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Creation of novel nonlinear properties in nanowire metal complexes with strong electron correlation

Research Project

Project/Area Number 26248015
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionTohoku University

Principal Investigator

Yamashita Masahiro  東北大学, 材料科学高等研究所, 教授 (60167707)

Co-Investigator(Kenkyū-buntansha) 高石 慎也  東北大学, 理学研究科, 准教授 (10396418)
井口 弘章  東北大学, 理学研究科, 助教 (30709100)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥42,380,000 (Direct Cost: ¥32,600,000、Indirect Cost: ¥9,780,000)
Fiscal Year 2017: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2016: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2015: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2014: ¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Keywordsナノワイヤー金属錯体 / 強相関電子系 / 平均原子価状態 / 熱電材料 / 平均原子価 / 一次元電子系 / 非線形 / 熱電 / 混合原子価 / 非線形現象 / 低次元電子系
Outline of Final Research Achievements

We have succeeded in synthesizing the novel Pd-Br chain compound with averaged valence state which is stable up to 400 K. We measured physical properties of this compound. This compound showed extremely high electrical conductivity (40 Scm-1at room temperature), which is 10^6 higher than previous Pd-Br compound. The averaged valence state was stable up to 443 K(decomposition temperature). Such a stable averaged valence state has not been shown in the previous Pd-Br chains. This is because hydrogen bond between hydroxy group of the dabdOH ligand and Br- ion made 1D chains far away each other, and resultantly compression of 1D chain direction occured.
We also measured thermoelectoric property of a series of MX chain compounds. We measured [Ni1-xCox(chxn)2Br]Br2. The pure [Ni(chxn)2Br]Br2 showed negative Seebeck efficient, whereas the absolute value of that decreased with increasing Co ratio.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(85 results)

All 2018 2017 2016 2015 2014

All Journal Article (44 results) (of which Int'l Joint Research: 13 results,  Peer Reviewed: 44 results,  Open Access: 6 results,  Acknowledgement Compliant: 19 results) Presentation (41 results) (of which Int'l Joint Research: 12 results,  Invited: 23 results)

  • [Journal Article] Changing Single-Molelcule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy Substituted Phthalocyaninate Double-Decker Complex by Protonation/Deprotonation2018

    • Author(s)
      Y. Horii, Y. Horie, K. Katoh, B. K. Breedlove and M. Yamashita
    • Journal Title

      Inorganic Chemistry

      Volume: 57 Pages: 565-574

    • DOI

      10.1021/acs.inorgchem.7b02124

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Molecular and supramolecular aspects in mononuclear manganese(III) Schiff-base spin crossover complexes2017

    • Author(s)
      S. Wang, Y. Juan, F. Ju, W. Xu, K. Kagesawa, Y. Li, M. Yamashita and W. Huang
    • Journal Title

      Dalton Trans.

      Volume: 46 Pages: 11063-11077

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Elucidation of Dual Magnetic Relaxation Processes in Dinuclear Dysprosium(III) Phthalocyaninato Triple-Decker Single-Molecule Magnets Depending on the Octacoordination Geometry2017

    • Author(s)
      K. Katoh, Y. Aizawa, T. Morita, B. K. Breedlove, M. Yamashita
    • Journal Title

      Chem. Eur. J.

      Volume: 23 Pages: 15377-15386

    • DOI

      10.1002/chem.201703014

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(III)-phthalocyaninato quadruple-decker complex2017

    • Author(s)
      Y. Horii, K. Katoh, B. K. Breedlove, M. Yamashita
    • Journal Title

      Chem. Commun.

      Volume: 53 Pages: 8561-8564

    • DOI

      10.1039/c7cc03553e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiple Magnetic Relaxation Pathways and Dual-Emission Modulated by a Heterometallic Tb-Pt Bonding Environment2017

    • Author(s)
      T. Yoshida, D. C. Izougu, D. Iwasawa, S. Ogata, M. Hasegawa, B. K. Breedlove, G. Cosquer, W. Wernsdorfer, M. Yamashita
    • Journal Title

      Chem. Eur. J.

