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Zero-filed ESR dedicated for development of battery materials

Research Project

Project/Area Number 25288007
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionKyoto University

Principal Investigator

Takeda Kazuyuki  京都大学, 理学(系)研究科(研究院), 准教授 (20379308)

Co-Investigator(Kenkyū-buntansha) 香川 晃徳  大阪大学, 基礎工学研究科, 助教 (70533701)
根来 誠  大阪大学, 基礎工学研究科, 助教 (70611549)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2013: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Keywords電子スピン共鳴(ESR) / ゼロ磁場ESR / 電池材料 / 電子スピン共鳴
Outline of Final Research Achievements

The purpose of this project was to build an experimental setup for electron spin resonance (ESR) spectroscopy dedicated for development of battery materials, where the following difficulties were expected: (i) dielectric loss in the battery material degrading the resonant characteristics of the microwave cavity for ESR measurements, (ii) short skin depth in conducting materials that limit the accessible sample volume, and (iii) decomposition of the air-sensitive materials during ESR measurement. To cope with these challenges, we aimed at zero-filed ESR by accessing the transitions between energy levels separated by zero-field splitting interactions. To enable studies of thin, flat samples, we developed non-resonant micro-stripline detectors. In addition, we build a compact ESR system that can be put inside a glove-box.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (6 results)

All 2016 2015

All Presentation (5 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Presentation] オプトメカニクスを利用した磁気共鳴信号の光変換2016

    • Author(s)
      武田和行
    • Organizer
      量子スピン系研究会
    • Place of Presentation
      福井大学
    • Year and Date
      2016-12-02
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ku帯及びX帯多周波数任意波形パルスESR分光計の開発2016

    • Author(s)
      和久田翔吾、根来誠、ヤップユンセン、濱崎宰、香川晃徳、北川勝浩
    • Organizer
      第55回電子スピンサイエンス学会年会 SEST2016
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ku帯ストリップライン型共振器を用いた電子スピン量子操作に関する研究2016

    • Author(s)
      久野真由子、岨圭祐、ヤップユンセン、根来誠、香川晃徳、北川勝浩
    • Organizer
      第55回電子スピンサイエンス学会年会 SEST2016
    • Place of Presentation
      大阪市立大学
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Converting NMR signals into light via a membrane capacitor2016

    • Author(s)
      武田和行
    • Organizer
      Novel Magnetic Resonance Techniques in Millimeter and Terahertz Waves and their Applications to Bioscience (MR-THz2016)
    • Place of Presentation
      神戸大学
    • Year and Date
      2016-11-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マイクロストリップライン型広帯域進行波ESR分光計の開発2015

    • Author(s)
      竹内祐介、香川晃徳、根来誠、北川勝浩、武田和行
    • Organizer
      第54回電子スピンサイエンス学会年会(SEST2015)
    • Place of Presentation
      新潟コンベンションセンター
    • Year and Date
      2015-11-02
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 緩和時間測定方法及び磁気共鳴測定装置2016

    • Inventor(s)
      武田和行・鈴木貴之
    • Industrial Property Rights Holder
      武田和行・鈴木貴之
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-07-28
    • Related Report
      2016 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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