity for monovalent anions in Electrodialysis2013

    • Author(s)
      Naoki Kawamura, Keita Takamura, Nobuyuki Tanaka, Mitsuru Higa
    • Organizer
      The 8th Conference of Aseanian Membrane Society(AMS8)
    • Place of Presentation
      西安(中国)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Preparation and characterization of ion exchange membranes with charge mosaic structure2013

    • Author(s)
      Tetsuro Maeda, Naoki Shigeta, Kohei Ukai, Ryutaro Kanawa, Yuriko Kakihana, Mitsuru Higa
    • Organizer
      The 8th Conference of Aseanian Membrane Society(AMS8)
    • Place of Presentation
      西安(中国)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ion Exchange Membranes for Sustainable Water and Energy2013

    • Author(s)
      比嘉 充
    • Organizer
      9th World Congress of Chemical Engineering
    • Place of Presentation
      ソウル(韓国)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Evaluation of permselectivity for harmful ions in anion-exchange membranes2013

    • Author(s)
      Naoki Kawamura, Keita Takamura, Mitsuru Higa, Nobuyuki Tanaka
    • Organizer
      The 6th Membrane Conference of Visegrad Countries permea2013
    • Place of Presentation
      ワルシャワ(ポーランド)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 新規なPVA系共重合体を用いたイオン交換膜の作成および特性評価2013

    • Author(s)
      鵜飼晃平・金輪龍太郎・垣花百合子・比嘉 充
    • Organizer
      膜シンポジウム2013
    • Place of Presentation
      京都府立医科大学(京都市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 種々の膜構造を有する陰イオン交換膜におけるイオン選択透過性の評価2013

    • Author(s)
      河村直樹・高村啓太・亀山智一・田中伸幸・比嘉 充
    • Organizer
      膜シンポジウム2013
    • Place of Presentation
      京都府立医科大学(京都市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 電気透析における陰イオン交換膜の膜構造とファウリング特性との関係2013

    • Author(s)
      高村啓太、田中伸幸、比嘉 充
    • Organizer
      膜シンポジウム2013
    • Place of Presentation
      京都府立医科大学(京都市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Evaluation of permselectivity for harmful ions in anion-exchange membranes2013

    • Author(s)
      Naoki Kawamura, Keita Takamura, Nobuyuki Tanaka, Mitsuru Higa
    • Organizer
      2013 Kyushu-Seibu/Pusan-Gyeongnam Joint Symposium on High Polymers(16th) and Fibers(14th)
    • Place of Presentation
      佐賀大学本庄キャンパス(佐賀市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Characterization of charge mosaic membrane prepared by polymer coating method2013

    • Author(s)
      R. Kanawa・N. Shigeta・ A. Jikihara・M. Higa
    • Organizer
      The 8th International Membrane Science and Technology Conference (IMSTEC 2013)
    • Place of Presentation
      メルボルン(オーストラリア)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Simulation study on power density and power generation efficiency of a reverse electrodialysis system2013

    • Author(s)
      S. Fujii・K. Takemura・M. Higa
    • Organizer
      The 8th International Membrane Science and Technology Conference (IMSTEC 2013)
    • Place of Presentation
      メルボルン(オーストラリア)
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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