      Volume: 23 Pages: 10527-10531

    • DOI

      10.1002/chem.201702989

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Orientation of a Terbium(III)-Phthalocyaninato Double-Decker Complex for Effective Suppression of Quantum Tunneling of the Magnetization2017

    • Author(s)
      T. Yamabayashi, K. Katoh, B. K. Breedlove, M. Yamashita
    • Journal Title

      Materials

      Volume: 22 Pages: 999-1008

    • DOI

      10.3390/molecules22060999

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Three dimensional porous Hofmann clathrate [MIIPtII(CN)4] (M = Co, Ni) synthesized by using postsynthetic reductive elimination2017

    • Author(s)
      Takuro Okamura, Bin Wu, Hiroaki Iguchi, Brian K. Breedlove, Masahiro Yamashita, Wataru Kosaka, Hitoshi Miyasaka, Shinya Takaishi
    • Journal Title

      Chem. Commun.

      Volume: 53 Pages: 6512-6515

    • DOI

      10.1039/c7cc01766a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Proton Control of the Lanthanoid Single-Ion Magnet Behavior of a Double-Decker Complex with an Indolenine-Substituted Annulene Ligand2017

    • Author(s)
      Z. Liang, M. Damjanovic, M. Kamila, G. Cosquer, B. K. Breedlove, M. Enders and M. Yamashita
    • Journal Title

      Inorg. Chem.

      Volume: 56 Pages: 6512-6521

    • DOI

      10.1021/acs.inorgchem.7b00626

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiple Hydrogen-Bond Approach to Uncommon Pd(III) Oxidation State: A Pd-Br Chain with High Conductivity and Thermal Stability2017

    • Author(s)
      Mian M. Rasel, Hiroaki Iguchi, Shinya Takaishi, Hideaki Murasugi, T. Miyamoto, Hiroshi Okamoto, Hisaaki Tanaka, Shin-ichi Kuroda, Brian K. Breedlove, MasahiroYamashita
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Pages: 6562-6565

    • DOI

      10.1021/jacs.7b02558

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Field-Induced Slow Magnetic Relaxation of Gd(III) Complex with Pt-Gd Heterometallic Bond2017

    • Author(s)
      T. Yoshida, G. Cosquer, D. C. Izuogu, H. Ohtsu, M. Kawano, Y. -H. Lan, W. Wernsdorfer, H. Nojiri, B. K. Breedlove, M. Yamashita
    • Journal Title

      Chem. Eur. J.

      Volume: ー Pages: 4551-4556

    • DOI

      10.1002/chem.201700886

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Packing Structure Effects on the Slow Magnetic Relaxation Pathways of Dysprosium (III) Complexes2017

    • Author(s)
      M. Kamila, G. Cosquer, Brian. K. Breedlove and M. Yamashita
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 90 Issue: 5 Pages: 595-595

    • DOI

      10.1246/bcsj.20160408

    • NAID

      130006770716

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Slow relaxation of the magnetization observed in an antiferromagnetically ordered phase for SCM-based two-dimensional layered compounds2017

    • Author(s)
      Kagesawa Koichi, Nishimura Yuki, Yoshida Hiroki, Breedlove Brian K., Yamashita Masahiro, Miyasaka Hitoshi
    • Journal Title

      Dalton Trans.

