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Entire process view for film formation by chemical vapor deposition

Research Project

Project/Area Number 25420772
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionYokohama National University

Principal Investigator

Habuka Hitoshi  横浜国立大学, 工学(系)研究科(研究院), 教授 (40323927)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywords化学気相堆積 / 圧電性結晶振動子 / その場評価技術
Outline of Final Research Achievements

In order to develop the technique for understanding the entire view of the chemical vapor deposition process including the transport phenomena and the chemical reaction, the piezoelectric crystal microbalance (langasite crystal microbalance, LCM) was used. By means of measuring the wide conditions of gas density and gas viscosity in the temperature range from room temperature to high temperatures, the function for describing the LCM frequency during such the process was obtained and verified. Next, the frequency change caused due to the introduction of precursors was measured and analyzed. The lowest temperature for initiating the surface chemical reaction was identified and verified by the macroscopic film deposition. Finally, by this measurement, the transient processes till achieving the thermal steady state was classified. The temperature change due to the reaction heat and that due to the heat capacity had different time constant.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (14 results)

All 2016 2015 2014 2013 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results)

  • [Journal Article] In Situ Measurement for Evaluating Temperature Change Related to Silicon film Formation in a SiHCl3-H2 System2016

    • Author(s)
      Kento Miyazaki, Ayumi Saito and Hitoshi Habuka
    • Journal Title

      ECS Journal of Solid State Science and Technology

      Volume: 5 Issue: 2 Pages: P16-P20

    • DOI

      10.1149/2.0101602jss

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] In-situ Observation of Chemical Vapor Deposition Using SiHCl3 and BCl3 Gases2015

    • Author(s)
      Ayumi Saito, Kento Miyazaki, Misako Matsui and Hitoshi Habuka
    • Journal Title

      Physica Status Solidi C

      Volume: 12 Issue: 7 Pages: 953-957

    • DOI

      10.1002/pssc.201510002

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] In-Situ Monitoring of Chemical Vapor Deposition from Trichlorosilane Gas and Monomethylsilane Gas Using Langasite Crystal Microbalance2013

    • Author(s)
      Hitoshi Habuka and Yurie Tanaka
    • Journal Title

      Journal of Surface Engineered Materials and Advanced Technology

      Volume: 3 Issue: 01 Pages: 61-66

    • DOI

      10.4236/jsemat.2013.31a009

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Langasite Crystal Microbalance Frequency Behavior over Wide Gas Phase Conditions for Chemical Vapor Deposition2013

    • Author(s)
      Hitoshi Habuka and Misako Matsui
    • Journal Title

      Surface and Coatings Technology

      Volume: 230 Pages: 312-315

    • DOI

      10.1016/j.surfcoat.2013.06.052

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] CVD装置内熱挙動のランガサイト結晶振動子によるその場測定2015

    • Author(s)
      宮崎賢都, 齋藤 あゆ美, 松井美沙子, 羽深 等
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋(名古屋国際会議場)
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] In-situ observation of chemical vapor deposition using SiHCl3 and BCl3 Gases2015

    • Author(s)
      Ayumi Saito, Kento Miyazaki, Misako Matsui, and Hitoshi Habuka
    • Organizer
      EuroCVD20
    • Place of Presentation
      Sempach, Switzerland
    • Year and Date
      2015-07-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hitoshi HabukaAtmospheric Pressure Chemical Vapor Deposition Observed by Langasite Crystal Microbalance2015

    • Author(s)
      Hitoshi Habuka
    • Organizer
      BIT’s 4th Annual World Congress of Advanced Materials-2015
    • Place of Presentation
      Chongqing, China
    • Year and Date
      2015-05-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In-Situ Observation of Chemical vapor deposition Using Langasite Crystal Microbalance2014

    • Author(s)
      Hitoshi Habuka
    • Organizer
      Collaborative Conference on Crystal Growth 3CG 2014
    • Place of Presentation
      Holyday Inn. Phuket, Thailand
    • Year and Date
      2014-11-03
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ランガサイト結晶振動子を用いたその場測定によるSiHCl3-BCl3混合系化学気相堆積の観察2014

    • Author(s)
      齋藤 あゆ美, 宮崎賢都, 松井美沙子, 羽深 等
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学、札幌
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Langasite Crystal Microbalance for In-Situ Monitor of Chemical Vapor Deposition2014

    • Author(s)
      Hitoshi Habuka
    • Organizer
      IUMRS-ICA2014
    • Place of Presentation
      福岡大学,福岡市
    • Year and Date
      2014-08-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ランガサイト結晶振動子による化学気相堆積プロセス測定法(1)

    • Author(s)
      松井美沙子, 齋藤 あゆ美、羽深 等
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都府)
    • Related Report
      2013 Research-status Report
  • [Presentation] ランガサイト結晶振動子による化学気相堆積プロセス測定法(2)

    • Author(s)
      松井美沙子, 羽深 等
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学(京都府)
    • Related Report
      2013 Research-status Report
  • [Presentation] Method for Determining Chemical Vapor Deposition Occurrence Using Langasite Crystal Microbalance

    • Author(s)
      Hitoshi Habuka, Misako Matsui and Ayumi Saito
    • Organizer
      17th International Conference of Crystal Growth and Epitaxy
    • Place of Presentation
      Univ. Warsaw (Warsaw, Poland)
    • Related Report
      2013 Research-status Report
  • [Presentation] Langasite crystal microbalance frequency behavior over wide gas phase conditions for chemical vapor deposition

    • Author(s)
      Hitoshi Habuka* and Misako Matsui
    • Organizer
      EuroCVD19
    • Place of Presentation
      Varna (Bulgaria)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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