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Sequential upgrading and conversion of biomass with intermediate recycling system

Research Project

Project/Area Number 26249120
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionKyushu University

Principal Investigator

Hayashi Jun-ichiro  九州大学, 先導物質化学研究所, 教授 (60218576)

Co-Investigator(Kenkyū-buntansha) 工藤 真二  九州大学, 先導物質化学研究所, 助教 (70588889)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥41,210,000 (Direct Cost: ¥31,700,000、Indirect Cost: ¥9,510,000)
Fiscal Year 2016: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Fiscal Year 2015: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Fiscal Year 2014: ¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Keywordsバイオマス / 水熱処理 / リグニン / 熱分解 / 炭化 / 水素化 / 水素化分解 / リグニンモノマー / 解重合 / 密度汎関数理論 / 水素化触媒 / バイオチャーアシステッド水電解 / 水熱改質 / 炭化物 / モノマー / モノマー化 / ガス化 / コークス / リサイクル / 活性炭
Outline of Final Research Achievements

This study aimed at development of sequential chemical processes that begin with hydrothermal upgrading of biomass to upgrade it to lignin-rich solid, and produce clean char, high-strength hard carbon, syngas, hydrogen, high-surface-area activated carbon with specific surface area over 2,500 m2/g, lignin monomers, cyclohexanols, furans. During the period of study, the proof-of-concept of the following novel processes (including catalysts) have been reached; heavy-oil-recycling pyrolysis, pyrolysis of depolymerized lignin, lignin hydrogenolysis in alkaline water, hydrogenation of lignin and monomers, hot-briquetting/carbonization, electrochemical gasification of lignin and biochar, non-catalytic steam gasification of clean char.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(26 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (4 results) Journal Article (12 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 10 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 7 results,  Invited: 3 results)

  • [Int'l Joint Research] Beijing Univ. of Chem. Technol./China Univ. of Mining Technol.(China)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Gadjah Mada University(Indonesia)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Gaja Madah University(Indonesia)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] China University of Mining Technology(China)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Nano-sized nickel catalyst for deep hydrogenation of lignin monomers and first-principles insight into the catalyst preparation2017

    • Author(s)
      Shi-Chao Qi, Lu Zhang,Hisahiro Einaga, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 5 Pages: 3948-3965

    • DOI

      10.1039/c6ta08538e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Theoretical Study on Hydrogenolytic Cleavage of Intermonomer Linkages in Lignin2017

    • Author(s)
      Shi-Chao Qi, Lu Zhang, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi*
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY A

      Volume: 5 Pages: 2868-2877

    • DOI

      10.1021/acs.jpca.7b00602

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Recent application of calculations of metal complexes based on density functional theory2016

    • Author(s)
      Shi-Chao Qi, Jun-ichiro Hayashi, Lu Zhang
    • Journal Title

      RSC Advances

      Volume: 6 Pages: 77375-77395

    • DOI

      10.1039/c6ra16168e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Interactions between Volatiles and Char during Pyrolysis of Biomass: Reactive Species Determining and Reaction over Functionalized Carbon Nanotubes2016

    • Author(s)
      Yong Huang, Yalun Hu, Jun-ichiro Hayashi, Yunming Fang
    • Journal Title

      Energy & Fuels

      Volume: 30 Pages: 5758-5765

    • DOI

      10.1021/acs.energyfuels.6b00725

    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] Steam-Oxygen Gasification of Potassium-Loaded Lignite: Proof of Concept of Type IV Gasification2016

    • Author(s)
      Hua Yang, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      Energy Fuels

      Volume: 30 Pages: 1616-1627

    • DOI

      10.1021/acs.energyfuels.5b02258

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Kinetics and Mechanism of CO2 Gasification of Chars from 11 Mongolian Lignites2016

    • Author(s)
      Enkhsaruul Byambajav, Yasuyo Hachiyama, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      Energy Fuels

      Volume: 30 Pages: 1636-1646

    • DOI

      10.1021/acs.energyfuels.5b02262

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Gasification of Lignin Dissolved In Alkaline Water2015

    • Author(s)
      Hikaru Kawata, Li Chen, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      Proc. APCChE 2015 Congress

      Volume: 1 Pages: 3135992-3135992

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Modification of Reactivity and Strength of Formed Coke from Victorian Lignite by Leaching of Metallic Species2015

    • Author(s)
      Karnowo, Shinji Kudo, Aska Mori, Zayda faizah Zahara, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      ISIJ Int.