      Volume: 46 Pages: 3170-3178

    • DOI

      10.1039/c6dt04636c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optically visible phase separation between Mott-Hubbard and charge-density-wave domains in a Pd-Br chain complex2016

    • Author(s)
      T. Yoshida, S. Takaishi, H. Iguchi, H. Okamoto, H. Tanaka, S. Kuroda, Y. Hosomi, S. Yoshida, H. Shigekawa, T. Kojima, H. Ohtsu, M. Kawano, B. K. Breedlove, L. Gué rin, and M. Yamashita
    • Journal Title

      Chemistry Select

      Volume: 2 Pages: 259-263

    • DOI

      10.1002/slct.201600065

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Direct Observation of Ordered High-Spin-Low-Spin Intermediate States of an Iron(III) Three-Step Spin-Crossover Complex2016

    • Author(s)
      Z.-Y. Li, H. Ohtsu, T. Kojima, J.-W. Dai, T. Yoshida, B. K. Breedlove, W.-X. Zhang, H. Iguchi, O. Sato, M. Kawano, M. Yamashita
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Pages: 5184-5189

    • DOI

      10.1002/anie.201511281

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photo-activation of Single Molecule Magnet Behavior in Manganese-based Complex2016

    • Author(s)
      A. Fetoh, G. Cosquer, M. Morimoto, M. Irie, O. El-Gammal, G. A. El-Reash, B. K. Breedlove M. Yamashita
    • Journal Title

      Scientific Reports

      Volume: 6 Pages: 23785-23785

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structure Insights into the Counterion Effects on the Manganese(lll) Spin Crossover System with Hexadentate Schiff-Base Ligands2016

    • Author(s)
      S. Wang, W. T. Xu, W. R. He, S. Takaishi, Y. H. Li, M. Yamashita amd W. Huang
    • Journal Title

      Dalton Trans

      Volume: 45 Pages: 5676-5688

    • DOI

      10.1039/c5dt04824a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Symmetry of octa-coordination environment has a substantial influence on dinuclear TbIII triple-decker single-molecule magnets2016

    • Author(s)
      K. Katoh, B. K. Breedlove, M. Yamashita
    • Journal Title

      Chem. Sci.

      Volume: 該当なし Pages: 4329-4340

    • DOI

      10.1039/c5sc04669f

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 1D chains of lanthanoid ions and a dithienylethene ligand showing slow relaxation of the magnetization2016

    • Author(s)
      Mudasir Ahmad Yatoo, Goulven Cosquer, Masakazu Morimoto, Masahiro Irie, Brian K. Breedlove, Masahiro Yamashita
    • Journal Title

      Magnetochemistry

      Volume: 2 Pages: 21-21

    • DOI

      10.3390/magnetochemistry2020021

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A highly emissive distyrylthieno[3,2-b]thiophene based red luminescent organic single crystal: Aggregation induced emission, optical waveguide edge emission, and balanced ambipolar carrier transport2016

    • Author(s)
      Shuai Mu, Kazuaki Oniwa, Tienan Jin, Naoki Asao, Masahiro Yamashita, Shinya Takaishi
    • Journal Title

      Organic Electronics.

      Volume: 34 Pages: 23-27

    • DOI

      10.1016/j.orgel.2016.04.001

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Tuneable mechanical and dynamical properties in the ferroelectric perovskite solid solution [NH3NH2](1-x)[NH3OH]x Zn(HCOO)32016

    • Author(s)
      G. Kieslich, S. Kumagai, A. C. Forse, S. Sun, S. Henke, M. Yamashita, C. P. Grey and A. K. Cheetham
    • Journal Title

      Chem. Sci.

      Volume: 7 Pages: 5108-5112

    • DOI

      10.1039/c6sc01247g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Temperature dependence of Peierls-Hubbard Phase Transition in [Pd(cptn)2Br] Br2 Studied by Scanning Tunneling Microscopy2016

    • Author(s)
      Y. Hoshimi, S. Yoshida, A. Taninaka, T. Yoshida, S. Takaishi, O. Takeuchi, M. Yamashita and H. Shigekawa
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 55

    • NAID

      120007129519

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Field-induced single-ion magnetism based on spin-phonon relaxation in a distorted octahedral high-spin cobalt(II)complex2016

    • Author(s)
      R. Ishikawa, S. Ueno, S. Kawata, Y. Horii, R. Nakanishi, B. K. Breedlove and M. Yamashita
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2016 Pages: 3233-3239

    • DOI

      10.1002/ejic.201600481

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] How Ions Arrange in Solution: Detailed Insight from Nuclear Magnetic Resonance Spectroscopy2016

    • Author(s)
      M. Damjanovic, T. Morita, Y. Horii, K. Katoh, M. Yamashita and M. Enders
    • Journal Title

      Chem. Eur. J.

