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Mechanical and Separation Properties of Nanoporous Thin Carbon Membranes

Research Project

Project/Area Number 25708035
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypePartial Multi-year Fund
Research Field Polymer/Textile materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

FUJII Yoshihisa  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主任研究員 (70578062)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥23,010,000 (Direct Cost: ¥17,700,000、Indirect Cost: ¥5,310,000)
Fiscal Year 2015: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2014: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
Fiscal Year 2013: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsカーボン / 分離膜 / ナノ薄膜 / 構造・物性 / 傾斜構造 / 架橋高分子 / 粘弾性 / 膨潤 / プラズマCVD / 高分子 / 薄膜
Outline of Final Research Achievements

Polymer-based membranes are widely used for gas separation, filtration, desalination of seawater, wastewater treatment, etc. Chemical, petrochemical, energy and environment-related industries, however, strongly require highly durable membranes applicable under extreme conditions, since the present polymeric membranes gradually deteriorate with time due to undesired swelling, clogging, and chemical reactions. At present, a widely used technique for diamond-like carbon (DLC) deposition is plasma chemical vapor deposition (CVD) using organic compounds. In the plasma CVD of organic compounds, a highly cross-linked network of sp3 carbons is obtained under certain conditions, resulting in thin carbon films with mechanical stability comparable to that of diamond. Recently, we successfully prepared nanoporous DLC membranes which exhibited extremely high permeability to water and organic solvents while maintaining a considerable degree of mechanical strength.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (22 results)

All 2016 2015 2014 2013

All Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results) Presentation (11 results) (of which Invited: 3 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 1 results)

  • [Journal Article] Hydrophobized Plant Polyphenol: Self-Assembly and Promising Antibacterial, Adhesive, and Anticorrosion Coatings2016

    • Author(s)
      Debabrata Payra, Masanobu Naito, Yoshihisa Fujii, Yuki Nagao
    • Journal Title

      Chemical Communications

      Volume: 52 Issue: 2 Pages: 312-315

    • DOI

      10.1039/c5cc07090b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoprecipitation for Ultrafiltration Membranes2015

    • Author(s)
      •Q. Wang, S. Samitsu, Y. FUJII, C. Yoshikawa, T. Miyazaki, H. Banno, I. Ichinose
    • Journal Title

      J. Polym. Sci. Pt. B-Polym. Phys.

      Volume: 53 Issue: 9 Pages: 615-620

    • DOI

      10.1002/polb.23688

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Confinement Effect on the Effective Viscosity of Plasticized Polymer Films2015

    • Author(s)
      Fei Chen, Dongdong Peng, Yudai Ogata, Keiji Tanaka, Zhaohui Yang, Yoshihisa Fujii, Norifumi L. Yamada, Chi-hang Lam, Ophelia K. C. Tsui
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 20 Pages: 7719-7726

    • DOI

      10.1021/acs.macromol.5b01780

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bioinspired adhesive polymer coatings for efficient and versatile corrosion resistance2015

    • Author(s)
      Debabrata Payra, Masanobu Naito, Yoshihisa Fujii, Norifumi L. Yamada,
    • Journal Title

      RSC Advances

      Volume: 5 Pages: 15977-15984

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrophilic Polymer Nanofibre Networks for Rapid Removal of Aromatic Compounds from Water2014

    • Author(s)
      Mohan Raj Krishnan, Sadaki Samitsu, Yoshihisa Fujiia and Izumi Ichinose
    • Journal Title

      Chem. Commun

      Volume: 50 Issue: 66 Pages: 9393-9396

    • DOI

      10.1039/c4cc01786b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] DLC ろ過フィルタ2014

    • Author(s)
      藤井義久、佐光貞樹、一ノ瀬泉
    • Journal Title

      NEW DIAMOND

      Volume: 30 Pages: 35-37

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin free-standing membranes from metal hydroxide nanostrands2013

    • Author(s)
      Santanu Karan, Qifeng Wang, Sadaki Samitsu, Yoshihisa Fujii, Izumi Ichinose
    • Journal Title

