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Innovation of Zeolite Synthesis/Production Method by Seed-Directed Approach

Research Project

Project/Area Number 26249118
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionThe University of Tokyo

Principal Investigator

Okubo Tatsuya  東京大学, 大学院工学系研究科(工学部), 教授 (40203731)

Co-Investigator(Kenkyū-buntansha) 脇原 徹  東京大学, 大学院工学系研究科(工学部), 准教授 (70377109)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥42,770,000 (Direct Cost: ¥32,900,000、Indirect Cost: ¥9,870,000)
Fiscal Year 2017: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2016: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥29,380,000 (Direct Cost: ¥22,600,000、Indirect Cost: ¥6,780,000)
Keywordsゼオライト / 水熱合成 / 種結晶添加 / 高速合成 / 種結晶添加法 / 結晶成長 / 水熱合成法 / OSDA / 種結晶 / 触媒 / 材料合成プロセス / ナノ多孔性材料 / 結晶化
Outline of Final Research Achievements

For synthesizing zeolite, a crystalline microporous material, hydrothermal synthesis has been widely used, and the obtained zeolite is widely utilized industrially as
catalysts, adsorbents, ion exchangers, and so on. However, there are still many obstacles for synthesizing zeolites in industry, for example, high cost raw materials (organic structure directing agent, OSDA) and long synthesis time. In this research, we investigated each problem as a barrier for industrial production and developed several methods such as OSDA-free, OSDA-replacement, and ultra-fast synthesis methods.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(28 results)

All 2018 2017 2016 2015

All Journal Article (9 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 9 results,  Acknowledgement Compliant: 6 results,  Open Access: 3 results) Presentation (19 results) (of which Int'l Joint Research: 9 results,  Invited: 3 results)

  • [Journal Article] Seed-directed synthesis of zincoaluminosilicate MSE-type zeolites using co-precipitated gels with tetraethylammonium hydroxide as a simple organic structure directing agent2018

    • Author(s)
      Sogukkanli Sibel、Iyoki Kenta、Elangovan Shanmugam P.、Itabashi Keiji、Koike Natsume、Takano Miku、Kubota Yoshihiro、Okubo Tatsuya
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 257 Pages: 272-280

    • DOI

      10.1016/j.micromeso.2017.08.032

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Seed-directed Synthesis of CON-type Zeolite Using Tetraethylammonium Hydroxide as a Simple Organic Structure-directing Agent2018

    • Author(s)
      Sibel Sogukkanli, Kenta Iyoki, Shanmugam P. Elangovan, Keiji Itabashi, Tatsuya Okubo
    • Journal Title

      Chem. Eur. J.

      Volume: 46 Pages: 1419-1421

    • DOI

      10.1002/chem.201705277

    • NAID

      130006067886

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic-free synthesis of zincoaluminosilicate zeolites from homogeneous gels prepared by a co-precipitation method2017

    • Author(s)
      Koike Natsume、Chaikittisilp Watcharop、Iyoki Kenta、Yanaba Yutaka、Yoshikawa Takeshi、Elangovan Shanmugam Palani、Itabashi Keiji、Okubo Tatsuya
    • Journal Title

      Dalton Transactions

      Volume: 46 Pages: 10837-10846

    • DOI

      10.1039/c7dt02001e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational seed-directed synthesis of MSE-type zeolites using a simple organic structure-directing agent by extending the composite building unit hypothesis2017

    • Author(s)
      Sibel Sogukkanli, Kenta Iyoki, Shanmugam P. Elangovan, Keiji Itabashi, Miku Takano, Zhendong Liu, Satoshi Inagaki, Toru Wakihara, Yoshihiro Kubota, Tatsuya Okubo
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 245 Pages: 1-7

    • DOI

      10.1016/j.micromeso.2017.02.073

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Two-Stage Crystallization of Meso- and Macroporous MFI and MEL Zeolites Using Tributylamine-Derived Diquaternary Ammonium Cations as Organic Structure-Directing Agents2017

    • Author(s)
      Sye Hoe Keoh, Watcharop Chaikittisilp, Akira Endo, Atsushi Shimojima, Tatsuya Okubo
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 90 Issue: 5 Pages: 586-594

    • DOI

      10.1246/bcsj.20170023

    • NAID

      130006770708

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Factors Governing the Formation of Hierarchically and Sequentially Intergrown MFI Zeolites by Using Simple Diquaternary Ammonium Structure-Directing Agents2016

