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Improvement of polymer-based organic transistor performance by thin-film formation techniques utilizing liquid crystalline nature

Research Project

Project/Area Number 25286045
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Applied materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

Sakamoto Kenji  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主席研究員 (00222000)

Co-Investigator(Renkei-kenkyūsha) YASUDA Takeshi  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主幹研究員 (30380710)
Research Collaborator BULGAREVICH Kirill  
DEGUCHI Yu  
Project Period (FY) 2013-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2016: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Keywords有機トランジスタ / 有機半導体 / 液晶性 / 光配向膜 / フロー・コーティング / 配向制御 / LB膜 / LB膜 / 高分子構造・物性 / 電子デバイス・機器 / フローコーティング
Outline of Final Research Achievements

To improve the performance of polymer-based organic field-effect transistors (OFETs) and reduce the device-to-device variation, we have developed coating methods of high mobility organic semiconductors with capability of controlling molecular orientation. We established "self-assisted flow coating (SAFC)" as a scalable coating method that can apply to hydrophobic (lyophobic) gate dielectric surfaces, which induce edge-on orientation of polymeric organic semiconductors. Using SAFC, we succeeded in fabricating arrays of polymer-based OFETs that show a field-effect mobility comparable to that of a-Si based FETs and the device-to-device variation of less than 3%. Furthermore, we developed alignment layers to induce high in-plane orientational order of the backbone structure of polymeric organic semiconductor. By combined use of a flow coating method and the alignment layer, we succeeded in fabricating highly oriented polymeric organic semiconductor thin films.

Report

(6 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (33 results)

All 2018 2017 2016 2015 2014 2013 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 4 results) Presentation (21 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results) Remarks (7 results)

  • [Journal Article] Spatially Uniform Thin-Film Formation of Polymeric Organic Semiconductors on Lyophobic Gate Insulator Surfaces by Self-Assisted Flow-Coating2017

    • Author(s)
      Kirill Bulgarevich, Kenji Sakamoto, Takeo Minari, Takeshi Yasuda, and Kazushi Miki
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9 Issue: 7 Pages: 6237-6245

    • DOI

      10.1021/acsami.6b15398

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pretilt angle of liquid crystals generated by polyimide photo-alignment layers treated with vapor of primary and tertiary alkylamines2016

    • Author(s)
      Kenji Sakamoto, Kiyoaki Usami, Shogo Kiyohara, and Kazushi Miki
    • Journal Title

      Proc. of SPIE

      Volume: 9940 Pages: 994008-994008

    • DOI

      10.1117/12.2235677

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photo-alignment property of azobenzene-containing polyimide films swollen by alkyl-amine2015

    • Author(s)
      Kenji Sakamoto, Kiyoaki Usami, and Kazushi Miki
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: 611 Issue: 1 Pages: 153-159

    • DOI

      10.1080/15421406.2015.1030213

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photo-alignment Efficiency Enhancement of Polyimide Alignment Layers by Alkyl-amine Vapor Treatment2014

    • Author(s)
      K. Sakamoto, K. Usami, and K. Miki
    • Journal Title

      Appllied Physics Express

      Volume: 7 Issue: 8 Pages: 081701-081701

    • DOI

      10.7567/apex.7.081701

    • NAID

      210000137181

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Small device-to-device variation of 6,13-bis(triisopropylsilylethynyl)pentacene field-effect transistor arrays fabricated by a flow-coating method2014

    • Author(s)
      Kenji Sakamoto, Kirill Bulgarevich, and Kazushi Miki
    • Journal Title

      Japanease Journal of Applied Physics

      Volume: 53 Issue: 2S Pages: 02BE01-02BE01

    • DOI

      10.7567/jjap.53.02be01

    • NAID

      210000143386

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Photoalignment behavior of polyimide containing azobenzene in the backbone structure treated with vapor of primary and tertiary alkylamines2018

    • Author(s)
      Kenji Sakamoto, Kiyoaki Usami
    • Organizer
      27th International Liquid Crystal Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of polymeric organic semiconductor films on lyophobic gate insulator surfaces by self-assisted flow-coating2017

    • Author(s)
      Kirill Bulgarevich, 坂本謙二,三成剛生,安田剛,三木一司
    • Organizer
      第64回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 異なる級のアルキルアミンで処理されたポリイミド光配向膜の分子配向2017

    • Author(s)
      坂本謙二,宇佐美清章
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Chemical imidization of photo-aligned films of polyimide containing azobenzene in the backbone structure2016

    • Author(s)
      Kiyoaki, Usamin, Natsumi Konishi, and Kenji Sakamoto
    • Organizer
      12th International Conference on Nano-Molecular Electronics 
    • Place of Presentation
      Kobe International Conference Center (Kobe)
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Polymer-based organic field-effect transistor arrays fabricated on highly hydrophobic gate insulator surfaces by flow-coating2016

    • Author(s)
      Kirill Bulgarevich, Kazushi Miki, Kenji Sakamoto, Takeo Minari, and Takeshi Yasuda
    • Organizer
      12th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      Kobe International Conference Center (Kobe)
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoalignment behavior of polyimide containing azobenzene in the backbone structure treated with different classes of alkylamin2016

    • Author(s)
      Kenji Sakamoto, Kiyoaki Usami, Shogo Kiyohara, and Kazushi Miki
    • Organizer
      2nd International Conference on Photoalignment and Photopatterning in Soft Materials
    • Place of Presentation
      Toyoda Auditorium, Nagoya University (Nagoya)
    • Year and Date
      2016-11-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] フロー・コート法で作製したpBTTT-C16膜の電荷輸送特性の面内均一性2016