      Volume: 17 Pages: 3423-3429

    • DOI

      10.1002/cphc.201600804

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] A scanning tunneling microscopy study of the electronic and spin states of bis(phthalocyaninato)terbium(III) (TbPc2) molecules on Ag(111)2016

    • Author(s)
      F. Ara, Z. K. Qi, J. Hou, T. Komeda, K. Katoh, M. Yamashita,
    • Journal Title

      Dalton. Trans.

      Volume: 45 Pages: 16644-16652

    • DOI

      10.1039/c6dt01967f

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Surface confinement of TbPc2-SMMs: structural, electronic and magnetic properties2016

    • Author(s)
      E. Moreno Pineda, T. Komeda, K. Katoh, M. Yamashita, M. Ruben,
    • Journal Title

      Dalton. Trans.

      Volume: 45 Pages: 18417-18433

    • DOI

      10.1039/c6dt03298b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Weak Dy(III)-Dy(III) Interaction in Dy(III)-Phthalocyaninato Multiple-Decker Single-Molecule Magnetic Effectively Suppress Magnetic Relaxation2016

    • Author(s)
      Y. Horii, K. Katoh, G. Cosquer, B. K. Breedlove and M. Yamashita
    • Journal Title

      Inorganic Chemistry

      Volume: 55 Pages: 11782-11790

    • DOI

      10.1021/acs.inorgchem.6b01870

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Heterometallic Cu(ll)-Dy(III) clusters of differnt nuclearities with slow magnetic relaxation2016

    • Author(s)
      R. Modak, Y. Sikdar, G. Cosquer, S. Chatterjee, M. Yamashita, and S. Gosawami
    • Journal Title

      Inorg. Chem.

      Volume: 55 Pages: 691-699

    • DOI

      10.1021/acs.inorgchem.5b02107

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Hybrid Molecular Compound Exhibiting Slow Magntic Relaxation and Electrical Conductivity2016

    • Author(s)
      Y. Shen, G. Cosquer, Brian. K. Breedlove and M. Yamashita
    • Journal Title

      Magnetochemistry

      Volume: 2 Pages: 44-44

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Frontier of Molecular Spintronics Based on Multiple-Decker Phthalocyaninato Tb(lll) Single-Molecule Magnets2016

    • Author(s)
      K. Katoh, T. Komeda, M. Yamashita
    • Journal Title

      Chem. Rec.

      Volume: 16 Pages: 987-1016

    • DOI

      10.1002/tcr.201500290

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Remote control of SMM behaviour via DTE ligands2015

    • Author(s)
      Goulven Cosquer, Brian K. Breedlove, Masahiro Yamashita
    • Journal Title

      Dalton Trans.

      Volume: 44 Pages: 2936-2942

    • DOI

      10.1039/c4dt02618g

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photo-control of the magnetic properties of Dy(III) and Ho(III) homometal coordination polymers bridged by a diarylethene ligand2015

    • Author(s)
      Goulven Cosquer, Masakazu Morimoto, Masahiro Irie, Ahmed Fetoh, Brian K. Breedlove, Masahiro Yamashita
    • Journal Title

      Dalton Trans.

      Volume: 44 Pages: 5996-6002

    • DOI

      10.1039/c4dt03093a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Charge-bistable Pd(III)/Pd(ll,lV) coordination polymers: phase transition and their applications to optical properties2015

    • Author(s)
      S. Kumagai, S. Takaishi, H. Iguchi, and M. Yamashita
    • Journal Title

      Dalton Trans.

