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Exciton Dynamics in Crystalline Domains of Conjugated Polymers

Research Project

Project/Area Number 26248033
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

OHKITA Hideo  京都大学, 工学研究科, 教授 (50301239)

Co-Investigator(Kenkyū-buntansha) 玉井 康成  京都大学, 工学研究科, 助教 (30794268)
辨天 宏明  京都大学, 工学研究科, 助教 (60422995)
Research Collaborator Tamai Yasunari  
Project Period (FY) 2014-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥41,860,000 (Direct Cost: ¥32,200,000、Indirect Cost: ¥9,660,000)
Fiscal Year 2018: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2017: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2016: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Fiscal Year 2014: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Keywords一重項励起子拡散 / 共役高分子 / 励起子相互作用 / J凝集 / H凝集 / 結晶性 / 励起子拡散 / 次元性 / 超放射 / 一重項分裂 / 結晶性共役高分子 / 結晶化度 / 一重項励起子 / 三重項励起子 / 分子内電荷移動 / 励起子拡散定数 / 励起子カップリング / 振動緩和 / 非緩和励起子 / ダイナミクス / フェルスター
Outline of Final Research Achievements

In this project, we studied the following three issues. First, we studied the exciton dynamics in J-aggregated crystalline conjugated polymer PNOz4T films. As a result, we found that two-dimensional exciton diffusion is dominant at room temperature and one-dimensional exciton diffusion is dominant at lower temperatures. Second, we studied the exciton dynamics in highly crystalline J-aggregated conjugated polymer P3HT films. As a result, we found that singlet excitons exhibit rapid radiative and non-radiative rate ~100 time faster than those for H-aggregated normal P3HT films. Third, we studied singlet fission in crystalline conjugated polymer PDPP3T films. As a result, we found that singlet fission more efficiently proceeds in H-aggregated films rather than in J-aggregated films.

Academic Significance and Societal Importance of the Research Achievements

結晶性共役高分子の結晶相における一重項励起子拡散の次元性は高分子鎖の凝集形態に強く依存することを実証した。これにより、凝集形態を制御することにより必要に応じた励起子拡散を実現できると期待される。高度に結晶化したJ凝集性を示すP3HTにおける輻射遷移速度と無輻射遷移速度の増大機構について未解明であるが、高度な結晶化に由来した集団的協働現象である可能があり学術的意義が高い新規物性である。結晶性共役高分子における一重項分裂は、H凝集形態において高効率に進行することから、形態制御による一重項分裂のさらなる高効率化が期待される。

Report

(6 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (48 results)

All 2019 2018 2017 2016 2015 2014

All Journal Article (9 results) (of which Open Access: 6 results,  Peer Reviewed: 8 results,  Acknowledgement Compliant: 4 results) Presentation (38 results) (of which Int'l Joint Research: 9 results,  Invited: 11 results) Book (1 results)

  • [Journal Article] 共役高分子膜における一重項分裂2018

    • Author(s)
      大北英生, 玉井康成, 笠井普文
    • Journal Title

      日本化学繊維研究所講演集

      Volume: 75 Pages: 42-29

    • NAID

      40021507488

    • Related Report
      2018 Annual Research Report
    • Open Access
  • [Journal Article] 高分子太陽電池における励起子・キャリアダイナミクス2017

    • Author(s)
      大北英生、玉井康成
    • Journal Title

      光化学

      Volume: 48 Pages: 139-146

    • NAID

      120006471159

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exciton and Charge Dynamics in Polymer Solar Cells2017

    • Author(s)
      玉井康成
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 74 Issue: 5 Pages: 430-451

    • DOI

      10.1295/koron.2017-0028

    • NAID

      130006096676

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transient Absorption Spectroscopy for Polymer Solar Cells2016

    • Author(s)
      Hideo Ohkita, Yasunari Tamai, Hiroaki Benten, Shinzaburo Ito
    • Journal Title

      IEEE J. Sel. Top. Quantum Electron.

      Volume: 22 Issue: 1 Pages: 100-111

    • DOI

      10.1109/jstqe.2015.2457615

    • NAID

      120005741085

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Ultrafast Singlet Fission in a Push-Pull Low Bandgap Polymer Film2015

    • Author(s)
      Yukitomo Kasai, Yasunari Tamai, Hideo Ohkita, Hiroaki Benten, Shinzaburo Ito
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 51 Pages: 15980-15983

    • DOI

      10.1021/jacs.5b09361

    • NAID

      120005741086

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Exciton Diffusion in Conjugated Polymers: From Fundamental Understanding to Improvement in Photovoltaic Conversion Efficiency2015

    • Author(s)
      Yasunari Tamai, Hideo Ohkita, Hiroaki Benten, Shinzaburo Ito
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 6 Pages: 3417-3428

    • NAID

      120005672540

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Highly Efficient Exciton Harvesting and Charge Transport in Ternary Blend Solar Cells Based on Wide- and Low-Bandgap Polymers2015

    • Author(s)
      Yanbin Wang, Hideo Ohkita, Hiroaki Benten, Shinzaburo Ito
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 40 Pages: 27217-27224

