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Development of inovating high-pressure and high-temperature apparatus for neutron diffraction and approaches to unsolved questions on ices and planetary sciences

Research Project

Project/Area Number 26246039
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Quantum beam science
Research InstitutionThe University of Tokyo

Principal Investigator

Kagi Hiroyuki  東京大学, 大学院理学系研究科(理学部), 教授 (70233666)

Co-Investigator(Kenkyū-buntansha) 服部 高典  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 J-PARCセンター, 研究主幹 (10327687)
町田 真一  一般財団法人総合科学研究機構(総合科学研究センター(総合科学研究室)及び中性子科学センター(研究開発, 中性子科学センター, 研究員 (30554373)
小松 一生  東京大学, 大学院理学系研究科(理学部), 准教授 (50541942)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥41,600,000 (Direct Cost: ¥32,000,000、Indirect Cost: ¥9,600,000)
Fiscal Year 2017: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2016: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2015: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2014: ¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Keywords氷 / 高圧 / 中性子回折 / 低温 / 地球化学 / 水素結合 / 量子ビーム / 惑星起源・進化 / 惑星起源・進化
Outline of Final Research Achievements

This project aims at developing a new high-pressure apparatus for measuring neutron diffraction measurements which can precisely control pressure even at low temperature conditions. The scientific target is to obtain crystal structure and physicochemical properties of high-pressure phase ices.
By combining liquid nitrogen and cryostat apparatuses, we achieved the low temperature limit down to 40 K. The apparatus enabled us to conduct neutron diffraction measurements at high pressure and low temperature regions where we could not achieve. We clarified the mechanism of salt incorporation process in ice VII which is a high pressure form of ice. Furthermore, a new model on hydrogen ordering process in iceVI was proposed.

Academic Significance and Societal Importance of the Research Achievements

氷は身近にありふれた物質であるにもかかわらず、未解決問題を多く有する奥が深い物質である。本研究では低温条件で自在に圧力を制御できる高圧発生装置を開発し、任意の条件で氷の中性子回折パターンを測定し、これまで未解決であった氷の問題②正面から取り組んだ。本研究で得られた成果は、氷の結晶構造に見られる水素原子の無秩序ー秩序相転移に関して、新しいモデルを提案することになった。また、本研究により氷VIIに多量の塩が入るメカニズムが明らかになった。これらの研究成果により、氷の未解決問題に解答を与えることができ、基礎化学に大きな発展をもたらした。また、本研究は氷惑星の内部物性の理解にも大きな貢献をもたらす。

Report

(5 results)
  • 2018 Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (35 results)

All 2019 2018 2017 2016 2015 2014

All Journal Article (18 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 18 results,  Open Access: 11 results,  Acknowledgement Compliant: 6 results) Presentation (17 results) (of which Int'l Joint Research: 5 results,  Invited: 5 results)

  • [Journal Article] Search for a ferroelectrically ordered form of ice VII by neutron diffraction under high pressure and high electric field2019

    • Author(s)
      Yamane R., Komatsu K., Maynard-Casely H.E., Lee S., Booth N., and Kagi H.
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 17 Pages: 174201-174201

    • DOI

      10.1103/physrevb.99.174201

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Direct observation of symmetrization of hydrogen bond in d-AlOOH under mantle conditions using neutron diffraction2018

    • Author(s)
      Sano-Furukawa A., Hattori T., Komatsu K., Kagi H., Nagai T., Molaison J.J., dos Santos A.M. and Tulk C.A.
    • Journal Title

      Scientific Reports

      Volume: 8 Issue: 1 Pages: 15520-15520

    • DOI

      10.1038/s41598-018-33598-2

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Pressure-induced stacking disorder in boehmite2018

    • Author(s)
      Ishii Y.、Komatsu K.、Nakano S.、Machida S.、Hattori T.、Sano-Furukawa A.、Kagi H.
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 24 Pages: 16650-16656

    • DOI

      10.1039/c8cp02565g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High-Pressure - High-Temperature Study of Benzene: Refined Crystal Structure and New Phase Diagram up to 8 GPa and 923 K2018

    • Author(s)
      Chanyshev Artem D.、Litasov Konstantin D.、Rashchenko Sergey V.、Sano-Furukawa Asami、Kagi Hiroyuki、Hattori Takanori、Shatskiy Anton F.、Dymshits Anna M.、Sharygin Igor S.、Higo Yuji
    • Journal Title

      Crystal Growth & Design

      Volume: 印刷中 Issue: 5 Pages: 3016-3026

    • DOI

      10.1021/acs.cgd.8b00125

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Behavior of intermolecular interactions in α-glycine under high pressure2018

    • Author(s)
      Shinozaki, Ayako Komatsu, Kazuki Kagi, Hiroyuki Fujimoto, Chikako Machida, Shinichi Sano-Furukawa, Asami Hattori, Takanori
    • Journal Title