      Volume: 44 Pages: 8590-8599

    • DOI

      10.1039/c5dt00439j

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Interactions on the Single-Molecule Magnet Properties of Terbium(III)–Phthalocyaninato Quintuple-Decker Complexes2015

    • Author(s)
      Yoji Hori, Keiichi Katoh, Nobuhiro Yasuda, Brian K. Breedlove, and Masahiro Yamashita
    • Journal Title

      Inorg. chem.

      Volume: 54 (7) Pages: 3297-3305

    • DOI

      10.1021/ic502951t

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Ligand π-Radical Interaction with f-shel Unpaired Electrons in Phthalocyaninato-Lanthanoid Single-Molecule Magnets; A Solution NMR Spectroscopic and DFT Study2015

    • Author(s)
      M. Damjanovic, T. Morita, K. Katoh, M. Yamashita, M. Enders
    • Journal Title

      Chemistry- A European Journal

      Volume: 21 Pages: 14421-14432

    • DOI

      10.1002/chem.201501944

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Tuning Interchain Interactions in Two-Dimensional Networks of Mn(lll) Schiff-Base Complexes and Dicarboxylic Acids by Varying the Linker2015

    • Author(s)
      Y. Aono, H. Yoshida, K. Katoh, B. K. Breedlove, K. Kagesawa, M. Yamashita
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Pages: 7096-7102

    • DOI

      10.1021/acs.inorgchem.5b01154

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Role of entropic effects in controlling the polymorphism in ferroelectric formate frameworks2015

    • Author(s)
      G. Kieslich, S. Kumagai, K. T. Butler, T. Okamura, C. H. Hendron, M. Yamashita, A. Walsh, and A. K. Cheetham
    • Journal Title

      Chem. Commun.

      Volume: 51 Pages: 15538-15541

    • DOI

      10.1039/c5cc06190c

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Fabrication of one-dimensional grating structure on organic single-crystal surface2014

    • Author(s)
      Kenichi Maruyama, Jinpeng Li, Wataru Takahashi, Shu Hotta, Shinya Takaishi, Masahiro Yamashita, and Taishi Takenobu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 2S Pages: 02BC19-02BC19

    • DOI

      10.7567/jjap.53.02bc19

    • NAID

      210000143367

    • ISSN
      0021-4922, 1347-4065
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recent Progress in MMX-Chain Complexes: Unique Electronic States and Characteristics Developed by Introducing Binary Countercations2014

    • Author(s)
      Iguchi, Hiroaki; Takaishi, Shinya; Yamashita, Masahiro
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 1 Pages: 69-79

    • DOI

      10.1246/cl.130961

    • NAID

      130004427093

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Anisotropy in a spin 1/2 Quasi-One-Dimensional Antiferromagnetic Copper(II) Complex CuCl2(pdz) with a Staggered g-tensor2014

    • Author(s)
      Shinya Takaishi, Hiroshi Kitagawa, Hisaaki Tanaka, Shin-ichi Kuroda, Ryuichi Ikeda
    • Journal Title

      Dalton Trans.

      Volume: 43 Pages: 11529-11532

    • DOI

      10.1039/c4dt00809j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Predominance of Covalency in Water-Vapor-Responsive MMX-Type Chain Complexes revealed by (129)I Moesbauer Spectroscopy2014

    • Author(s)
      H. Iguchi, S. Kitao, M. Seto, S. Takaishi, and M. Yamashita
    • Journal Title

      Dalton Trans.

      Volume: 43 Pages: 8767-8773

    • DOI

      10.1039/c4dt00627e

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid-State Electrochemistry of Semiconducting MMX-Type Diplatinum-Iodide Chain Complexes2014

    • Author(s)
      H. Iguchi, A. Nafady, S. Takaishi, M. Yamashita, and A. M. Bond
    • Journal Title

      Inorg. Chem.

