| Budget Amount *help |
¥40,300,000 (Direct Cost: ¥31,000,000、Indirect Cost: ¥9,300,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2016: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Fiscal Year 2015: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2014: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
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| Outline of Final Research Achievements |
We have elucidated the respective mechanisms of “preferential enrichment” and "positive magneto-LC effect", which are unique chemical complexity phenomena arising from the phase transition of aggregated chiral organic compounds and were discovered by us using a molecular chirality or an electron spin as the probe, respectively. Consequently, the former phenomenon has turned out to become a general chiral resolution method by forming the cocrystals of chiral racemic organic compounds and achiral organic ones. On the other hand, the latter phenomenon has been ascribed to the occurrence of spin glass-like superparamagnetic interactions in organic radical liquid crystalline materials, similar to the case of magnetic metal alloys.
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