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Chiral conjugated molecules leading to emegence of intrinsic circularly polarized luminescence features

Research Project

Project/Area Number 25620068
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionTokyo University of Science (2014-2015)
National Institute for Materials Science (2013)

Principal Investigator

FURUMI SEIICHI  東京理科大学, 理学部, 准教授 (30391220)

Co-Investigator(Renkei-kenkyūsha) TAKEUCHI Masayuki  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点・分子機能化学グループ, グループリーダー (70264083)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsキラリティー / 円偏光発光 / 共役系化合物 / エネルギー移動 / 白色発光 / 光弾性変調器
Outline of Final Research Achievements

This research project aims at the emergence of intrinsic circularly polarized luminescence (CPL) features from chiral conjugated molecules. For this purpose, we constructed an original optical system to enable precise measurement of CPL spectra from the chiral conjugated molecules. We succeeded in the measurement of CPL spectra by combining both photoelastic modulators (PEM) and excitation laser. We will demonstrate the precise CPL spectral measurements of chiral conjugated molecules at various situations such as solid-state crystals or films through our original optical measurement system.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (26 results)

All 2016 2015 2014 2013 Other

All Journal Article (11 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 1 results) Presentation (11 results) (of which Invited: 7 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Thermotropic Properties of Cholesteric Liquid Crystal from Hydroxypropyl Cellulose Mixed Esters2015

    • Author(s)
      T. Ishizaki, S. Uenuma and S. Furumi
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 72 Issue: 12 Pages: 737-745

    • DOI

      10.1295/koron.2015-0029

    • NAID

      130005115701

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Colloidal Crystallization and Ionic Liquid Induced Partial β-Phase Transformation of Poly(Vinylidene Fluoride) Nanoparticles2015

    • Author(s)
      Daichi Okada, Hideki Kaneko, Katsuhiro Kato, Seiichi Furumi, Masaki Takeguchi, Yohei Yamamoto
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 8 Pages: 2570-2575

    • DOI

      10.1021/acs.macromol.5b00337

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis, Crystal Structure, and Photophysical Properties of a 1,1’-Bitriphenylene-Based Sila[7]helicene2015

    • Author(s)
      K. Murayama, Y. Oike, S. Furumi, M. Takeuchi, K. Noguchi, K. Tanaka
    • Journal Title

      European Journal of Organic Chemistry

      Volume: 2015 Issue: 7 Pages: 1409-1414

    • DOI

      10.1002/ejoc.201403565

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] 高分子とコロイド結晶の複合化で波長可変レーザーをつくる2015

    • Author(s)
      古海 誓一
    • Journal Title

      NEWTON

      Volume: 35 Pages: 4-4

    • Related Report
      2015 Annual Research Report
  • [Journal Article] 研究室紹介 東京理科大学 理学部第一部 応用化学科 古海研究室2015

    • Author(s)
      古海 誓一
    • Journal Title

      液晶

      Volume: 19 Pages: 168-170

    • NAID

      40020551070

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Enantioselective Synthesis and Enhanced Circularly Polarized Luminescence of S-Shaped Double Azahelicenes2014

    • Author(s)
      K. Nakamura, S. Furumi, M. Takeuchi, T. Shibuya, K. Tanaka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 15 Pages: 5555-5558

    • DOI

      10.1021/ja500841f

    • Related Report
      2014 Research-status Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Aligned 1-D Nanorods of a π-Gelator Exhibit Molecular Orientation and Excitation Energy Transport Different from Entangled Fiber Networks2014

    • Author(s)
      K. Sakakibara, P. Chithra, B. Das, T. Mori, M. Akada, J. Labuta, T. Tsuruoka, S. Maji, S. Furumi, L.K. Shrestha, J.P. Hill, Somobrata Acharya, K. Ariga, A. Ajayaghosh
    • Journal Title

      Journal of the American Chemical Society

      Volume: 136 Issue: 24 Pages: 8548-8551

    • DOI

      10.1021/ja504014k

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Tetramethylbithiophene in π-conjugated alternating copolymers as an effective structural component for the formation of spherical assemblies2014

    • Author(s)
      L. Tong, S. Kushida, J. Kuwabara, T. Kanbara, N. Ishii, A. Saeki, S. Seki, S. Furumi, and Y. Yamamoto
    • Journal Title

      Polym. Chem.