      Volume: 53 Pages: 4022-4028

    • DOI

      10.1021/ic402980t

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Excitation-Photon-Energy Selectivity of Photoconversions in Halogen-Bridged Pd-Chain Compounds: Mott Insulator to Metal or Charge-Density-Wave State2014

    • Author(s)
      H. Matsuzaki, M. Iwata, T. Miyamoto, T. Terashige, K. Iwano, S. Takaishi, M. Takamura, S. Kumagai, M. Yamashita, R. Takahashi, Y. Wakabayashi, and H. Okamoto
    • Journal Title

      Phys. Rev. Lett.

      Volume: 113 Pages: 096403-096403

    • DOI

      10.1103/physrevlett.113.096403

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Bromide-Bridged Palladium(III) Chain Complex Showing Charge Bistability Near Room Temperature2014

    • Author(s)
      S. Kumagai, S. Takaishi, B. K. Breedlove, H. Okamoto, H. Tanaka, S. Kuroda, and M. Yamashita
    • Journal Title

      Chem. Commun.

      Volume: 50 Pages: 8382-8384

    • DOI

      10.1039/c4cc02547d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Continuous Control of Optical Gaps in Quasi-One-Dimensional Bromide-Bridged Platinum Complexes by Utilizing Chemical Pressure2014

    • Author(s)
      Shohei Kumagai, Hiroaki Iguchi, Shinya Takaishi, Brian K Breedlove, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Kenichi Kato, Masaki Takata
    • Journal Title

      Inorg. Chem.

      Volume: 53 Pages: 11764-11769

    • DOI

      10.1021/ic502071u

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2016

    • Author(s)
      Masahiro Yamashita
    • Organizer
      Le Quartz Brest Congresブレスト国際会議場、Brest/France
    • Place of Presentation
      Le Quartz Brest Congresブレスト国際会議場、Brest/France
    • Year and Date
      2016-07-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2016

    • Author(s)
      Masahiro Yamashita
    • Organizer
      ICSM2016 合成金属の科学と技術に関する国際会議(ICSM2016)
    • Place of Presentation
      広州白雲国際コンベンションセンター ,中国
    • Year and Date
      2016-06-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2016

    • Author(s)
      Masahiro Yamashita
    • Organizer
      Energy Materials Nanotechnology (EMN2016)
    • Place of Presentation
      Hotel Neptun/Importanne Hotels&Resort, Dubrovnik/Croatia
    • Year and Date
      2016-05-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2016

    • Author(s)
      Masahiro Yamashita
    • Organizer
      5th International Conference on Superconductivity and Magnetism (ICSM2016)
    • Place of Presentation
      Liberty Hotels LYKIA, Fethiye/Turkey
    • Year and Date
      2016-04-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      The International Chemical Congress of Pacific Basin Societies2015(Pacifichem)
    • Place of Presentation
      "Hawaii Convention Center,Honolulu
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      "1st International Caparica Christmas Congress on Translational Chemistry
    • Place of Presentation
      Aldeia Dos Capuchos Golf&Spa,Lisbon(Portugal)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      World Congress and Expo on Oil, Gas Petrochemistry
    • Place of Presentation
      Crowne Plaza Dubai Deria,Dubai(UAE)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets :Toward Green IT Innovation2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      第9回日露分子磁性分子スピンデバイス国際会議
    • Place of Presentation
      淡路島夢舞台
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electronic States of Quasi-One-Dimensional Halogen-Bridged Metal Complexes in Polar Space Groups2015

    • Author(s)
      熊谷翔平, 井口弘章, 高石慎也, 山下正廣
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      国立大学法人奈良女子大学
    • Year and Date
      2015-09-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pd-Br 一次元錯体における電荷移動相転移に伴う相分離現象の解明2015

    • Author(s)
      吉田健文, 井口弘章, 高石慎也, 山下正廣
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      国立大学法人奈良女子大学
    • Year and Date
      2015-09-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Bifunctional Macrocyclic metal complexes as CO2 reduction electrocatalysts2015

    • Author(s)
      Md.Ahsan Habib, Brian K. Breedlove, Masahiro Yamashita
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      国立大学法人奈良女子大学
    • Year and Date
      2015-09-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] "Photo-control of the Magnetic Properties in ManganeseBased2015

