Synthesis of Zeolite-Templated Carbon from Ionic Liquids

• Project/Area Number: 26286020
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Nanomaterials engineering
• Research Institution: Tohoku University
• Principal Investigator: Nishihara Hirotomo 東北大学, 多元物質科学研究所, 准教授 (80400430)
• Co-Investigator(Renkei-kenkyūsha): KYOTANI TAKASHI 東北大学, 多元物質科学研究所, 教授 (90153238) ; TSUDA TETSUYA 大阪大学, 工学研究科, 准教授 (90527235) ; TANAKA HIDEKI 京都大学, 工学研究科, 准教授 (80376368)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000); Fiscal Year 2016: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2015: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000); Fiscal Year 2014: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
• Keywords: 多孔質炭素 / グラフェン / ホウ素ドープ / 窒素ドープ / イオン液体 / ゼオライト / ヘテロ原子 / 電気化学キャパシタ / 燃料電池

Outline of Final Research Achievements

Zeolite-templated carbons enriched by B and N were successfully prepared by using ionic liquid as a partial carbon source. The resulting BN-doped carbon exhibited a better catalytic activity for oxygen-reduction reaction than that of N-doped zeolite-templated carbon.
By an electrochemical method, zeolite-templated carbons could be functionalized by quinone-type and ether-type groups and they exhibited a large pseudocapacitance in an organic electrolyte to achieve 330 F/g of total capacitance.
Zeolite-templated carbons could be decorated by sub-nanometer Pt clusters. The resulting sample exhibited a high activity for hydrogen spillover even at a room temperature.