      Volume: 55 Issue: 4 Pages: 765-774

    • DOI

      10.2355/isijinternational.55.765

    • NAID

      130005066805

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Coke from Hydrothermally Treated Biomass in Sequence of Hot Briquetting and Carbonization2014

    • Author(s)
      Shinji Kudo, Aska Mori, Ryosuke Soejima, Karnowo, Seiji Nomura, Yusuke Dohi, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      ISIJ Int.

      Volume: 54 Issue: 11 Pages: 2461-2469

    • DOI

      10.2355/isijinternational.54.2461

    • NAID

      130004704993

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Examination of Kinetics of Non-catalytic Steam Gasification of Biomass/Lignite Chars and Its Relationship with the Variation of the Pore Structure2014

    • Author(s)
      Shinji Kudo, Yasuyo Hachiyama, Hyun-Seok Kim, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      Energy & Fuels

      Volume: 28 Pages: 5902-5908

    • DOI

      10.1021/ef501517n

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and Mechanism of Steam Gasification of Char from Hydrothermally Treated Woody Biomass2014

    • Author(s)
      Lei Bai,†,‡ Karnowo,† Shinji Kudo, Koyo Norinaga, Yong-gang Wang, Jun-ichiro Hayashi
    • Journal Title

      Energy & Fuels

      Volume: 28 Pages: 7133-7139

    • DOI

      10.1021/ef501898h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Characteristics of Hydrothermal Treatment of Woody Biomass and Features of Upgraded Solid2014

    • Author(s)
      Zayda Faizah Zahara,Karnowo, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Journal Title

      Innovative Energy & Environmental Chemical Engineering (ISBN 978-89-5708249-2)

      Volume: 4 Pages: 24-29

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Enhancement of pyrolytic degradation of lignin by its chemical modification through catalytic hydrogenation2016

    • Author(s)
      Toru Masumi, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      The 26th International Symposium on Chemical Engineering
    • Place of Presentation
      Seagaia Phoenix Center, Miyazaki, Japan
    • Year and Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Biochar-assisted water electrolysis2016

    • Author(s)
      Rei Nakamoto, Ri Chin, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      The 26th International Symposium on Chemical Engineering
    • Place of Presentation
      Seagaia Phoenix Center, Miyazaki, Japan
    • Year and Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics and mechanism of CO2 gasification of char from sugarcane bagasse2016

    • Author(s)
      Zayda Faizah Zahara, Daniyanto, Yasuyo Hachiyama, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      3rd Asian Conference on Biomass Science
    • Place of Presentation
      Niigata, Japan
    • Year and Date
      2016-01-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Steam-Oxygen Gasification of Potassium-Loaded Lignite: Proof of Concept of Type IV Gasification2015

    • Author(s)
      Jun-ichiro Hayashi, Hua Yang, Shinji Kudo, Koyo Norinaga
    • Organizer
      5th Sino-Australian Symposium on Advanced Coal and Biomass Utilisation Technologies
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Kinetics and Mechanism of CO2 Gasification of Chars from 11 Mongolian Lignites2015

    • Author(s)
      Enkhsaruul Byambajav, Yasuyo Hachiyama, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      5th Sino-Australian Symposium on Advanced Coal and Biomass Utilisation Technologies
    • Place of Presentation
      Wuhan, China
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Jun-ichiro Hayashi2015

    • Author(s)
      Pyrolysis and Gasification of Biomass Topic II: Pyrolysis and Carbonization of Biomass
    • Organizer
      Short Course on Biomass to Fuels & Chemicals
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Year and Date
      2015-10-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrochemical Gasification of Lignin Dissolved In Alkaline Water2015

    • Author(s)
      Hikaru Kawata, Li Chen, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      APCChE 2015 Congress
    • Place of Presentation
      Melbourne, Australia
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical Gasification of Lignin and Its Derivatives2014

    • Author(s)
      Hikaru Kawata, Ri Chin, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      The 27th International Symposium on Chemical Engineering
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Year and Date
      2014-12-05 – 2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Conversion of Lignite into Syngas in a Sequence of Dissolution, Oxidation and Catalytic Reforming in Alkaline Water2014

    • Author(s)
      Junya Tahara1, Aska Mori2, Yasuyo Hachiyama, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      The 27th International Symposium on Chemical Engineering
    • Place of Presentation
      Kuala Lumpur, Malaysia
    • Year and Date
      2014-12-05 – 2014-12-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Characteristics of Hydrothermal Treatment of Woody Biomass and Features of Upgraded Solid2014

    • Author(s)
      Zayda Faizah Zahara,Karnowo, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      The 4th Asian Conference on Innovative Energy & Environmental Chemical Engineering
    • Place of Presentation
      Yoesu, Korea
    • Year and Date
      2014-11-09 – 2014-11-12
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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