    • Author(s)
      Sye Hoe Keoh, Watcharop Chaikittisilp, Koki Muraoka, Rino R. Mukti, Atsushi Shimojima, Prashant Kumar, Michael Tsapatsis, Tatsuya Okubo
    • Journal Title

      Chemistry of Materials

      Volume: 28 Pages: 8997-9007

    • DOI

      10.1021/acs.chemmater.6b03887

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Energy Analysis of Aluminosilicate Zeolites with Comprehensive Ranges of Framework Topologies2016

    • Author(s)
      Koki Muraoka, Watcharop Chaikittisilp, Tatsuya Okubo
    • Journal Title

      Journal of the American Chemical Society

      Volume: 138 Pages: 6184-6193

    • DOI

      10.1021/jacs.6b01341

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Highly nanoporous silicas with pore apertures near the boundary between micro- and mesopores through an orthogonal self-assembly approach2015

    • Author(s)
      Koki Muraoka, Watcharop Chaikittisilp, Yutaka Yanaba, Takeshi Yoshikawab、Tatsuya Okubo
    • Journal Title

      Chemical Communications

      Volume: 51 Pages: 10718-10721

    • DOI

      10.1039/c5cc02801a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Structure-Directing Behaviors of Tetraethylammonium Cations toward Zeolite Beta Revealed by the Evolution of Aluminosilicate Species Formed during the Crystallization Process2015

    • Author(s)
      Takaaki Ikuno, Watcharop Chaikittisilp, Zhendong Liu, Takayuki Iida, Yutaka Yanaba, Takeshi Yoshikawa, Shinji Kohara, Toru Wakihara, Tatsuya Okubo
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Pages: 14533-14544

    • DOI

      10.1021/jacs.5b11046

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 新規ジンコシリケートCHA型ゼオライトの合成とその2価イオン交換能2018

    • Author(s)
      小池夏萌・伊與木健太・Sye Hoe Keoh・Watcharop Chaikittisilp・大久保 達也
    • Organizer
      化学工学会 第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ゼオライト合成のフロンティア2018

    • Author(s)
      大久保達也
    • Organizer
      日本化学会 第98春季年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 共沈法均一ゲルを用いたジンコアルミノシリケートゼオライトのOSDA-free合成2017

    • Author(s)
      小池夏萌・Chaikittisilp Watcharop・伊與木健太・Shanmugam Palani Elangovan・板橋慶治・大久保達也
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学(東京都江東区豊洲)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 種結晶添加法によるシンプルな有機構造規定剤を用いたMSE型ゼオライトの合理的合成2017

    • Author(s)
      ソウグクカンル シベル・伊與木健太・ エランゴバン シャンムガム・板橋慶治・高野美育・劉振東・稲垣怜史・脇原徹・窪田好浩・大久保達也
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学(東京都江東区豊洲)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Seed-Directed Synthesis of Zincoaluminosilicate *BEA-type Zeolites with Higher Yields and Broader Chemical Compositions from Mechanochemically Pretreated Reactants2017

    • Author(s)
      Kenta Iyoki, Sye Hoe Keoh, Watcharop Chaikittisilp, Keiji Itabashi, Toru Wakihara, Tatsuya Okubo
    • Organizer
      The 3rd Euro-Asia Zeolite Conference
    • Place of Presentation
      バリ(インドネシア)
    • Year and Date
      2017-01-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Seed-directed, OSDA-free synthesis of zincoaluminosilicate mordenite2017

    • Author(s)
      Natsume Koike, Watcharop Chaikittisilp, Kenta Iyoki, Shanmugam P. Elangovan, Keiji Itabashi, Tatsuya Okubo
    • Organizer
      The 3rd Euro-Asia Zeolite Conference
    • Place of Presentation
      バリ(インドネシア)
    • Year and Date
      2017-01-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 均一ゲルを原料とした有機物を用いないジンコアミノシリケート * BEA、MFI、MOR型ゼオライトの合成2017

    • Author(s)
      小池夏萌 ・Watcharop Chaikittisilp ・伊與木健太 ・ Shanmugam Palani Elangovan・板橋慶治・大久保 達也
    • Organizer
      第33回ゼオライト研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis of various zinco(alumino)silicate zeolites by focusing on preparation methods of raw materials2017