      Volume: 5 Issue: 11 Pages: 3583-3587

    • DOI

      10.1039/c4py00023d

    • Related Report
      2014 Research-status Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 高分子材料によるアクティブなフォトニック結晶レーザー2014

    • Author(s)
      古海 誓一
    • Journal Title

      セラミックス

      Volume: 49 Pages: 900-904

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Active lasing from organic colloidal photonic crystals2013

    • Author(s)
      S. Furumi
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 1 Issue: 38 Pages: 6003-6012

    • DOI

      10.1039/c3tc30704b

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Self-assembled organic and polymer photonic crystals for laser applications2013

    • Author(s)
      S. Furumi
    • Journal Title

      Polymer Journal

      Volume: 45 Issue: 6 Pages: 579-593

    • DOI

      10.1038/pj.2012.181

    • NAID

      10031174553

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ソフトな有機・高分子フォトニック結晶レーザー2016

    • Author(s)
      古海 誓一
    • Organizer
      電子情報通信学会(IEICE)・2016年電子情報通信学会総合大会 「有機光デバイス技術の最新動向(OPE、OME、PCC共催企画セッション)」
    • Place of Presentation
      九州大学
    • Year and Date
      2016-03-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 低環境負荷な半導体ナノ結晶の精密合成と高効率なフルカラーレーザー素子への応用2016

    • Author(s)
      古海 誓一
    • Organizer
      公益財団法人 中部電気利用基礎研究振興財団・平成27年度 助成研究発表会
    • Place of Presentation
      メルパルクNAGOYA
    • Year and Date
      2016-03-10
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機・高分子材料によるソフト・チューナブルレーザーの創製2015

    • Author(s)
      古海 誓一
    • Organizer
      北海道大学 電子科学研究所・物質・デバイス領域共同研究拠点事業 第12回スマート分子材料講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 発光性CuInS2/ZnSナノ結晶の合成と評価2015

    • Author(s)
      本田 智士・保坂 眞・青井 遼・大西 耀・古海 誓一
    • Organizer
      日本MRS・第25回 日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] コロイドフォトニック結晶のレーザーへの応用展開2015

    • Author(s)
      古海 誓一
    • Organizer
      公益財団法人 科学技術交流財団・コロイドマテリアル応用化研究会
    • Place of Presentation
      科学技術交流財団 研究交流センター
    • Year and Date
      2015-10-28
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 単分散シリカ微粒子の精密合成とコロイド結晶への展開2015

    • Author(s)
      山本 諒・大野 工司・古海 誓一
    • Organizer
      日本化学会・第66回 コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] コレステリル基を導入したセルロース誘導体による液晶の発現と特性2015

    • Author(s)
      石崎 拓郎・古海 誓一
    • Organizer
      日本液晶学会・2015年 日本液晶学会討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] セルロース誘導体によるコレステリック液晶の発現2015

    • Author(s)
      石﨑 拓郎・上沼 駿太郎・古海 誓一
    • Organizer
      高分子学会・第64回 年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 自己組織化による有機・高分子フォトニック結晶の構築とレーザーへの応用2014

    • Author(s)
      古海 誓一
    • Organizer
      2014 KIPS若手高分子シンポジウム
    • Place of Presentation
      京都大学 桂キャンパス
    • Year and Date
      2014-12-12
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] オパールを模倣したナノ周期配列構造によるソフトな高分子レーザー2014

    • Author(s)
      古海 誓一
    • Organizer
      積水化学 自然に学ぶものづくりフォーラム
    • Place of Presentation
      イイノホール
    • Year and Date
      2014-10-16
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Active Organic Photonic Crystal Lasers by Self-assembly2014

    • Author(s)
      Seiichi Furumi
    • Organizer
      2014 Tsukuba Nanotechnology Symposium (TNS'14)
    • Place of Presentation
      Univ. Tsukuba
    • Year and Date
      2014-07-25 – 2014-07-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Book] Organic and Hybrid Photonic Crystals2015

    • Author(s)
      S. Furumi
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report
  • [Book] 技術シーズを活用した研究開発テーマの発掘2013

    • Author(s)
      澤田 勉, 不動寺 浩, 古海 誓一, 迫田 和彰
    • Total Pages
      5
    • Publisher
      技術情報協会
    • Related Report
      2013 Research-status Report
  • [Remarks] webページ

    • URL

      http://www.tus.ac.jp/fac_grad/p/index.php?69b1

    • Related Report
      2015 Annual Research Report
  • [Remarks] 所属機関が作成したwebページ

    • URL

      http://www.tus.ac.jp/fac_grad/p/index.php?69b1

    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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