    • Author(s)
      Ahmed Hamdy Ahmed Radwan, Masahiro Yamashita
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      国立大学法人奈良女子大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Giant Magnetoresistance and Tunneling Magnetoresistance Based on Single-Molecule Magnets2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      第2回日独二国間会議
    • Place of Presentation
      国立大学法人奈良女子大学
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets :Toward Green IT Innovation2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      Indaba8
    • Place of Presentation
      Skukuza, Kruger National Park,South Africa
    • Year and Date
      2015-08-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets :Toward Green IT Innovation2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      5th Asian conference on Coordination Chemistry,ACCC5
    • Place of Presentation
      The University of Hong Kong
    • Year and Date
      2015-07-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics Based on Single-Molecule Magnets2015

    • Author(s)
      Masahiro Yamashita
    • Organizer
      98th Canadian Chemistry Conference and Exhibiion
    • Place of Presentation
      Otawa, Shaw Centre,Canada
    • Year and Date
      2015-06-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mixed-valence to averaged-valence phase transition in quasi-one-dimensional bromo-bridged palladium complexes2015

    • Author(s)
      Shinya Takaishi, Takefumi Yoshida, Shohei Kumagai, Masahiro Yamashita, Hiroshi Okamoto, Yuka, Hosomi, Shoji Yoshida, Hidemi Shigekawa, Hisaaki Tanaka, Shin-ichi Kuroda
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Dense Formate Frameworks with and ABX3 Perovskite-like Architecture: Tuning Properties by A-site Substitution2015

    • Author(s)
      Shohei Kumagai, GregorKieslich, Anthony K. Cheetham, Shinya Takaishi, Masahiro Yamashita
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 擬一次元Br架橋Pd錯体におけるMH-CDW相転移2015

    • Author(s)
      高石慎也
    • Organizer
      第二回東北大学リーディング大学院研究会プログラム「金属錯体の個体物性最前線-金属錯体と固体物性物理と生物物性の連携新領域をめざして」
    • Place of Presentation
      東北大学
    • Year and Date
      2015-02-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] CDW-MH Phase Transition in Quasi-One-Dimensional Halogen-Bridged Metal Complexes & Recent Progresses in Halogen-Bridged Metal Complexes (Toward Electronic Devices)2015

    • Author(s)
      高石慎也
    • Organizer
      Symposium on Recent Development in Electron and X-ray Physics
    • Place of Presentation
      東北大学
    • Year and Date
      2015-02-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Control of Packing Motif and Physical Properties in Coordination Polymers based on 2,3-pyrazinedithiolate Complexes2014

    • Author(s)
      Shinya Takaishi
    • Organizer
      France-Japan joint workshop FRONTIER2014
    • Place of Presentation
      Nantes University, France
    • Year and Date
      2014-12-08
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] MV-AV Phase Transition in Quasi-One-Dimensional Halogen-Brid2014

    • Author(s)
      Shinya Takaishi
    • Organizer
      The 16thJapan-Korea Joint Symposium on Organometallic and Coordination Chemistry
    • Place of Presentation
      東北大学
    • Year and Date
      2014-10-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Frontier of Quantum Molecular Spintronics based on Single-Molecule Magnets2014

    • Author(s)
      Masahiro Yamashita
    • Organizer
      SPINOS2014
    • Place of Presentation
      Himeji(Japan)
    • Year and Date
      2014-10-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Structures, Synthesis of Metal Organic Frameworks with Highly Pi-Conjugated Ligand2014

    • Author(s)
      Bin Wu, Shinya Takaishi, Masahiro Yamashita
    • Organizer
      MOF2014
    • Place of Presentation
      Kobe international conference center
    • Year and Date
      2014-09-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] MMX-Chain-Based Flexible Framework: Changing The Electronic States and Conductivity by Dehydration and Electrochemical Oxidation2014

