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Development of glass ceramic materials containing 3d transition metal ions with anomalous valence for super broadband optical amplifiers

Research Project

Project/Area Number 25620184
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionKyoto University

Principal Investigator

TANABE Setsuhisa  京都大学, 人間・環境学研究科(研究院), 教授 (20222119)

Research Collaborator ZHUANG Yixi  京都大学, 大学院人間・環境学研究科
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords遷移金属 / 蛍光 / 結晶化ガラス / 光通信 / 光増幅器 / 異常原子価 / ガラス / 光ファイバ
Outline of Final Research Achievements

Transparent glass ceramics doped with 3d transition metal ions were developed forsuper broadband optical amplifier. In order to achieve broad luminescence in telecommunication wavalength, glass ceramics precipitated with nanocrystals containing Cr4+ ions, anormalous valence were fabricated. From XRD, various glass ceramics containing either Mg2SiO4 or Li2ZnSiO4 were developed in which tetravalent Cr with d2 configuration are stabilized at tetrahedral sites.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (23 results)

All 2015 2014 2013 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Open Access: 5 results,  Acknowledgement Compliant: 5 results) Presentation (13 results) (of which Invited: 2 results) Remarks (1 results)

  • [Journal Article] Deep-red persistent luminescence in Cr3+-doped LaAlO3 perovskite phosphor for in vivo imaging2015

    • Author(s)
      Y. Katayama, H. Kobayashi, S. Tanabe
    • Journal Title

      Applied Physics Express

      Volume: 8 Issue: 1 Pages: 012102-012102

    • DOI

      10.7567/apex.8.012102

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Multi-color persistent luminescence in transparent glass ceramics containing spinel nano-crystals with Mn2+ ions2014

    • Author(s)
      Y. Zhuang, J. Ueda, S. Tanabe
    • Journal Title

      Appl. Phys. Lett.

      Volume: 105 Issue: 19

    • DOI

      10.1063/1.4901749

    • NAID

      120005522499

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Wavelength tailorability of broadband near-infrared luminescence in Cr4+-activated transparent glass-ceramics2014

    • Author(s)
      Y. Zhuang, S. Tanabe, J. Qiu
    • Journal Title

      J. Am. Ceram. Soc.

      Volume: 97 Issue: 11 Pages: 3519-3523

    • DOI

      10.1111/jace.13128

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] A brief review on red to near-infrared persistent luminescence in transition-metal-activated phosphors2014

    • Author(s)
      Y. Zhuang, Y. Katayama, J. Ueda, S. Tanabe
    • Journal Title

      Opt. Mater.

      Volume: 36 Issue: 11 Pages: 1907-1912

    • DOI

      10.1016/j.optmat.2014.05.035

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Band-gap variation and a self-redox effect induced by compositional deviation in ZnxGa2O3+x:Cr3+ persistent phosphors2014

    • Author(s)
      Y. Zhuang, J. Ueda, S. Tanabe, P. Dorenbos
    • Journal Title

      J.Mater.Chem.C

      Volume: 2 Issue: 28 Pages: 5502-5509

    • DOI

      10.1039/c4tc00369a

    • NAID

      120005623265

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effect of Bi_2O_3 doping on persistent luminescence of MgGeO_3 : Mn^(2+) phosphor2014

    • Author(s)
      Y. Katayama, J. Ueda, S. Tanabe
    • Journal Title

      Optical Materials Express

      Volume: 4 Issue: 4 Pages: 613-623

    • DOI

      10.1364/ome.4.000613

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Tunable trap depth in Zn (Gal xAlx) 204 : Cr, Bi red persistent phosphors : considerations of high temperature nersistent luminescence and photostimulated persistent luminescence2013

    • Author(s)
      Y. Zhuang. J. Ueda, S. Tanabe
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 1 Issue: 47 Pages: 7849-7855

    • DOI

      10.1039/c3tc31462f

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Conversion of valence state and coordination state of Fe in transparent glass-ceramics containing Li2ZnSiO4 nanocrystals2013

    • Author(s)
      Y. Zhuang, S. Tanabe
    • Journal Title

      Journal of the American Ceramics Society

      Volume: 96 Issue: 9 Pages: 2864-2869

    • DOI

      10.1111/jace.12398

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhancement of red persistent luminescence in Cr3+-doped ZnGa204 phosphors by Bi203 codoping2013