      The Journal of Chemical Physics

      Volume: 148 Issue: 4 Pages: 044507-044507

    • DOI

      10.1063/1.5009980

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural incorporation of MgCl2 into ice VII at room temperature2017

    • Author(s)
      M. Watanabe K. Komatsu, F. Noritake, and H. Kagi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 印刷中 Issue: 5S3 Pages: 05FB03-05FB03

    • DOI

      10.7567/jjap.56.05fb03

    • NAID

      210000147806

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Partially ordered state of ice XV2016

    • Author(s)
      Komatsu K., Noritake F., Machida S., Sano-Furukawa A., Hattori T., Yamane R. and Kagi H.
    • Journal Title

      Scientific Reports

      Volume: 6 Pages: 28920-28920

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Ice VII from aqueous salt solutions: From a glass to a crystal with broken H-bonds2016

    • Author(s)
      Klotz, S., Komatsu K., Pietrucci F., Kagi H., Ludl A.-A., Machida S., Hattori T., Sano-Furukawa A. and Bove L.E.
    • Journal Title

      Scientific Reports

      Volume: 6 Pages: 32040-32040

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Stability and partial oligomerization of naphthalene under high pressure at room temperature2016

    • Author(s)
      A. Shinozaki, K. Mimura, T. Nishida, T. Inoue, S. Nakano, and H. Kagi
    • Journal Title

      Chemical Physics Letters

      Volume: 662 Pages: 263-267

    • DOI

      10.1016/j.cplett.2016.09.042

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pressure-induced freeze concentratio of alanine aqueous solution as a novel field of chemical reaction2016

    • Author(s)
      Takahashi S., Kagi H., Fujimoto C., Shinozaki A., Gotou H., Nishida T. and Mimura K.
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 3 Pages: 334-337

    • DOI

      10.1246/cl.160992

    • NAID

      130005436526

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Design and Performance of High-Pressure PLANET Beamline at Pulsed Neutron Source at J-PARC2015

    • Author(s)
      Hattori, T., A. Sano-Furukawa, H. Arima, K. Komatsu, A. Yamada, Y. Inamura, T. Nakatani, Y. Seto, T. Nagai, W. Utsumi, T. Iitaka, H. Kagi, Y. Katayama, T. Inoue, T. Otomo, K. Suzuya, T. Kamiyama, M. Arai T. Yagi
    • Journal Title

      Nuclear Instruments and Methods in Physics Research Section A

      Volume: 780 Pages: 55-67

    • DOI

      10.1016/j.nima.2015.01.059

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Crystal structure of magnesium dichloride decahydrate determined by X-ray and neutron diffraction under high pressure2015

    • Author(s)
      Komatsu, K., Shinozaki, A., Machida, S., Matsubayashi, T., Watanabe, M., Kagi, H., Sano-Furukawa, A. and Hattori, T.
    • Journal Title

      Acta Crystallogr. B

      Volume: 71 Issue: 1 Pages: 74-80

    • DOI

      10.1107/s205252061500027x

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In Situ Observation of Pressure-induced Crystallization from Amorphous Calcium Carbonate by Time-resolved X-ray Diffraction2015

    • Author(s)
      Maruyama K., Kagi H., Inoue T., Ohfuji H. and Yoshino T.
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 4 Pages: 434-436

    • DOI

      10.1246/cl.141062

    • NAID

      130005062153

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Pressure-induced oligomerization of alanine at 25 °C2015

    • Author(s)
      Chikako Fujimoto, Ayako Shinozaki, Koichi Mimura, Tamihito Nishida, Hirotada Gotou, Kazuki Komatsu, Hiroyuki Kagi
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 69 Pages: 13358-13361

    • DOI

      10.1039/c5cc03665h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Performance of ceramic anvils for high pressure neutron scattering.2014

    • Author(s)
      K. Komatsu, S. Klotz, A. Shinozaki, R. Iizuka, L.E. Bove, and H. Kagi
    • Journal Title

      High Pressure Research (Proceeding of EHPRG)

      Volume: 34 Issue: 4 Pages: 494-499

    • DOI

      10.1080/08957959.2014.986476

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Six-axis multi-anvil press for high-pressure, high-temperature neutron diffraction experiments2014

    • Author(s)
      Sano-Furukawa A., Hattori T., Arima H., Yamada A., Sabata S., Kondo M., Nakamura A., Kagi H. and Yagi T.
    • Journal Title

      Review of Scientific Instruments

      Volume: 85 Issue: 11 Pages: 113905-113905

    • DOI

      10.1063/1.4901095

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Doping incompatible elements into calcite through amorphous calcium carbonate2014

    • Author(s)
      Matsunuma S., Kagi H., Komatsu K., Maruyama K. and Yoshino T.
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 11 Pages: 5344-5348