    • DOI

      10.1039/c5cp05161d

    • NAID

      120005689176

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Efficient Exciton Harvesting through Long-Rnage Energy Transfer2015

    • Author(s)
      Yanbin Wang, Hideo Ohkita, Hiroaki Benten, Shinzaburo Ito
    • Journal Title

      ChemPhysChem

      Volume: 印刷中 Issue: 6 Pages: 1263-1267

    • DOI

      10.1002/cphc.201402740

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 共役高分子における一重項励起子ダイナミクス2014

    • Author(s)
      大北英生、玉井康成、郭嘉謨、辨天宏明、伊藤紳三郎
    • Journal Title

      日本写真学会誌

      Volume: 77 Pages: 301-307

    • NAID

      130005264898

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Energy Gap Dependence of Singlet Exciton Lifetimes in Non-Fullerene Acceptors2019

    • Author(s)
      Tomoki Ohmura, Shun Yamaguchi, Kota Tsujioka, Yasunari Tamai, Hideo Ohkita
    • Organizer
      Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Two-Dimensional Exciton Diffusion Dynamics in Crystalline Conjugated Polymer Thin Films2019

    • Author(s)
      Yasuhiro Murata, Kent Yamaguchi, Yasunari Tamai, Hideo Ohkita
    • Organizer
      Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 結晶性共役高分子における一重項励起子分裂2018

    • Author(s)
      吉高一輝, 笠井普文, 玉井康成, 大北英生
    • Organizer
      2018KIPS若手高分子シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fast Non-Radiative Decay of Singlet Excitons in Ultra-Low-Bandgap Polymer Films2018

    • Author(s)
      Yasunari Tamai, Tomoki Ohmura, Kota Tsujioka, Yukitomo Kasai, Shun Yamaguchi, Hideo Ohkita
    • Organizer
      2018 MRS Fall Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 結晶性共役高分子薄膜における二次元励起子拡散2018

    • Author(s)
      村田恭大, 山口賢人, 玉井康成, 大北英生
    • Organizer
      第27回ポリマー材料フォーラム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 結晶性共役高分子薄膜における一重項励起子異方性拡散2018

    • Author(s)
      玉井康成, 村田恭大, 山口賢人, 大北英生
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 結晶性共役高分子薄膜における二次元励起子拡散2018

    • Author(s)
      村田恭大, 玉井康成, 大北英生
    • Organizer
      2018年光化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非フラーレン系アクセプターの一重項励起子寿命に対するエネルギーギャップ依存性2018

    • Author(s)
      大村智貴, 玉井康成, 大北英生
    • Organizer
      第64回高分子研究発表会(神戸)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 結晶性共役高分子薄膜における二次元励起子拡散2018

    • Author(s)
      村田恭大, 玉井康成, 大北英生
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高分子太陽電池の効率向上のための最新技術2018

    • Author(s)
      大北英生
    • Organizer
      京都大学テックコネクト
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Toward Highly Efficient Polymer Solar Cells2017

    • Author(s)
      Hideo Ohkita
    • Organizer
      Global Photovoltaic Conference 2017
    • Place of Presentation
      Gwangju, Korea
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高効率高分子太陽電池のための新戦略2017

    • Author(s)
      大北英生
    • Organizer
      フォトポリマー懇話会
    • Place of Presentation
      I-siteなんば(大阪府大阪市)
    • Year and Date
      2017-01-27
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 結晶性共役高分子薄膜における励起子拡散ダイナミクス2017

    • Author(s)
      玉井康成, 山口賢人, 大北英生
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 共役高分子薄膜に生成する一重項励起子の無輻射遷移2017

    • Author(s)
      大北英生, 山口峻, 辻岡宏太, 玉井康成
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Singlet Fission in Conjugated Polymers2017

    • Author(s)
      Yasunari Tamai, Yukitomo Kasai, Hideo Ohkita
    • Organizer
      9th International Conference on Molecular Electronics and Bioelectronics (M&BE9)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 狭バンドギャップ高分子における分子内一重項励起子分裂2017

    • Author(s)
      吉高一輝, 玉井康成, 大北英生
    • Organizer
      第63回高分子研究発表会(神戸)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Limits for Photocurrent Generation in Polymer Solar Cells Consisting of Near-IR Polymers2017

    • Author(s)
      Yasunari Tamai, Shun Yamaguchi, Kota Tsujioka, Hideo Ohkita
    • Organizer
      SPIE Organic Photonics + Electronics (SPIE 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 共役高分子薄膜における一重項励起子分裂2017

    • Author(s)
      大北英生, 玉井康成, 笠井普文
    • Organizer
      公益財団法人日本化学繊維研究所第75回講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機薄膜太陽電池の高効率化を目指す新戦略2016

    • Author(s)
      大北英生
    • Organizer
      有機太陽電池研究コンソーシアム 第22回定例研究会
    • Place of Presentation
      京大宇治キャンパス(京都府宇治市)
    • Year and Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Toward Further Improvements in Photovoltaic Performance of Polymer Solar Cells2016

    • Author(s)
      Hideo Ohkita
    • Organizer
      Joint Kyoto University - Victoria University of Wellington Workshop 2016
    • Place of Presentation
      Wellington, New Zealand
    • Year and Date
      2016-11-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機薄膜太陽電池―発電機構―2016

