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Establishment of carbon nanotube-tubing method for formation of pure metal nanoparticles

Research Project

Project/Area Number 25600024
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionMie University

Principal Investigator

KOSHIO Akira  三重大学, 工学(系)研究科(研究院), 助教 (70362358)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsカーボンナノチューブ / 金属ナノ粒子 / アーク放電 / 金属内包カーボンナノチューブ / 樹脂
Outline of Final Research Achievements

Novel method of formation for metal nanoparticles were studied via one of the fruitful property we had recently found, elution of metal encapsulated in carbon nanotubes (CNTs) at low temperature. We found that composite films of copper-encapsulated CNTs and resins had visible absorption at about 590 nm of the maximum absorption wavelength. Moreover, the maximum absorption wavelength of heat treated samples indicated small blue shift of about 5 nm compared to samples without heat treatment. The absorption result was consistent in the temperature region of copper nanoparticle formation outside CNTs observed by electron microscopy.
Furthermore, we succeeded in formation of copper-titanium and copper-germanium alloy-encapsulated CNTs in high efficiency and encapsulation rate on the same degree with copper-encapsulated CNTs. The elution temperature of these alloy-encapsulated CNTs were lower than that of copper-encapsulated CNTs about 200°C.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (10 results)

All 2015 2014 2013

All Presentation (7 results) Patent(Industrial Property Rights) (3 results)

  • [Presentation] Formation of carbon nanotubes filled with Cu-binary alloys and elution of encapsulated metals at low temperature2015

    • Author(s)
      Akira Koshio, Yusaku Kuwata, Takahiro Hashii, Fumio Kokai
    • Organizer
      The Sixteenth International Conference on the Science and Application of Nanotubes
    • Place of Presentation
      Nagoya University (Nagoya, Japan)
    • Year and Date
      2015-06-29 – 2015-07-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photoluminescence of Carbon Nanoparticles Produced by Arc Discharge in CO22015

    • Author(s)
      Akira Koshio, Hiromi Katayama, Kazu Takemura, Fumio Kokai
    • Organizer
      9th International Conference on New Diamond and Nano Carbons
    • Place of Presentation
      Shizuoka GRANSHIP (Shizuoka, Japan)
    • Year and Date
      2015-05-24 – 2015-05-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] CuTi内包カーボンナノチューブの形成と内包金属の低温溶出2015

    • Author(s)
      桑田裕作, 小塩明, 小海文夫
    • Organizer
      ナノ学会第13回大会
    • Place of Presentation
      東北大学片平さくらホール(仙台)
    • Year and Date
      2015-05-11 – 2015-05-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] アーク放電法により作製した炭素ナノ粒子のフォトルミネッセンス2014

    • Author(s)
      片山広海, 武村和, 小塩明, 小海文夫
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      大野城まどかぴあ(福岡県大野城市)
    • Year and Date
      2014-12-08 – 2014-12-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photoluminescence of carbon nanoparticles produced by arc discharg2014

    • Author(s)
      Hiromi Katayama, Akira Koshio, Fumio Kokai
    • Organizer
      The 4th International Symposium for Sustainability by Engineering at MIU (IS2EMU2014)
    • Place of Presentation
      Mie University (Mie, Japan)
    • Year and Date
      2014-11-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structural changes of carbon nanotubes filled with copper by acid treatment2013

    • Author(s)
      Takashi Miyabayashi, Akira Koshio, Fumio Kokai
    • Organizer
      The 3rd International Symposium for Sustainability by Engineering at MIU
    • Place of Presentation
      Mie University (Mie, Japan)
    • Related Report
      2013 Research-status Report
  • [Presentation] 壊して調べてナノカーボンを知る2013

    • Author(s)
      小塩明
    • Organizer
      ナノマテリアル研究の新潮流と展望
    • Place of Presentation
      名古屋大学野依記念物質科学研究館(名古屋市)
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] カーボンナノチューブ組成物、及び、カーボンナノチューブ膜2014

    • Inventor(s)
      杉岡卓央、小川賢、小塩明、冨谷利信、橋井崇浩、小海文夫
    • Industrial Property Rights Holder
      株式会社日本触媒
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 金属内包カーボンナノチューブ及びカーボンナノチューブ膜2014

    • Inventor(s)
      杉岡卓央、小川賢、小塩明、橋井崇浩、小海文夫
    • Industrial Property Rights Holder
      株式会社日本触媒
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] ゲルマニウムナノワイヤーの製造方法2014

    • Inventor(s)
      杉岡卓央、小川賢、小塩明、橋井崇浩、小海文夫
    • Industrial Property Rights Holder
      株式会社日本触媒
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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