    • Author(s)
      Y. Zhuang, J. Ueda, S. Tanabe
    • Journal Title

      Applied Physics Express

      Volume: 6 Issue: 5 Pages: 52602-52602

    • DOI

      10.7567/apex.6.052602

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] LaAlO3:Cr3+ペロブスカイト蛍光体の深赤色長残光特性2015

    • Author(s)
      ○片山裕美子、小林大晃、田部勢津久
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大湘南キャンパス(平塚市)
    • Year and Date
      2015-03-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Eu3+をトラップ増感剤とした新規赤色Mn残光蛍光体(ZnyMg1-y)GeO3:Mn2+-Eu3+の光学特性評価2015

    • Author(s)
      ○家弓朋広、片山裕美子、上田純平、田部勢津久
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大湘南キャンパス(平塚市)
    • Year and Date
      2015-03-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Mn 添加透明結晶化ガラスの作製と発光色変化2015

    • Author(s)
      庄逸煕、○田部勢津久
    • Organizer
      The 25th Meeting on Glasses for Photonics~新しいフォトニクス部品とガラス材料との接点~
    • Place of Presentation
      東京
    • Year and Date
      2015-01-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Optical properties of MgGeO3:Mn2+, Ln3+(Ln=Yb, Eu)2014

    • Author(s)
      T. Kayumi, Y. Katayama, J. Ueda, S. Tanabe
    • Organizer
      第55回ガラスおよびフォトニクス材料討論会と第10 回ガラス技術シンポジウム
    • Place of Presentation
      東工大大岡山キャンパス
    • Year and Date
      2014-11-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Mn-Bi 共添加MgGeO3蛍光体における赤色長残光機能発現2014

    • Author(s)
      ○片山裕美子、上田純平、田部勢津久
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス (横浜)
    • Related Report
      2013 Research-status Report
  • [Presentation] 赤色長残光を示すCr添加透明結晶化ガラスの作製と光学特性評価2014

    • Author(s)
      ○松崎乃里子、庄逸煕、上田純平、田部勢津久
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス (横浜)
    • Related Report
      2013 Research-status Report
  • [Presentation] Broadband near-infrared luminescence in Cr4+-activated transparent glass ceramics2013

    • Author(s)
      ○Y. Zhuang, S. Tanabe
    • Organizer
      第54回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      産業技術総合研究所 関西センター(池田)
    • Related Report
      2013 Research-status Report
  • [Presentation] Red persistent and photostimulable phosphors for bio-imaging (基調講演)2013

    • Author(s)
      ○S. Tanabe, Y. Katayama
    • Organizer
      The 2nd International Workshop on Persistent and Photostimulable Phosphors
    • Place of Presentation
      華南理工大学 (広州、中国)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Tunable trap depth in Zn(Ga1-xAlx)2O4:Cr,Bi red persistent phosphors: considerations of high-temperature persistent lumines cence and photostimulated persistent luminescence2013

    • Author(s)
      ○Y. Zhuang, J. Ueda, S. Tanabe
    • Organizer
      The 2nd International Workshop on Persistent and Photostimulable Phosphors
    • Place of Presentation
      華南理工大学 (広州、中国)
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Bi doping on persistent luminescence and photo-stimulated luminescence properties of MgGeO3:Mn2013

    • Author(s)
      ○Y. Katayama, J. Ueda, S. Tanabe
    • Organizer
      International Workshop on Luminescent Materials 2013 (LumiMat'13)
    • Place of Presentation
      京都大学芝蘭会館別館 (京都)
    • Related Report
      2013 Research-status Report
  • [Presentation] Photoconductivity and electronic structures of persistent phosphors2013

    • Author(s)
      ○S. Tanabe, J. Ueda
    • Organizer
      2013 JSAP-MRS Joint Symposia,Sympo. I:"Rare Earth Doped Advanced Materials for Photonic Applications
    • Place of Presentation
      同志社大学田辺キャンパス (京田辺)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Bi2O3添加MgGeO3:Mn蛍光体における赤色長残光特性2013

    • Author(s)
      ○片山裕美子、上田純平、田部勢津久
    • Organizer
      第35回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学田辺キャンパス (京田辺)
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Zn/Ga ratio on persistent luminescence in Bi or/and Cr doped ZnGa2O4 phosphors2013

    • Author(s)
      ○Y. Zhuang, S. Tanabe
    • Organizer
      10th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 10)
    • Place of Presentation
      Hotel Del Coronado (San Diego, USA)
    • Related Report
      2013 Research-status Report
  • [Remarks] 京都大学 人間・環境学研究科 田部研究室

    • URL

      http://www.talab.h.kyoto-u.ac.jp/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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