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Control of the colloid agglomeration using laser irradiation and its application on the nano-micro structure fabrication

Research Project

Project/Area Number 25390042
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nano/Microsystems
Research InstitutionShimane University

Principal Investigator

Tsuji Takeshi  島根大学, 総合理工学研究科(研究院), 准教授 (50284568)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsコロイド / 微粒子 / ナノ材料 / レーザー / ナノ粒子 / ミクロン粒子 / 凝集 / サブミクロン粒子
Outline of Final Research Achievements

Laser melting in liquids attracts much attention as a novel technique to prepare spherical particles of sub-micron size. In this research, we have applied this technique to prepare gold sub-micron particles (AuSMP) and investigated the formation mechanism. As a result of the investigation, we have clarified following things.
1) The agglomeration of the source gold nanoparticles is necessary to obtain AuSMP. 2) When stabilizing reagent is used, the agglomeration is induced by laser irradiation dynamically. 3) As the stabilizing reagents, inorganic salts such as NaCl can be used as well as the ordinary stabilizing reagents such as sodium citrate. 4) The stabilizing reagents influence on the agglomeration process and AuSMP size.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (38 results)

All 2016 2015 2014 2013 Other

All Journal Article (12 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (24 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results) Remarks (2 results)

  • [Journal Article] Preparation of Gold Submicron-sized Particles using Laser Irradiation for Gold Nanoparticles Stabilized by Carbonate2015

    • Author(s)
      辻. 剛志, 高. 勇海, 辻. 正治, 石. 善恵, 越. 直人
    • Journal Title

      IEEJ Transactions on Electronics, Information and Systems

      Volume: 135 Issue: 9 Pages: 1090-1095

    • DOI

      10.1541/ieejeiss.135.1090

    • NAID

      130005096934

    • ISSN
      0385-4221, 1348-8155
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Laser Melting in Liquids Using Gold Nanoparticles Stabilized by Na2CO32015

    • Author(s)
      Tsuji, Takeshi, Takade, Isami, Tsuji, Masaharu, Ishimawa, Yoshie and Koshizaki, Naoto
    • Journal Title

      Journal of Laser Micro Nanoengineering

      Volume: 10 Issue: 3 Pages: 329-333

    • DOI

      10.2961/jlmn.2015.03.0017

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of submicron-sized spherical particles of gold using laser-induced melting in liquids and low-toxic stabilizing reagent2015

    • Author(s)
      Tsuji, T., Higashi, Y., Tsuji, M., Ishikawa, Y. and Koshizaki, N.
    • Journal Title

      Applied Surface Science

      Volume: 348 Pages: 10-15

    • DOI

      10.1016/j.apsusc.2015.02.057

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of antimony sulfide semiconductor nanoparticles by pulsed laser ablation in liquid2015

    • Author(s)
      Sun, Ren-De and Tsuji, Takeshi
    • Journal Title

      Applied Surface Science

      Volume: 348 Pages: 38-44

    • DOI

      10.1016/j.apsusc.2015.02.041

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origins of lasing emission in a resonance-controlled ZnO random laser2014

    • Author(s)
      T. Nakamura; H. Fujiwara; R. Niyuki; K. Sasaki; Y. Ishikawa; N. Koshizaki; T. Tsuji; S. Adachi
    • Journal Title

      New Journal of Physics

      Volume: 16 Issue: 9 Pages: 093054-093054

    • DOI

      10.1088/1367-2630/16/9/093054

    • NAID

      120005600750

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of Ag-Pt Alloy Triangular Nanoframes by Galvanic Replacement Reactions2014

    • Author(s)
      Masaharu Tsuji, Mika Hamasaki, Atsuhiko Yajima, Masashi Hattori, Takeshi Tsuji, and Hirofumi Kawazumi
    • Journal Title