Research Products

• [Int'l Joint Research] Ben-Gurion University of the Negev(イスラエル)
• [Int'l Joint Research] Ioffe Physical-Technical Institute(ロシア連邦)
• [Int'l Joint Research] CSIC(スペイン)
• [Int'l Joint Research] Universidad de Alicante/University of Malaga(スペイン)
• [Int'l Joint Research] Thammasat University/Kasetsart University(タイ)
• [Journal Article] Nuclear magnetic resonance study of zeolite-templated carbon (2016)
  • Author(s): A. M. Panich, V. Y. Osipov, H. Nishihara, T. Kyotani
  • Journal Title: Synthetic Metals Volume: 221 Pages: 149-152
  • DOI: 10.1016/j.synthmet.2016.08.021
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Effect of heteroatoms in ordered microporous carbons on their electrochemical capacitance (2016)
  • Author(s): H. Itoi, H. Nishihara, T. Kyotani
  • Journal Title: Langmuir Volume: 32 Issue: 46 Pages: 11997-12004
  • DOI: 10.1021/acs.langmuir.6b02667
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Pseudocapacitance of Zeolite-Templated Carbon in Organic Electrolytes (2015)
  • Author(s): Khanin Nueangnoraj, Hirotomo Nishihara, Takafumi Ishii, Norihisa Yamamoto, Hiroyuki Itoi, Raúl Berenguer, Ramiro Ruiz-Rosas, Diego Cazorla-Amorós, Emilia Morallón, Masashi Ito, Takashi Kyotani
  • Journal Title: Energy Storage Materials Volume: 1 Pages: 35-41
  • DOI: 10.1016/j.ensm.2015.08.003
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Study on Electrochemical Capacitance using Templated Carbons (2015)
  • Author(s): Nishihara, Hiromoto, Itoi, Hiroyuki, Nueangnoraj, Khanin, Berenguer, Raul, Berenguer-Murcia, Angel, Ruiz-Rosas, Ramiro, Cazorla-Amoros, Diego, Morallon, Emilia, Kyotani, Takashi
  • Journal Title: Boletin del Grupo Espanol del Carbon Volume: 37 Pages: 6-8
  • Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Characterization of a zeolite-templated carbon by electrochemical quartz crystal microbalance and in situ Raman (2015)
  • Author(s): S. Leyva-Garcia, K. Nueangnoraj, D. Lozano-Castello, H. Nishihara, T. Kyotani, E. Morallon, D. Cazorla-Amoros
  • Journal Title: Carbon Volume: 89 Pages: 63-73
  • DOI: 10.1016/j.carbon.2015.03.016
  • Peer Reviewed
• [Journal Article] Photocatalytic Performance of TiO2-Zeolite Templated Carbon Composites in Organic Contaminant Degradation (2014)
  • Author(s): W. Donphai, T. Kamegawa, M. Chareonpanich, K. Nueangnoraj, H. Nishihara, T. Kyotani, H. Yamashita
  • Journal Title: Physical Chemistry Chemical Physics Volume: 16 Issue: 45 Pages: 25004-25007
  • DOI: 10.1039/c4cp03897e
  • Peer Reviewed / Open Access
• [Journal Article] Preparation of Highly Dispersed Pt Nanoparticles Supported on Zeolite-templated Carbon and Catalytic Application in Hydrogenation Reaction (2014)
  • Author(s): Jiang, C.; Hara, K. Namba, K.; Kobayashi, H.; Ittisanronnachai, S.; Nishihara, H.; Kyotani, T.; Fukuoka, A.
  • Journal Title: Chemistry Letters Volume: 43 Issue: 11 Pages: 1794-1796
  • DOI: 10.1246/cl.140699
  • NAID: 130004677610
  • Peer Reviewed
• [Presentation] 単層グラフェン多孔体 (2017)
  • Author(s): 西原洋知
  • Organizer: 第17回ナノテク高機能テキスタイル基盤技術研究会
  • Place of Presentation: 信州大学（上田市）
  • Invited
• [Presentation] Elastic carbon nanosponges (2017)
  • Author(s): Hirotomo Nishihara
  • Organizer: CBNM5
  • Place of Presentation: 信州大学（長野市）
  • Int'l Joint Research / Invited
• [Presentation] カーボン系材料のナノ空間制御とエネルギー貯蔵への応用 (2016)
  • Author(s): 西原洋知
  • Organizer: 第30回日本吸着学会研究発表会
  • Place of Presentation: 長崎大学（長崎市）
  • Year and Date: 2016-11-10
  • Invited
• [Presentation] Oxidation-resistant and elastic mesoporous carbon with single-layer graphene walls (2016)
  • Author(s): Hirotomo Nishihara
  • Organizer: The 3rd CWRU-Tohoku Joint workshop
  • Place of Presentation: 東北大学（仙台市）
  • Year and Date: 2016-08-09
  • Int'l Joint Research / Invited
• [Presentation] Preparation of a high surface area ordered microporous carbon co-doped with nitrogen and boron (2016)
  • Author(s): Alberto Castro-Muniz, Hirotomo Nishihara, Tetsuya Hirota, Mao Ohwada, Li Li-Xiang, Tetsuya Thuda, Susumu Kuwabata, and Takashi Kyotani
  • Organizer: CWRU-TU 3rd Joint workshop
  • Place of Presentation: 東北大学（仙台市）
  • Year and Date: 2016-08-09
• [Presentation] Nitrogen and boron co-doping in ordered microporous carbon by using hard template method (2016)
  • Author(s): Alberto Castro-Muniz, Hirotomo Nishihara, Tetsuya Hirota, Mao Ohwada, Li-Xiang Li, Tetsuya Thuda, Susumu Kuwabata, and Takashi Kyotani
  • Organizer: Carbon2016
  • Place of Presentation: Pennsylvania, USA
  • Year and Date: 2016-07-10
• [Presentation] Graphene-based 3D frameworks for electrochemical capacitors (2016)
  • Author(s): Hirotomo Nishihara, Takashi Kyotani
  • Organizer: 2016 International Conference on Advanced Capacitors
  • Place of Presentation: びわ湖大津プリンスホテル（大津市）