    • Author(s)
      Hiroaki Iguchi, Shinya Takaishi, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Shin-Ichi Kuroda, Ayman Nafady, Alan Bond, Masahiro Yamashita
    • Organizer
      MOF2014
    • Place of Presentation
      Kobe international conference center
    • Year and Date
      2014-09-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] In Situ Synthesis Metal Organic Frameworks Inserted Ferrocenium Ion Derivatives That Can Orientate Along Magnetic Field2014

    • Author(s)
      Shinichi Tomoguchi, Shinya Takaishi, Hiroaki Iguchi, Keichi Katoh, Brian Breedlove, Masahiro Yamashita
    • Organizer
      MOF2014
    • Place of Presentation
      Kobe international conference center
    • Year and Date
      2014-09-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] 単分子量子磁石を用いた量子分子スピントロニクスの最前線2014

    • Author(s)
      山下正廣
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 129IメスバウアースペクトルによるMMX型Chain錯体の電子状態の考察2014

    • Author(s)
      井口弘章、北尾真司、瀬戸誠、高石慎也、山下正廣
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structures, Synthesis of Hydrogen-Bonded Organic Frameworks2014

    • Author(s)
      Bin Wu, Shinya Takaishi, Masahiro Yamashita
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] フェロセニウム化合物の多孔性配位高分子への導入と磁気特性2014

    • Author(s)
      友口真一、高石慎也、井口弘章、影澤幸一、Brian K. Breedlove, 加藤恵一、山下正廣
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 走査型トンネル顕微鏡による臭素架橋Pd錯体の電子状態観察2014

    • Author(s)
      吉田健文・高石慎也・井口弘章・山下正廣
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 一次元ハロゲン架橋金属錯体のFET特性2014

    • Author(s)
      熊谷翔平、高石慎也、山下正廣
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Frontier of Quantum Molecular Spintronics based on Single-Molecule Quantum Magnets2014

    • Author(s)
      山下正廣
    • Organizer
      錯体化学会第64回討論会・日英ジョイントシンポジウム
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] テトラフェニルメタン骨格を用いた多孔性有機高分子の開発とその気体吸蔵特性の評価2014

    • Author(s)
      Mengqi Gao, 高石慎也、山下正廣
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2014-09-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] テトラフェニルメタンデンドリマー構造を用いた水素結合フレームワークの合成2014

    • Author(s)
      豊福 宣行,眞木晴季,高石慎也,山下正廣
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2014-09-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] テトラフェニルメタン骨格を有するケージ分子を元とした大きな表面積を持つCOFの合成2014

    • Author(s)
      志田大和、高石慎也、山下正廣
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2014-09-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Frontier of Quantum Molecular Spintronics based on Single-Molecule Magnets2014

    • Author(s)
      Masahiro Yamashita
    • Organizer
      ICCC41
    • Place of Presentation
      Singapore(Republic of Singapore)
    • Year and Date
      2014-07-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics based on Single-Molecule Magnets2014

    • Author(s)
      Masahiro Yamashita
    • Organizer
      ICMM2014
    • Place of Presentation
      Saint peterrsburg(Russia)
    • Year and Date
      2014-07-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics based on Multiple-Decker Phthalocyaninato Ln(III) Single-Molecule Magnets2014

    • Author(s)
      Masahiro Yamashita
    • Organizer
      E-MRS
    • Place of Presentation
      Lille(France)
    • Year and Date
      2014-05-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Frontier of Quantum Molecular Spintronics based on Single-Molecule Magnets2014

    • Author(s)
      Masahiro Yamashita
    • Organizer
      CSC2014
    • Place of Presentation
      Vancouver(Canada)
    • Year and Date
      2014-05-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 単分子量子磁石を用いた量子分子スピントロニクスの最前線2014

    • Author(s)
      山下正廣
    • Organizer
      山口大学講演会
    • Place of Presentation
      山口大学
    • Year and Date
      2014-04-25
    • Related Report
      2014 Annual Research Report
    • Invited

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Published: 2014-04-04   Modified: 2019-03-29  

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