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Proton conducting coordination polymer operating over 200 degC

Research Project

Project/Area Number 25810047
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionThe University of Tokushima (2014)
Kyoto University (2013)

Principal Investigator

INUKAI Munehiro  徳島大学, ソシオテクノサイエンス研究部, 講師 (60537124)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsプロトン伝導体 / 固体電解質 / 燃料電池 / 固体NMR / プロトン伝導
Outline of Final Research Achievements

Proton conductive solids have been attracted for solid electrolyte in fuel cells. In the study, we focused on coordination polymers as a platform for proton conduction under anhydrous intermediated temperature (200-400℃). We obtained several new proton conducing coordination polymers. Among them, coordination polymers showed high thermal stability up to c.a. 200℃ or very high proton conductivity (0.01 S/cm)

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (8 results)

All 2015 2014 2013

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 1 results,  Open Access: 1 results) Presentation (4 results)

  • [Journal Article] 1.Reversible Solid-to-Liquid Phase Transition of Coordination Polymer Crystals2015

    • Author(s)
      Daiki Umeyama, Satoshi Horike, Munehiro Inukai, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 2 Pages: 864-870

    • DOI

      10.1021/ja511019u

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Study on a 2D layer coordination framework showing order-to-disorder phase transition by ionothermal synthesis.2015

    • Author(s)
      Wenqian Chen, Satoshi Horike, Munehiro Inukai, Susumu Kitagawa
    • Journal Title

      Polymer Journal

      Volume: 47 Issue: 2 Pages: 141-145

    • DOI

      10.1038/pj.2014.100

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction2014

    • Author(s)
      Satoshi Horike, Wenqian Chen, Tomoya Itakura, Munehiro Inukai, Daiki Umeyama, Hiroyuki Asakura, Susumu Kitagawa
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 71 Pages: 10241-10243

    • DOI

      10.1039/c4cc04370g

    • NAID

      120005657898

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Template-Directed Proton Conduction Pathways in a Coordination Framework2014

    • Author(s)
      Munehiro Inukai, Satoshi Horike, Wenqian Chen, Daiki Umeyama, Tomoya Itakura, Susumu Kitagawa
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 27 Pages: 10404-10409

    • DOI

      10.1039/c4ta01261e

    • NAID

      120005651931

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ゲスト分子が誘起する配位高分子のプロトン輸送能と耐熱性2013

    • Author(s)
      犬飼宗弘、堀毛悟史、梅山大樹、北川進
    • Organizer
      第39回固体イオニクス討論会
    • Place of Presentation
      くまもと県民交流館パレア
    • Related Report
      2013 Research-status Report
  • [Presentation] イオン伝導性配位高分子の開発と拡散NMR・固体NMRによる伝導機構の解明2013

    • Author(s)
      犬飼宗弘、堀毛悟史、上坪祐介、梅山大樹、北川進
    • Organizer
      第52回NMR討論会
    • Place of Presentation
      石川県立音楽堂
    • Related Report
      2013 Research-status Report
  • [Presentation] テンプレート分子の内部配列による配位高分子の高速プロトン輸送能と高耐熱性2013

    • Author(s)
      犬飼宗弘、堀毛悟史、Wenqian Chen、梅山大樹、板倉智也、北川進
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学千原キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 高耐熱性を示すプロトン伝導性配位高分子の構築2013

    • Author(s)
      犬飼宗弘、堀毛悟史、梅山大樹、北川進
    • Organizer
      第16回超イオン導電体物性研究会 第63回固体イオニクス研究会
    • Place of Presentation
      日立市日立シビックセンター
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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