      Materials Letters

      Volume: 121 Pages: 113-117

    • DOI

      10.1016/j.matlet.2014.01.093

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Syntheses of Ag-Au and Ag-Pd Alloy Triangular Hollow Nanoframes by Galvanic Replacement Reactions without and with Post-treatment Using NaCl in an Aqueous Solution2014

    • Author(s)
      Masaharu Tsuji, Takafumi Kidera, Atsuhiko Yajima, Mika Hamasaki, Masashi Hattori, Takeshi Tsuji, and Hirofumi Kawazumi
    • Journal Title

      CrystEngComm

      Volume: 16 Issue: 13 Pages: 2684-2691

    • DOI

      10.1039/c3ce42244e

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of submicron-sized gold particles using laser-induced agglomeration-fusion process2014

    • Author(s)
      T. Tsuji; Y. Higashi ; M. Tsuji ; Y. Ishikawa,N. Koshizaki
    • Journal Title

      Proc. SPIE

      Volume: 8969 Pages: 89690B-89690B

    • DOI

      10.1117/12.2036912

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation and investigation of the formation mechanism of submicron-sized spherical particles of gold using laser ablation and laser irradiation in liquids2013

    • Author(s)
      T. Tsuji, M. Tsuji , 他
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 15 Issue: 9 Pages: 3099-3107

    • DOI

      10.1039/c2cp44159d

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mechanism of pulse laser interaction with colloidal nanoparticles2013

    • Author(s)
      Alexander Pyatenko, Hongqiang Wang, Naoto Koshizaki, Takeshi Tsuji
    • Journal Title

      Laser & Photonics Reviews

      Volume: 7 Issue: 4 Pages: 596-604

    • DOI

      10.1002/lpor.201300013

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of spherical-shaped submicron particles of ZnO using laser-induced melting of submicron-sized source materials2013

    • Author(s)
      Takeshi Tsuji, Yuuma Higashi, Masaharu Tsuji, Hideki Fujiwara, Yoshie Ishikawa, Naoto Koshizaki
    • Journal Title

      Journal of Laser Micro/Nanoengineering

      Volume: 8 Issue: 3 Pages: 292-295

    • DOI

      10.2961/jlmn.2013.03.0017

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] レーザー光による金ナノ粒子の凝集-溶融過程の制御2013

    • Author(s)
      辻 剛志
    • Journal Title

      光化学

      Volume: 44 Pages: 146-149

    • NAID

      40019924266

    • Related Report
      2013 Research-status Report
  • [Presentation] 液中レーザープロセスを用いたコロイドの凝集-溶融過程の制御2016

    • Author(s)
      辻 剛志, 高出 勇海, 山田 尚正, 浅海 千明, 北川 文弥, 石川 善恵, 越崎 直人
    • Organizer
      レーザー学会学術講演会第36回年次大会
    • Place of Presentation
      名古屋 (名城大学)
    • Year and Date
      2016-01-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 液中レーザー照射によるナノ粒子の凝集・溶融過程の制御 (2)2015

    • Author(s)
      辻 剛志, 高出 勇海, 浅海 千明, 北川 文弥
    • Organizer
      レーザー学会第487回研究会「新レーザー技術」
    • Place of Presentation
      松江 (くにびきメッセ)
    • Year and Date
      2015-12-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] ハロゲン化物イオンによって保護された金ナノ粒子のレーザー誘起凝集過程の解析2015

    • Author(s)
      浅海 千明, 辻 剛志
    • Organizer
      2015ハロゲン利用ミニシンポジウム
    • Place of Presentation
      松江 (島根大学)
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 液中レーザープロセスを用いた球状サブミクロン粒子の作製2015

    • Author(s)
      辻 剛志
    • Organizer
      平成27年度物質・デバイス領域共同研究拠点共同研究研究会
    • Place of Presentation
      札幌 (北海道大学)
    • Year and Date
      2015-11-21
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Control of agglomeration-fusion process of colloidal particles using laser processes in liquids2015

