| Project/Area Number |
25810117
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Organic and hybrid materials
|
|---|
| Research Institution | Nagoya University |
|---|
Principal Investigator |
HARA Mitsuo 名古屋大学, 工学(系)研究科(研究院), 助教 (10631971)
|
|---|
| Project Period (FY) |
2013-04-01 – 2015-03-31
|
| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
|
|---|
| Keywords | 有機・無機ハイブリッド / メソポーラス / 垂直配向 / リオトロピック液晶 / ゾルゲル法 / 液晶性ポリマー |
|---|
| Outline of Final Research Achievements |
An amphiphilic diblock copolymer PMEO-b-PAz, which was consist of a liquid crystalline azobenzene derivative methacrylate and an oligo(ethylene oxide) methacrylate, was synthesized by two-step atom transfer radical polymerization method. PMEO-b-PAz exhibited lyotropic liquid crystallinity in water system. In a spincast film of PMEO-b-PAz hybridized with silica or titania, a lyotropic liquid crystalline lamellar phase of the diblock copolymer aligned spontaneously perpendicular to the substrate plane due to thermal annealing process. We also attained to obtain a nanoporous metal oxide film with vertical alignment by removal of the organic component from the spincast film. Furthermore, the vertically-aligned nanoporous titania film had a potential for an anode of a dye-sensitised solar cell.
|