    • Author(s)
      大北英生
    • Organizer
      光化学応用講座―有機無機ハイブリッド太陽電池の基礎技術―
    • Place of Presentation
      東京大学先端科学技術研究センター(東京都目黒区)
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] レーザ分光法による高分子太陽電池の発電素過程の解明2016

    • Author(s)
      大北英生, 玉井康成, 郭嘉謨, 辨天宏明
    • Organizer
      情報科学用有機材料 第142委員会 C部会 第71回研究会
    • Place of Presentation
      キャンパスプラザ京都(京都府京都市)
    • Year and Date
      2016-10-04
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Efficiency Limiting Factors of Solution-Processed Photovoltaics2016

    • Author(s)
      Hideo Ohkita
    • Organizer
      E-MRS 2016 Fall Meeting
    • Place of Presentation
      Warsaw, Poland
    • Year and Date
      2016-09-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 結晶性共役高分子薄膜における一重項励起子拡散2016

    • Author(s)
      山口賢人, 玉井康成, 辨天宏明, 大北英生
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高分子太陽電池の機構解明と高効率化2016

    • Author(s)
      大北英生、辨天宏明、伊藤紳三郎
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 (東京)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Singlet Fission in a Low-Bandgap Conjugated Polymer Film2015

    • Author(s)
      Yukitomo Kasai, Yasunari Tamai, Hideo Ohkita, Hiroaki Benten, Shinzaburo Ito
    • Organizer
      2015 MRS Fall Meeting
    • Place of Presentation
      Boston (USA)
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] レーザ分光法による高分子太陽電池の革新原理の探究から限界効率の追究~2015

    • Author(s)
      大北英生、玉井康成、辨天宏明、伊藤紳三郎
    • Organizer
      第5回 CSJ化学フェスタ2015
    • Place of Presentation
      タワーホール船堀 (東京)
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 狭バンドギャップ高分子薄膜における一重項励起子分裂2015

    • Author(s)
      笠井普文、玉井康成、大北英生、辨天宏明、伊藤紳三郎
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学 (宮城)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 結晶性高分子太陽電池における電荷生成ダイナミクス2015

    • Author(s)
      大北英生、玉井康成、辨天宏明、伊藤紳三郎
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学 (宮城)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 共役高分子における非緩和励起子からの高速一重項分裂2015

    • Author(s)
      大北英生、笠井普文、玉井康成、辨天宏明、伊藤紳三郎
    • Organizer
      2015年光化学討論会
    • Place of Presentation
      大阪市立大学 (大阪)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 結晶性共役高分子薄膜における一重項励起子ダイナミクス2015

    • Author(s)
      山口賢人、大北英生、玉井康成、辨天宏明、伊藤紳三郎
    • Organizer
      第61回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館 (兵庫)
    • Year and Date
      2015-07-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機薄膜太陽電池における高効率励起子捕集2015

    • Author(s)
      玉井康成、久詰修平、王艶賓、辨天宏明、大北英生、伊藤紳三郎
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 狭バンドギャップポリマーにおける一重項励起子分裂2015

    • Author(s)
      笠井普文、玉井康成、大北英生、辨天宏明、伊藤紳三郎
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学(神奈川県平塚市)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] One-Dimensional Singlet Exciton Diffusion in Regioregular Poly(3-hexylthiophene) Films2014

    • Author(s)
      Yasunari Tamai, Yuu Matsuura, Hideo Ohkita, Hiroaki Benten, Shinzaburo Ito
    • Organizer
      The 10th SPSJ International Polymer Conference (IPC 2014)
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2014-12-02 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] One-Dimensional Singlet Exciton Diffusion in Crystalline Poly(3-hexylthiophene) Films2014

    • Author(s)
      Yasunari Tamai, Yuu Matsuura, Hideo Ohkita, Hiroaki Benten, Shinzaburo Ito
    • Organizer
      The 6th World Conference on Photovoltaic Energy Conversion (WCPEC-6)
    • Place of Presentation
      京都国際会館(京都府京都市)
    • Year and Date
      2014-11-23 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 結晶性ポリチオフェンの秩序性と一重項励起子拡散ダイナミクス2014

    • Author(s)
      玉井康成、大北英生、辨天宏明、伊藤紳三郎
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 狭バンドギャップポリマーの高次励起子における高速ダイナミクス2014

    • Author(s)
      笠井普文、玉井康成、大北英生、辨天宏明、伊藤紳三郎
    • Organizer
      第60回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館(兵庫県神戸市)
    • Year and Date
      2014-07-24 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 結晶性ポリチオフェンの秩序性と一重項励起子拡散2014

    • Author(s)
      玉井康成、松浦悠、大北英生、辨天宏明、伊藤紳三郎
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Book] 光技術動向調査報告書2017

    • Author(s)
      大北英生(分担)
    • Total Pages
      4
    • Publisher
      一般財団法人光産業技術振興協会
    • Related Report
      2017 Annual Research Report

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Published: 2014-04-04   Modified: 2020-03-30  

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