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Creation of electroactive function in single crystals of calcium aluminate electrides by element doping

Research Project

Project/Area Number 25420708
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionUniversity of Yamanashi

Principal Investigator

TANAKA Isao  山梨大学, 総合研究部, 教授 (40155114)

Research Collaborator WATAUCHI Satoshi  
NAGAO Masanori  
KAKIZAWA Kota  
YAMADA Mizuki  
ALI Md Mozahar  
MARUYAMA Erika  
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsアルミン酸カルシウム / 単結晶育成 / FZ法 / エレクトライド / C12A7 / 固溶限界 / 分配係数 / ブリッジマン法
Outline of Final Research Achievements

To aim development of transparent conductors and high-efficiency electron emitters without rear metals such as indium, high quality bulk single crystals of transition metal or rear-earth metal doped calcium aluminate C12A7 were grown, and the element-doping effects on the electrical properties in the electrides prepared using the grown crystals were investigated.
As the results, crystal growth by the traveling solvent floating zone (TSFZ) method with control of solid-liquid interface led to control dopant concentration in single crystals of transition metal or rear-earth metal doped C12A7. It was found that the rear-earth metal doping is effective on improvement of electrical conductivity in C12A7 electrides even though the solubility into C12A7 is very low.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (12 results)

All 2016 2015 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 2 results) Remarks (2 results)

  • [Journal Article] Crystal Growth and Characterization of Ca12Al14O33 (12CaO・7Al2O3) Doped with Transition-metal Elements (Mn, Fe, Co, Ni and Cu)2014

    • Author(s)
      Satoshi Watauchi, Takumi Shimomura, Minako Yamanaka, Isao Tanaka
    • Journal Title

      Journal of Flux Growth

      Volume: 9 Pages: 11-13

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Floating zone growth and characterization of 12(Ca1-xLnxO)・7Al2O3 (Ln3+ = Y3+, Ho3+, Nd3+, Eu3+) single crystals.2016

    • Author(s)
      Md Mozahar Ali, Masanori Nagao, Satoshi Watauchi, Isao Tanaka
    • Organizer
      第18回結晶成長国際会議
    • Place of Presentation
      名古屋国際会議場 (愛知県・名古屋市)
    • Year and Date
      2016-08-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystal growth of Cu-substituted Mayenite single crystals by the FZ method using the mirror-tilted type furnace2015

    • Author(s)
      Erika Maruyama, Masanori Nagao, Satoshi Watauchi, Isao Tanaka
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaiian Convention Center (Honolulu, USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 銅置換Mayenite単結晶のTSFZ 育成と熱電特性評価2015

    • Author(s)
      丸山恵李佳,Md Mozahar Ali,土屋寛太郎,丸山恵史,森孝雄,長尾雅則,綿打敏司,田中功
    • Organizer
      第10回日本フラックス成長研究発表会
    • Place of Presentation
      信州大学 (長野県・長野市)
    • Year and Date
      2015-12-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] ミラ-傾斜型集光炉を用いたTSFZ法による銅置換Mayenite単結晶育成2015

    • Author(s)
      丸山 恵李佳, 長尾 雅則, 綿打 敏司, 田中 功
    • Organizer
      第45回結晶成長国内会議
    • Place of Presentation
      北海道大学 (北海道・札幌市)
    • Year and Date
      2015-10-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Floating zone growth and characterization of 12CaxM1-xO・7Al2O3(M=Y3+, Eu3+, Ho3+ and Nd3+)single crystals2015

    • Author(s)
      Md Mozahar Ali, Masanori Nagao, Satoshi Watauchi, Isao Tanaka
    • Organizer
      第 28 回日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      富山大学 (富山県・富山市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 銅置換C12A7単結晶のFZ育成におけるミラー形状の影響2014

    • Author(s)
      丸山恵李佳, 長尾雅則, 綿打敏司, 田中 功
    • Organizer
      第9回日本フラックス成長研究発表会
    • Place of Presentation
      高知大学
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Research-status Report
  • [Presentation] ブリッジマン法によるC12A7エレクトライド結晶の育成2014

    • Author(s)
      山田瑞紀, 長尾雅則, 綿打敏司, 田中功
    • Organizer
      第27回日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 固液界面形状制御による銅置換アルミン酸カルシウム単結晶の高品質化2013

    • Author(s)
      田中 功,柿澤 浩太,長尾 雅則,綿打 敏司
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学工学部
    • Related Report
      2013 Research-status Report
  • [Presentation] FZ growth and electride preparation of Cu-substituted mayenite single crystals2013

    • Author(s)
      Kota Kakizawa, Masanori Nagao, Satoshi Watauchi, Isao Tanaka
    • Organizer
      International Symposium on Inorganic and Environmental Materials 2013 (ISIEM 2013)
    • Place of Presentation
      University of Rennes 1, France
    • Related Report
      2013 Research-status Report
  • [Remarks] 山梨大学研究者総覧

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispInfo.Scholar/4_3_20/A7C97FEAF2387814.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
  • [Remarks] 山梨大学研究者総覧

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispInfo.Scholar/4_3_20/A7C97FEAF2387814.html

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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