    • Author(s)
      Kirill Bulgarevich, 坂本謙二, 三成剛生, 安田剛, 三木一司
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ,(新潟)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 液晶性高分子-有機トランジスタの素子特性のばらつき評価2016

    • Author(s)
      坂本謙二, Kirill Bulgarevich, 三成剛生, 安田剛, 三木一司
    • Organizer
      2016年日本液晶学会討論会
    • Place of Presentation
      大阪工業大学(大阪)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] アミン蒸気処理されたアゾベンゼン含有ポリイミド光配向膜の面内異方性がプレチルト角に与える影響2016

    • Author(s)
      宇佐美 清章, 清原 翔吾, 川口翔平, 坂本 謙二
    • Organizer
      2016年日本液晶学会討論会
    • Place of Presentation
      大阪工業大学(大阪)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] Pretilt angle of liquid crystals generated by polyimide photo-alignment layers treated with vapor of primary and tertiary alkylamines2016

    • Author(s)
      Kenji Sakamoto, Kiyoaki Usami, Shogo Kiyohara, and Kazushi Miki
    • Organizer
      SPIE Optics + Photonics
    • Place of Presentation
      San Diego (USA)
    • Year and Date
      2016-08-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Influence of In-plane Anisotropy of Azobenzene- containing Polyimide Alignment Layers Treated with Alkyl-amine Vapor on Pretilt2016

    • Author(s)
      Kiyoaki Usami, Shogo Kiyohara, Syohei Kawaguchi,and Kenji Sakamoto
    • Organizer
      26th International Liquid Crystal Conference
    • Place of Presentation
      Kent (USA)
    • Year and Date
      2016-07-31
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子(pBTTT-C16)有機トランジスタアレイの 素子特性のばらつき2015

    • Author(s)
      ブルガレビッチ キリル,坂本謙二,三成剛生,安田剛,三木一司
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] アゾベンゼンを主鎖に含むポリイミドの光配向膜によるプレチルト角発生に及ぼす アミン蒸気処理の効果2015

    • Author(s)
      宇佐美清章,清原翔吾,坂本謙二
    • Organizer
      2015日本液晶学会討論会
    • Place of Presentation
      東京工業大学すずかけ台キャンパス
    • Year and Date
      2015-09-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] アルキルアミン蒸気処理時間とポリイミド光配向膜の面内異方性との関係2015

    • Author(s)
      坂本謙二
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Significant Improvement in Pretilt Angle Controllability by Polyimide Photo-alignment Layers by Alkyl-amine Vapor Treatment2014

    • Author(s)
      K. Sakamoto, K. Usami, K. Miki
    • Organizer
      1st International Conference on Photoalignment and Photopatterning in Soft Materials
    • Place of Presentation
      Hong Kong
    • Year and Date
      2014-11-29 – 2014-12-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] Relationship between Pretilt Angle and Molecular Orientation of Azo-PI Photo-alignment Layers Treated with Alkyl-amine Vapor2014

    • Author(s)
      K. Usami, S. Kiyohara, K. Sakamoto
    • Organizer
      1st International Conference on Photoalignment and Photopatterning in Soft Materials
    • Place of Presentation
      Hong Kong
    • Year and Date
      2014-11-29 – 2014-12-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] Highly Efficient Photoalignment Treatment for Polyimides Containing Azobenzene in the Backbone Structure2014

    • Author(s)
      Kenji Sakamoto, Kiyoaki Usami, and Kazushi Miki
    • Organizer
      International Conference on Organic Materials for Electronics and Photonics
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] アミン蒸気処理によるポリアミック酸膜の膨潤と光配向特性2014

    • Author(s)
      坂本謙二,宇佐美清章,三木一司
    • Organizer
      2014年日本液晶学会討論会
    • Place of Presentation
      松江くにびきメッセ
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Significant extension of pretilt angle controllable range with polyimide photo-alignment layers by an alkyl-amine vapour treatment2014

    • Author(s)
      Kenji Sakamoto, Kiyoaki Usami, and Kazushi Miki
    • Organizer
      25th International Liquid Crystal Conference
    • Place of Presentation
      Dublin,Ireland
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Molecular orientation of photo-alignment layers of azobenzene-containing polyimide treated with alkyl-amine vapour2014

    • Author(s)
      K. Usami, S. Kiyohara, and K. Sakamoto
    • Organizer
      25th International Liquid Crystal Conference
    • Place of Presentation
      Dublin,Ireland
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Alignment control of organic semiconductor molecules and its application2013

    • Author(s)
      Kenji Sakamoto
    • Organizer
      The 4th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
    • Place of Presentation
      Kanazawa, Japan
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks] NIMS Researchers Database

    • URL

      https://samurai.nims.go.jp/profiles/sakamoto_kenji

    • Related Report
      2017 Annual Research Report
  • [Remarks] 物質・材料研究機構 機能性材料研究拠点半導体ナノ界面グループ

    • URL

      http://www.nims.go.jp/research/group/seminanointer/index.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] NIMSの研究者情報データベース「SAMURAI」

    • URL

      http://samurai.nims.go.jp/SAKAMOTO_Kenji-j.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 物質・材料研究機構 高分子材料ユニット 界面機能グループ

    • URL

      http://www.nims.go.jp/units/PMU/3func_Rese.html

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/SAKAMOTO_Kenji-j.html

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Remarks] 独立行政法人物質・材料研究機構高分子材料ユニット界面機能グループ

    • URL

      http://www.nims.go.jp/group/g_electronic-functional/index.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/SAKAMOTO_Kenji-j.html

    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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