      Journal of Membrane Science

      Volume: 448 Pages: 270-291

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Future Prospects of Porous Diamond-Like Carbon Membranes2013

    • Author(s)
      藤井義久、佐光貞樹、一ノ瀬泉
    • Journal Title

      MEMBRANE

      Volume: 38 Pages: 200-206

    • NAID

      130004780898

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 多孔性カーボン膜の分離特性2015

    • Author(s)
      藤井義久・佐光貞樹・一ノ瀬泉
    • Organizer
      平成27年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-06-10
    • Related Report
      2015 Annual Research Report
  • [Presentation] 多孔性ダイヤモンド状カーボン膜の分離特性2015

    • Author(s)
      藤井義久・佐光貞樹・一ノ瀬泉
    • Organizer
      平成26年度東北地区先端高分子セミナー
    • Place of Presentation
      宮城県秋保温泉 岩沼屋
    • Year and Date
      2015-03-09 – 2015-03-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Nanoporous Carbon Membranes for the Purification of Oil-Contaminated Water2014

    • Author(s)
      藤井義久・佐光貞樹・一ノ瀬泉
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, Massachusetts
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノカーボン膜の力学特性2014

    • Author(s)
      藤井義久・佐光貞樹・一ノ瀬泉
    • Organizer
      第62回レオロジー討論会
    • Place of Presentation
      福井市地域交流プラザ
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ナノ細孔を有するカーボン超薄膜の分離特性2014

    • Author(s)
      藤井義久・佐光貞樹・一ノ瀬泉
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ細孔を有するカーボン超薄膜の力学特性2014

    • Author(s)
      藤井義久・佐光貞樹・一ノ瀬泉
    • Organizer
      平成26年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2014-06-11 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ細孔を有するカーボン超薄膜の熱物性2014

    • Author(s)
      藤井義久・佐光貞樹・一ノ瀬泉
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] ダイヤモンド状カーボンでできた高性能ろ過フィルター2013

    • Author(s)
      藤井義久、佐光貞樹、一ノ瀬泉
    • Organizer
      「ナノ界面技術の基盤構築」第3回公開シンポジウム
    • Place of Presentation
      アキハバラプラザ アキバホール,秋葉原, 東京
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 多孔性ダイヤモンド状カーボン膜2013

    • Author(s)
      藤井義久、佐光貞樹、一ノ瀬泉
    • Organizer
      第11回環境研究シンポジウム
    • Place of Presentation
      一橋大学 一橋講堂, 東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] 多孔性ダイヤモンド状カーボン膜2013

    • Author(s)
      藤井義久、佐光貞樹、一ノ瀬泉
    • Organizer
      第13回 NIMSフォーラム
    • Place of Presentation
      東京国際フォーラム ホールB7,東京都
    • Related Report
      2013 Annual Research Report
  • [Presentation] ナノ細孔を有するカーボン超薄膜の力学物性2013

    • Author(s)
      藤井義久、佐光貞樹、一ノ瀬泉
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス ,金沢市
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 硬質カーボン膜製NF又はRO膜、濾過フィルター、2層接合型濾過フィルター及びそれらの製造方法2014

    • Inventor(s)
      一ノ瀬泉/藤井義久/佐光貞樹
    • Industrial Property Rights Holder
      一ノ瀬泉/藤井義久/佐光貞樹
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-11-28
    • Related Report
      2014 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 硬質カーボン膜製NF又はRO膜、濾過フィルター、2層接合型濾過フィルター及びそれらの製造方法2014

    • Inventor(s)
      一ノ瀬泉/藤井義久/佐光貞樹
    • Industrial Property Rights Holder
      一ノ瀬泉/藤井義久/佐光貞樹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-166289
    • Filing Date
      2014-08-19
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] ダイヤモンド状カーボン膜、濾過フィルター、2層接合型濾過フィルター及びそれらの製造方法2014

    • Inventor(s)
      一ノ瀬泉/藤井義久/佐光貞樹
    • Industrial Property Rights Holder
      一ノ瀬泉/藤井義久/佐光貞樹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-081284
    • Filing Date
      2014-04-10
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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