| Project/Area Number |
25620051
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Functional solid state chemistry
|
|---|
| Research Institution | Hokkaido University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
OGASAWARA Masamichi 北海道大学, 触媒化学研究センター, 准教授 (70301231)
|
|---|
| Project Period (FY) |
2013-04-01 – 2015-03-31
|
| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
|---|
| Keywords | アセン / メタロセン / 閉環メタセシス / 縮環 / フェロセン / インデニル / フルオレニル / 架橋 / メタセシス / 閉環反応 / ルテニウム |
|---|
| Outline of Final Research Achievements |
Synthesis of the hybrid molecules between polyacenes, which are linearly-fused polycyclic benzenoide aromatic compounds, and metallocenes, which are transition-metal-containing aromatic compounds, was examined. As a metallocene scaffold, ferrocene was chosen because of its chemical stability and easier handling, and the construction of acene moieties within the coordination-spheres of ferrocenes was examined.
Introduction of two allylic substituents at the adjacent positions of a single Cp ligand in ferrocene, and treatment of the prepared ferrocene derivative with the Grubbs catalyst facilitated the ring-closing metathesis reaction to give the corresponding dihydroindenyl compound in nearly quantitative yield. Application of a similar reaction to decaallylferrocene gave single-bridged bis(tetrahydrofluorenyl)iron(II) species in high yield via five-fold ring-closing metathesis within a single molecule.
|