    • Author(s)
      Tsuji T, Takade I, Higashi Y, Tsuji M, Ishikawa I, Koshizaki N
    • Organizer
      ALT'15
    • Place of Presentation
      Faro (Potugal) (Universidade Do Algarve)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Laser-induced Melting in Liquids Using Gold Nanoparticles Stabilized by Na2CO32015

    • Author(s)
      Tsuji T, Takade I, Tsuji M, Ishikawa I, Koshizaki N
    • Organizer
      LAMP2015
    • Place of Presentation
      北九州 (北九州国際会議場)
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of the agglomeration-fusion process of gold nanoparticles using laser irradiation in liquids to prepare submicron-sized spherical particles2015

    • Author(s)
      辻 剛志, 高出 勇海, 東 優磨, 辻 正治, 石川善恵, 越崎直人
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      船橋,日本大学船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 液中レーザー照射と塩を用いた金ナノ粒子の凝集制御と金サブミクロン粒子の作製2015

    • Author(s)
      辻 剛志, 高出 勇海, 東 優磨, 辻 正治, 石川善恵, 越崎直人
    • Organizer
      レーザー学会学術講演会第35回年次大会
    • Place of Presentation
      東京,東海大学高輪キャンパス
    • Year and Date
      2015-01-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 液中レーザー光照射と塩を用いた金ナノ粒子の凝集・溶融過程の制御2014

    • Author(s)
      辻 剛志, 東 優磨, 辻 正治, 石川善恵, 越崎直人
    • Organizer
      第75回応用物理学
    • Place of Presentation
      札幌,北海道大学札幌キャンパス
    • Year and Date
      2014-09-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Preparation of non-toxic gold submicron-sized particles using laser-induced melting in liquids2014

    • Author(s)
      T. Tsuji; Y. Higashi ; M. Tsuji ; Y. Ishikawa,N. Koshizaki
    • Organizer
      International Symposium on Small Particles and Inorganic Clusters (ISSPIC) XVII
    • Place of Presentation
      Fukuoka, Maedashi Campus, Kyushu Univ.
    • Year and Date
      2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] Preparation of non-toxic gold submicron-sized particles using laser-induced melting in liquids2014

    • Author(s)
      Tsuji T, Higashi Y, M, Tsuji M, Koshizaki N, Ishikawa Y
    • Organizer
      3rd conference on laser ablation and nanoparticle generation in liquids (ANGEL 2014)
    • Place of Presentation
      Matsuyama, JAL City Hotel
    • Year and Date
      2014-05-20
    • Related Report
      2014 Research-status Report
  • [Presentation] Preparation of non-toxic gold submicron-sized particles using laser-induced melting in liquids

    • Author(s)
      T. Tsuji; Y. Higashi ; M. Tsuji ; Y. Ishikawa,N. Koshizaki
    • Organizer
      EOS Conference on Advanced Nanoparticle Generation and Excitation by Lasers in Liquids
    • Place of Presentation
      JALシティーホテル松山 (松山)
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of submicron-sized gold particles using laser-induced agglomeration-fusion process

    • Author(s)
      T. Tsuji; Y. Higashi ; M. Tsuji ; Y. Ishikawa,N. Koshizaki
    • Organizer
      LASE, Photonics West 2014
    • Place of Presentation
      Moscone Center (San Francisco)
    • Related Report
      2013 Research-status Report
  • [Presentation] 液中レーザー溶融法における二次溶融過程の解析及び制御

    • Author(s)
      豊原 史也, 辻 剛志, 辻 正治, 藤原 英樹, 石川善恵, 越崎直人
    • Organizer
      レーザー学会学術講演会第34回年次大会
    • Place of Presentation
      北九州国際会議場 (北九州)
    • Related Report
      2013 Research-status Report
  • [Presentation] レーザー光照射による金ナノ粒子の凝集・溶融過程の制御