    • Author(s)
      Natsume Koike, Watcharop Chaikittisilp, Kenta Iyoki, Shanmugam P. Elangovan, Keiji Itabashi, Tatsuya Okubo
    • Organizer
      Gordon Research Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Seed-Directed Synthesis of Multipore Zeolites using Tetraethylammonium Hydroxide as a Simple Organic Structure-Directing Agent2017

    • Author(s)
      Sibel Sogukkanli, Kenta Iyoki, Shanmugam P. Elangovan, Keiji Itabashi, Tatsuya Okubo
    • Organizer
      Gordon Research Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 種結晶添加法によるシンプルな有機構造規定剤を用いた CON型ゼオライトの合成2017

    • Author(s)
      ソウグクカンルシベル・伊與木健太・ エランゴバンシャンムガム・板橋慶治・大久保達也
    • Organizer
      第33回ゼオライト研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 亜鉛含有MOR型ゼオライトのOSDA-free合成2016

    • Author(s)
      小池夏萌・Watcharop Chaikittisilp・伊與木健太・Shanmugam Palani Elangovan・板橋慶治・大久保達也
    • Organizer
      第32回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区船堀)
    • Year and Date
      2016-12-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] Rational Seed-Directed Synthesis of MSE-type Zeolite usingSimple Organic Structure-Directing Agent by ExtendingComposite Building Unit Hypothesis2016

    • Author(s)
      Sibel Sogukkanli・Shannmugam P. Elangovan・板橋慶治・伊與木健太・高野美育・劉振東・稲垣怜史・脇原徹・窪田好浩・大久保達也
    • Organizer
      第32回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区船堀)
    • Year and Date
      2016-12-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] Structure-directing roles of alkali metal cations in the formation of FER-type zeolite2016

    • Author(s)
      Haruki Yoshida, Watcharop Chaikittisilp, Toru Wakihara, Tatsuya Okubo
    • Organizer
      The 12th Japan-Korea Symposium on Materials and Interfaces
    • Place of Presentation
      御殿場高原ホテル(静岡県御殿場市神山)
    • Year and Date
      2016-11-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Top-down and bottom-up approaches to nanosized and hierarchical zeolites2016

    • Author(s)
      Tatsuya Okubo
    • Organizer
      252nd ACS National Meeting and Exposition and 4th International Symposium on Mesoporous Zeolites
    • Place of Presentation
      ペンシルベニア州フィラデルフィア(米国)
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ultrafast and Continuous Flow Synthesis of High-Silica Zeolite SSZ-13 for NOx Removal2015

    • Author(s)
      劉振東・脇原徹・大島一典・西岡大輔・堀田悠介・Watcharop Chaikittisilp・松尾武士・武脇隆彦・大久保達也
    • Organizer
      第31回ゼオライト研究発表会
    • Place of Presentation
      とりぎん文化会館(鳥取県鳥取市尚徳町)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] ゼオライトベータの結晶化におけるテトラエチルアンモニウムカチオン集合体の構造規定効果2015

    • Author(s)
      Watcharop Chaikittisilp・生野敬明・脇原徹・大久保達也
    • Organizer
      第31回ゼオライト研究発表会
    • Place of Presentation
      とりぎん文化会館(鳥取県鳥取市尚徳町)
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] Insight into the Structure-Direction of Tetraethylammonium Cations in the Crystallization of Zeolite Beta2015

    • Author(s)
      Watcharop Chaikittisilp, Takaaki Ikuno, Toru Wakihara, Tatsuya Okubo
    • Organizer
      2015 AIChE Annual Meeting
    • Place of Presentation
      ユタ州ソルトレイクシティ(米国)
    • Year and Date
      2015-11-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Zeolites Using Dimers of Conventional Organic Structure-Directing Agents2015

    • Author(s)
      Sye Hoe Keoh, Watcharop Chaikittisilp, Tatsuya Okubo
    • Organizer
      2015 AIChE Annual Meeting
    • Place of Presentation
      ユタ州ソルトレイクシティ(米国)
    • Year and Date
      2015-11-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recent Progresses in Zeolite Synthesis--Beyond the Traditional Common Senses2015

    • Author(s)
      Tatsuya Okubo
    • Organizer
      2nd International Conference on Chemical Engineering, Food and Biotechnology
    • Place of Presentation
      ホーチミン(ベトナム)
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2014-04-04   Modified: 2019-03-29  

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