    • DOI

      10.1021/cg500953h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Phase transitions and hydrogen bonding in deuterated calcium hydroxide: High-pressure and high-temperature neutron diffraction measurements.2014

    • Author(s)
      izuka R., Komatsu K., Kagi H., Nagai T., Sano-Furukawa A., Hattori T., Gotou H. and Yagi T.
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 218 Pages: 95-102

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 12GPaまでの氷VII相の高圧下誘電率測定2018

    • Author(s)
      山根崚・ 小松 一生 ・ 鍵 裕之
    • Organizer
      高圧討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高圧下での有機化学反応からみた氷惑星における分子進化の可能 性2018

    • Author(s)
      鍵 裕之・高橋 修也・三 村 耕一 ・ 篠崎 彩子 ・ 小松 一生 ・ 藤本 千賀子 ・ 孫 語辰
    • Organizer
      高圧討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] MgCl2 常温高圧水和物の単結晶構造解析2018

    • Author(s)
      山下 恵史朗 ・ 小松 一生 ・ 鍵 裕之
    • Organizer
      高圧討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 誘電率測定による氷 VI-XV 相転移の高圧その場観測2018

    • Author(s)
      山根崚、小松一生、鍵裕之、郷地順、上床美也
    • Organizer
      日本鉱物科学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Incorporation of Nitrogen into the Lower-Mantle Minerals Under High Pressure and High Temperature2018

    • Author(s)
      Fukuyama K, Kagi H, Inoue T, Shinmei T, Kakizawa S, Takahata N & Sano Y
    • Organizer
      Goldschmidt Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 塩を含むアモルファス氷の高圧下における相変化について2017

    • Author(s)
      小松一生
    • Organizer
      量子ビームサイエンスフェスタ
    • Place of Presentation
      エポカルつくば(茨城県つくば市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Oligopeptide Formation of Alanine Under High Pressure at 25℃2017

    • Author(s)
      Fujimoto C, Shinozaki A, Mimura K, Nishida T, Gotou H, Komatsu K & Kagi H
    • Organizer
      Goldschmidt Conference
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 氷の秩序構造の分類2016

    • Author(s)
      山根 崚、小松 一生、則竹 史哉
    • Organizer
      日本鉱物科学会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Year and Date
      2016-09-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 圧力誘起凍結濃縮によるアミノ酸の脱水縮合反応2016

    • Author(s)
      高橋 修也、鍵 裕、,藤本 千賀子、小松 一生、篠崎 彩子、三村 耕一、西 田 民人
    • Organizer
      日本地球化学会年会
    • Place of Presentation
      大阪市立大学(大阪府大阪市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Structural incorporation of MgCl2 into ice VII at room temperature2016

    • Author(s)
      Watanabe M., Komatsu K., Noritake F. and Kagi H.
    • Organizer
      The 17th International Conference on High Pressure in Semiconductor Physics (HPSP-17) & Workshop on High-pressure Study on Superconducting (WHS)
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2016-08-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 氷XV相の構造と安定性の再評価2015

    • Author(s)
      小松 一生, 町田 真一, 則竹 史哉, 山根 崚, 佐野 亜沙美, 服 部 高典, 鍵 裕之
    • Organizer
      高圧討論会
    • Place of Presentation
      JMSアステールプラザ(広島県広島市)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 氷XV相の結晶構造の再検討2015

    • Author(s)
      小松 一生, 則竹 史哉, 山根 崚, 鍵 裕之, 町田 真一, 佐野 亜沙美, 服部 高典
    • Organizer
      日本鉱物科学会2015年年会
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Stable Ice VIIIは存在できるのか2015

    • Author(s)
      則竹 史哉, 小松一生, 鍵 裕之
    • Organizer
      日本鉱物科学会2015年年会
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 氷VI相の秩序構造の数え上げ2015

    • Author(s)
      山根 峻, 小松 一生, 則武史哉, 鍵 裕之
    • Organizer
      日本鉱物科学会2015年年会
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 室温下での氷VIIへのMgCl2の取り込み2015

    • Author(s)
      渡邉 真央,小松一生, 鍵 裕之
    • Organizer
      日本鉱物科学会2015年年会
    • Place of Presentation
      東京大学(東京都文京区)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Experimental studies on water and ice inside of the earth and planets2014

    • Author(s)
      Kagi H.
    • Organizer
      China-Japan Joint Forum on Geochemistry and Cosmochemistry
    • Place of Presentation
      富山大学(富山県・富山市)
    • Year and Date
      2014-09-16
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High-pressure neutron beamline at J-PARC and applications to earth-planetary science.2014

    • Author(s)
      Kagi H.
    • Organizer
      International Crystallography Union
    • Place of Presentation
      Montreal (Canada)
    • Year and Date
      2014-08-07
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2014-04-04   Modified: 2020-03-30  

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