| Project/Area Number |
25660086
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Bioorganic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
FUKUSHI YUKIHARU 北海道大学, (連合)農学研究科(研究院), 准教授 (60218906)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | キラル誘導体化試薬 / 官能基導入 / 9,10-ethanoanthracene / 立体選択的ラジカル反応 / 遠隔位 / ジアステレマー分離 / 遠隔位官能基化試薬 / NMR解析 / 遠隔位官能基導入 / 9,10-Ethanoanthracene / 選択的ラジカル反応 / ジアステレオマー分離 / 立体選択性 / 芳香族環 |
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| Outline of Final Research Achievements |
A study to create new remote-functionalization reagents has been done, however, isn’t complete yet. A new simple method to synthesize cis-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene was invented in the process. The diamine forms a condensed heterocyclic compound after monoimidation, followed by acylation reaction. On the contrary, monoamides and diamides are produced from the same diamine. Hereafter, these diamides or new amide-esters will be candidates for the new reagents.
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