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Dry-process, labo-level fabrication of de-hydrogenated catalysts based on surface nano-structure control

Research Project

Project/Area Number 26249150
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionTohoku University

Principal Investigator

WADAYAMA TOSHIMASA  東北大学, 環境科学研究科, 教授 (20184004)

Co-Investigator(Kenkyū-buntansha) 田邉 匡生  東北大学, 工学研究科, 准教授 (10333840)
Co-Investigator(Renkei-kenkyūsha) TODOROKI NAOTO  東北大学, 大学院環境科学研究科, 助教 (10734345)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥41,600,000 (Direct Cost: ¥32,000,000、Indirect Cost: ¥9,600,000)
Fiscal Year 2017: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Fiscal Year 2014: ¥20,280,000 (Direct Cost: ¥15,600,000、Indirect Cost: ¥4,680,000)
Keywords触媒・化学プロセス / ナノ材料 / 表面・界面物性 / 燃料電池 / エネルギーキャリア / 二酸化炭素電解還元
Outline of Final Research Achievements

Molecular behaviors of several molecules, e.g., energy carrier molecules, organic hydrides, alcohol, carbon dioxide on electrode surfaces are important subjects for future energy systems and, therefore, developments of effective electro-catalysts with suitable surface atomic arrangements and compositions are required. In this study, well-defined model catalysts (X/M(hkl)) are fabricated through molecular beam epitaxy (MBE) of alloying elements X on the low-index single crystal surfaces of Pt and Au (M(hkl); M=Pt, Au)). Then, surface structural analysis, electrochemical measurements are performed for the prepared X/M(hkl) model catalysts and discussed the relation between surface atomic arrangements, alloy compositions and catalytic properties.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (16 results)

All 2018 2017 2016 2015 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) (of which Int'l Joint Research: 1 results) Remarks (1 results)

  • [Journal Article] On-Line Mass Spectrometry for Ethanol Oxidation on Well-Defined Sn/Pt(hkl) Electrode Surfaces2016

    • Author(s)
      H. Nakamura, T. Inoue, T. Matsuda, N. Todoroki, T. Wadayama
    • Journal Title

      ECS Transactions

      Volume: 75 Issue: 14 Pages: 1029-1033

    • DOI

      10.1149/07514.1029ecst

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Reduction of CO2 on Ni- and Pt-Epitaxially Grown Cu(111) Surfaces2016

    • Author(s)
      N. Todoroki, N. Yokota, S. Nakahata, H. Nakamura, T. Wadayama
    • Journal Title

      Electrocatalysis

      Volume: 7 Issue: 1 Pages: 97-103

    • DOI

      10.1007/s12678-015-0286-6

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] コバルト表面修飾金単結晶表面における二酸化炭素電解還元反応生成物分析2018

    • Author(s)
      和田山 智正, 程 宏輝,鶴巻 碩人, 宮川 拓, 望月 智裕, 轟 直人
    • Organizer
      日本金属学会2018年春期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pt電極表面における酸素還元反応の回転ディスク-オンライン質量分析2018

    • Author(s)
      鶴巻 碩人, 望月 智裕,程 宏輝,轟 直人,和田山 智正
    • Organizer
      第85回電気化学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Au電極上におけるCO2還元生成物のオンライン質量分析2018

    • Author(s)
      轟 直人, 程 宏輝, 鶴巻 碩人, 望月 智裕, 宮川 拓, 和田山 智正
    • Organizer
      第85回電気化学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Au(hkl)表面におけるCO2電解還元反応生成物のオンライン電気化学質量分析2017

    • Author(s)
      程 宏輝,鶴巻 碩人,井上 達彦,轟 直人,和田山 智正
    • Organizer
      第84回電気化学会
    • Place of Presentation
      首都大学東京南大沢キャンパス、東京都八王子市
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Au基合金単結晶表面系におけるCO2電解還元生成物のオンライン電気化学質量分析2017

    • Author(s)
      程 宏輝, 鶴巻 碩人, 井上 達彦, 轟 直人, 和田山 智正
    • Organizer
      電気化学会第30回東北若手の会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Au(hkl)表面合金系におけるCO2電解還元生成物のその場分析2017

    • Author(s)
      程 宏輝, 鶴巻 碩人, 井上 達彦, 轟 直人, 和田山 智正
    • Organizer
      第10回新電極触媒シンポジウム&宿泊セミナー
    • Related Report
      2017 Annual Research Report
  • [Presentation] Online Electrochemical Mass Spectrometry for electrochemical CO2 reduction products on Au(hkl) Surfaces2017

    • Author(s)
      H. Tei, H. Tsurumaki, T. Inoue, N. Todoroki and T. Wadayama
    • Organizer
      ISSS-8
    • Related Report
      2017 Annual Research Report
  • [Presentation] よく規定されたAu表面における二酸化炭素電解還元過程のオンライン電気化学質量分析2017

    • Author(s)
      鶴巻 碩人, 程 宏輝, 轟 直人, 和田山 智正
    • Organizer
      日本金属学会 2017年秋期講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] On-Line Mass Spectrometry for Ethanol Oxidation on Well-Defined Sn/Pt(hkl) Electrode Surfaces2016

    • Author(s)
      H. Nakamura, T. Inoue, T. Matsuda, N. Todoroki, T. Wadayama
    • Organizer
      PRiME2016
    • Place of Presentation
      Hawaii Convention Center、USA
    • Year and Date
      2016-10-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] メチルシクロヘキサンの熱的脱水素反応で用いる蒸着Pt-Co合金触媒の活性な表面組成探索2016

    • Author(s)
      程 宏輝, 中村 大樹, 轟 直人, 和田山 智正
    • Organizer
      日本金属学会2016年秋期講演大会
    • Place of Presentation
      大阪大学豊中キャンパス、大阪府豊中市
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Sn/Pt(hkl)電極表面におけるエタノール酸化反応のオンライン質量分析2016

    • Author(s)
      中村 大樹, 井上 達彦, 松田 哲彦, 轟 直人, 和田山 智正
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学、大阪府吹田市
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 貴金属表面におけるメチルシクロヘキサンの電気化学挙動2015

    • Author(s)
      中村 大樹, 井上 達彦, 尾本 洋二, 轟 直人, 和田山 智正
    • Organizer
      日本金属学会2015年秋期講演大会
    • Place of Presentation
      九州大学、福岡県福岡市
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 白金基板上におけるメチルシクロヘキサンの電気化学的挙動2015

    • Author(s)
      井上達彦,尾本洋二,中村大樹,轟直人,和田山智正
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Remarks] 有機水素キャリアの脱水素化

    • URL

      http://www.material.tohoku.ac.jp/~kaimenb/research2.html

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report 2014 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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