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Characterization of metal oxide nanotubes and graphene composite by photovoltaic electrochemistry

Research Project

Project/Area Number 25390021
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanomaterials chemistry
Research InstitutionMeijo University

Principal Investigator

Bandow Shunji  名城大学, 理工学部, 教授 (20231540)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsナノチューブ / 酸化物 / 光電変換 / グラフェン / 太陽電池
Outline of Final Research Achievements

Evaluations of structural stability against temperature and optical band gap were carried out for zinc doped iron oxide nanotubes prepared by sol-gel method. As results, we found that the nanotube had magnetite structure and stable up to ca. 300℃, and that the band gap was narrowed to 2.0eV by Zn dope. Photovoltaic cell was constructed by using pristine iron oxide nanotubes, organometal halide perovskite and P3HT, which gave the spectral sensitivity of 40% at 400nm and it preserved near 10% level even at 600nm. Although the iron oxide nanotubes indicated the photovoltaic feature, we have not tried to apply the graphene as the electrode. Instead, in order to make carbon transparent electrodes, we study basic technic to disperse the carbon nanotubes without using surfactant.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (14 results)

All 2015 2014 2013

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Bandgap narrowing of iron oxide nanotubes upon doping with zinc and their spectral sensitivity used as photoelectrode2015

    • Author(s)
      Y. Kosugi, T. Tomiyasu, S. Bandow
    • Journal Title

      MRS Advances

      Volume: なし Issue: 59 Pages: 1-6

    • DOI

      10.1557/adv.2015.28

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structure and Electronic States of Zinc-Doped Iron Oxide Nanotubes Prepared by a Surfactant-Assisted Sol-Gel Method2014

    • Author(s)
      Yuta Kosugi, Shunji Bandow
    • Journal Title

      J. Inorg. Organomet. Polym.

      Volume: 24 Pages: 933-939

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural Stability of Iron Oxide Nanotubes and an Enhancement of Photo Induced Current Detected in the Complex with Fullerenols2014

    • Author(s)
      Shunji Bandow, Yuki Shiraki
    • Journal Title

      Mater. Res. Soc. Symp. Proc.

      Volume: 1659 Pages: 169-174

    • DOI

      10.1557/opl.2014.133

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] A nitrogen-doped graphene film prepared by chemical vapor deposition of a methanol mist containing methylated melamine resin2013

    • Author(s)
      Takahiro Mizuno, Morio Takizawa, Bun Tsuchiya, Makoto Jinno, Shunji Bandow
    • Journal Title

      Appl. Phys. A

      Volume: 113 Issue: 3 Pages: 645-650

    • DOI

      10.1007/s00339-013-8012-9

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Bandgap Narrowing of Iron Oxide Nanotubes upon Doping with Zinc and Their Spectral Sensitivity Used as Photoelectrode2015

    • Author(s)
      Yuta Kosugi, Takuya Tomiyasu, Shunji Bandow
    • Organizer
      2015 MRS Fall Meeting
    • Place of Presentation
      ボストン
    • Year and Date
      2015-11-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of iron oxide nanotubes with spectral sensitivity peak at red light region and its application to photo-voltaic device2015

    • Author(s)
      Yuta Kosugi, Takuya Tomiyasu, Shunji Bandow
    • Organizer
      The 49th Fullerene Nanotubes Graphene General Symposium
    • Place of Presentation
      福岡
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Optical band-gap narrowing of iron oxide nanotubes by temperature annealing and zinc doping2015

    • Author(s)
      Shunji Bandow, Yuta Kosugi
    • Organizer
      The 16th International Conference on the Science and Application of Nanotubes (NT15)
    • Place of Presentation
      名古屋
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spectral sensitivity of pristine and zinc doped iron-oxide nanotube based solar cell2015

    • Author(s)
      Yuta Kosugi, Shunji Bandow,
    • Organizer
      The 16th International Conference on the Science and Application of Nanotubes (NT15)
    • Place of Presentation
      名古屋
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical properties of boron- and nitrogen-doped carbon nanohorn aggregates2015

    • Author(s)
      Ryota Yuge, Shunji Bandow, Masako Yudasaka, Kiyohiko Toyama, Sumio Iijima, Noriyuki Tamura, Takashi Manako
    • Organizer
      Fullerene Nanotubes Graphene General Symposium
    • Place of Presentation
      東京大学・伊藤国際学術センター・伊藤謝恩ホール(東京都文京区)
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Characteristic of spectral sensitivity for the composite film of Zn doped iron oxide nanotubes and organometal halide perovskite2015

    • Author(s)
      Yuta Kosugi, Hiroyuki Kusuda, Ayano Saiki, Shunji Bandow
    • Organizer
      Fullerene Nanotubes Graphene General Symposium
    • Place of Presentation
      東京大学・伊藤国際学術センター・伊藤謝恩ホール(東京都文京区)
    • Year and Date
      2015-02-21 – 2015-02-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Structure and electrochemical properties of boron- and nitrogen-doped carbon nanohorn aggregates2014

    • Author(s)
      Ryota Yuge, Takashi Manako, Shunji Bandow, Masako Yudasaka, Kiyohiko Toyama, Sumio Iijima
    • Organizer
      Fullerene Nanotubes Graphene General Symposium
    • Place of Presentation
      名古屋大学・IB電子情報館(愛知県名古屋市千種区)
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Doping of zinc to the iron oxide nanotubes by using a poly-condensation of metal nitrate hydrates on the surface of surfactant2014

    • Author(s)
      Yuta Kosugi, Shunji Bandow
    • Organizer
      The 46th Fullerene Nanotubes Graphene General Symposium
    • Place of Presentation
      Tokyo
    • Related Report
      2013 Research-status Report
  • [Presentation] Structural transformation of iron oxide nanotubes by the heat treatment2013

    • Author(s)
      Shunji Bandow, Yuki Shiraki
    • Organizer
      The 45th Fullerene Nanotubes Graphene General Symposium
    • Place of Presentation
      Osaka
    • Related Report
      2013 Research-status Report
  • [Presentation] Structural Stability of Iron Oxide Nanotubes and an Enhancement of Photo Induced Current Detected in the Complex with Fullerenols2013

    • Author(s)
      Shunji Bandow, Yuki Shiraki
    • Organizer
      2013 MRS Fall Meeting
    • Place of Presentation
      Boston, MA USA
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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