    • Author(s)
      東 優磨, 辻 剛志, 辻 正治, 石川善恵, 越崎直人
    • Organizer
      レーザー学会学術講演会第34回年次大会
    • Place of Presentation
      北九州国際会議場 (北九州)
    • Related Report
      2013 Research-status Report
  • [Presentation] 原料ナノ粒子の表面修飾による金サブミクロン球状粒子生成過程の制御

    • Author(s)
      辻 剛志, 東 優磨, 辻 正治, 石川善恵, 越崎直人
    • Organizer
      東京工業大学応用セラミックス研究所共同利用研究ワークショップ
    • Place of Presentation
      東京工業大学田町キャンパス (東京)
    • Related Report
      2013 Research-status Report
  • [Presentation] 液中レーザーアブレーションを用いた表面修飾ナノ粒子の作製と形状制御

    • Author(s)
      辻 剛志, 東 優磨, 辻 正治, 石川 善恵, 越崎 直人
    • Organizer
      第80回レーザー加工学会
    • Place of Presentation
      東京大学生産科学研究所 (東京)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] レーザー光照射による金ナノ粒子の凝集-溶融過程の制御とサブミクロン球状粒子の作製

    • Author(s)
      辻 剛志, 矢羽田 達也, 安友 政登, 辻 正治, 井川 和宣, 石川 善恵, 越崎 直人
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学 (名古屋)
    • Related Report
      2013 Research-status Report
  • [Presentation] レーザー光照射による金ナノ粒子の凝集・溶融過程の制御

    • Author(s)
      辻 剛志, 東 優磨, 矢羽田 達也, 辻 正治, 井川 和宣, 石川 善恵, 越崎 直人
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学文教キャンパス (松山)
    • Related Report
      2013 Research-status Report
  • [Presentation] 液中レーザー溶融法による真球状サブミクロン金粒子の作製

    • Author(s)
      東 優磨, 辻 剛志, 辻 正治, 石川 善恵, 越崎 直人
    • Organizer
      第2回レーザー学会九州支部学生講演会
    • Place of Presentation
      武雄温泉ホテル (武雄)
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of Spherical Particles Using Laser-induced Melting of Submicron-sized Materials

    • Author(s)
      Tsuji T, Higashi Y, Tsuji M, Fujiwara H, Ishikawa Y, Koshizaki N
    • Organizer
      The 14th International Symposium on Laser Precision Microfabrication
    • Place of Presentation
      朱鷺メッセ (新潟)
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication and application of submicronspherical particles prepared by pulsed laser melting in liquid

    • Author(s)
      Koshizaki N, Ishikawa I, Pyatenko A, Katou Y, Tsuji T
    • Organizer
      The 14th International Symposium on Laser Precision Microfabrication
    • Place of Presentation
      朱鷺メッセ (新潟)
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of Spherical-Shaped Submicron Particles of ZnO Using Laser-induced Melting of Submicron-sized Source Materials.

    • Author(s)
      Higashi Y, Tsuji T, Tsuji M, Fujiwara H, Koshizaki N, Ishikawa Y
    • Organizer
      The 10th Conference on Lasers and Electro-Optics Pacific Rim
    • Place of Presentation
      京都国際会議場 (京都)
    • Related Report
      2013 Research-status Report
  • [Presentation] Fabrication of Submicron-sized Spherical Particles Using Laser-induced Agglomeration and Fusion of Nanoparticles

    • Author(s)
      Tsuji T, Yahata T, Yasutomo M, Tsuji M, Koshizaki N, Ishikawa Y
    • Organizer
      The 10th Conference on Lasers and Electro-Optics Pacific Rim
    • Place of Presentation
      京都国際会議場 (京都)
    • Related Report
      2013 Research-status Report
  • [Remarks] http://www.ipc.shimane-u.ac.jp/physchem-ii/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 島根大学総合理工学部物質科学科化学分野 物理化学(2)研究室

    • URL

      http://www.ipc.shimane-u.ac.jp/physchem-ii/index.html

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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