  • Year and Date: 2016-05-23
  • Int'l Joint Research / Invited
• [Presentation] 有機電解液中における炭素材料の陽極劣化とエッジサイトの関係 (2016)
  • Author(s): 田口海志、西原洋知、京谷隆、石井孝文、村松康司、Diego Cazolra-Amoros
  • Organizer: 先端技術セミナー2016
  • Place of Presentation: イーグレひめじ（姫路市）
  • Year and Date: 2016-03-04
• [Presentation] グラフェン多孔体による高耐電圧キャパシタ (2016)
  • Author(s): 西原洋知
  • Organizer: 第6回CSJ化学フェスタ2016
  • Place of Presentation: タワーホール船堀（東京）
  • Invited
• [Presentation] 炭素材料の構造と電気化学的劣化との相関 (2016)
  • Author(s): 西原洋知
  • Organizer: 電気化学セミナー4 「研究・開発のための電気化学測定法」エネルギーデバイスの解析・評価技術
  • Place of Presentation: 東京理科大学神楽坂キャンパス（東京）
  • Invited
• [Presentation] グラフェン系多孔体電極 (2016)
  • Author(s): 西原洋知
  • Organizer: 第12回スキルアップセミナー
  • Place of Presentation: 日本教育会館8階第三会議室（東京）
  • Invited
• [Presentation] Nanoporous materials with single-layer graphene walls (2016)
  • Author(s): Hirotomo Nishihara
  • Organizer: KU-GCG Forum 2016 - Green Innovation for Future
  • Place of Presentation: バンコク, タイ
  • Int'l Joint Research / Invited
• [Presentation] Graphene-based porous frameworks for supercapacitors (2016)
  • Author(s): Hirotomo Nishihara, Takashi Kyotani
  • Organizer: 5th International Conference from Nanoparticles and Nanomaterials to Nanodevices and Nanosystems
  • Place of Presentation: Porto Heli, Greece
  • Int'l Joint Research / Invited
• [Presentation] Graphene-based 3D frameworks for energy storage (2016)
  • Author(s): Hirotomo Nishihara, Takashi Kyotani
  • Organizer: The International Conference on Small Science
  • Place of Presentation: Purague, Czech Republic
  • Int'l Joint Research / Invited
• [Presentation] Preparation of carbon-based fusion materials and their applications (2015)
  • Author(s): H. Nishihara, T. Kyotani
  • Organizer: Pacifichem2015
  • Place of Presentation: Honolulu, アメリカ
  • Year and Date: 2015-12-15
  • Int'l Joint Research / Invited
• [Presentation] 電気二重層キャパシタ電極カーボンの酸化劣化とエッジ構造との関係 (2015)
  • Author(s): 西原洋知、田口海志、石井孝文、村松康司、Diego Cazolra-Amoros、京谷隆
  • Organizer: 第5回酸化グラフェンシンポジウム
  • Place of Presentation: 岡山大学（岡山市）
  • Year and Date: 2015-12-11
• [Presentation] Preparation of a nitrogen and boron co-doped ordered microporous carbon with high surface area (2015)
  • Author(s): Arberto Castro-Muniz, Hirotomo Nishihara, Tetsuya Hirota, Mao Ohwada, Li Li-Xiang, Tetsuya Tsuda, Susumu Kuwabata, Takashi Kyotani
  • Organizer: 第42回炭素材料学会年会
  • Place of Presentation: 関西大学千里山キャンパス（吹田市）
  • Year and Date: 2015-12-02
• [Presentation] 炭素材料の電気化学的耐性とエッジサイトの関係 (2015)
  • Author(s): 田口海志、西原洋知、京谷隆、石井孝文、村松康司、Diego Cazolra-Amoros
  • Organizer: 第42回炭素材料学会年会
  • Place of Presentation: 関西大学千里山キャンパス（吹田市）
  • Year and Date: 2015-12-02
• [Presentation] Relationships between electrochemical stability and edge sites in carbon materials (2015)
  • Author(s): Kaishi Taguchi, Hirotomo Nishihara, Takashi Kyotani, Takafumi Ishii, Yasuji Muramatsu, Diego Cazolra-Amoros
  • Organizer: Campus Asia Shanghai Symposium
  • Place of Presentation: Shanghai, 中国
  • Year and Date: 2015-11-04
  • Int'l Joint Research
• [Presentation] Zeolite-templated carbons for supercapacitors (2015)
  • Author(s): H. Nishihara
  • Organizer: GRAPHCHINA2015
  • Place of Presentation: Qingdao, 中国
  • Year and Date: 2015-10-28
  • Int'l Joint Research / Invited
• [Presentation] 鋳型法で合成した炭素材料のエネルギー貯蔵材としての応用 (2015)
  • Author(s): 西原洋知、干川康人、Castro-Muniz Alberto、京谷隆
  • Organizer: 第64回高分子討論会
  • Place of Presentation: 東北大学 川内キャンパス（仙台市）
  • Year and Date: 2015-09-15
• [Presentation] 臭素またはカルバゾール基によるエッジ選択的化学修飾をほどこしたゼオライト鋳型炭素材料の合成と光物性 (2015)
  • Author(s): 田嶋智之、後藤良子、小林和正、高口豊、Nueangnoraj Khanin、京谷隆、西原洋知
  • Organizer: 第64回高分子討論会
  • Place of Presentation: 東北大学 川内キャンパス（仙台市）
  • Year and Date: 2015-09-15
• [Presentation] Mesoporous Silica Coated with Nitrogen-Doped Carbon as Model Material for Electrochemical Applications (2015)
  • Author(s): Alberto Castro-Muniz, Yasuto Hoshikawa, Dae-Soo Yang, Hirotomo Nishihara, Jong-Sung Yu, Takashi Kyotani
  • Organizer: 平成27年度化学系学協会東北大会
  • Place of Presentation: 弘前大学（弘前市）
  • Year and Date: 2015-09-12
• [Presentation] Nanocarbons and composite materials for energy storage (2015)
  • Author(s): H. Nishihara
  • Organizer: Special Seminar at University of Chile
  • Place of Presentation: Santiago, チリ
  • Year and Date: 2015-08-28
  • Int'l Joint Research / Invited
• [Presentation] Nanocarbons and composite materials for energy storage (2015)
  • Author(s): H. Nishihara
  • Organizer: Special Seminar at University of Concepcion
  • Place of Presentation: Concepcion, チリ
  • Year and Date: 2015-08-25
  • Int'l Joint Research / Invited
• [Presentation] 高比表面積キャパシタ電極炭素のエッジ構造 (2015)
  • Author(s): 田口海志、西原洋知、京谷隆、石井孝文、村松康司、Diego Cazorla-Amoros
  • Organizer: 第53回炭素材料夏季セミナー
  • Place of Presentation: 東京ソラマチ（墨田区）
  • Year and Date: 2015-08-10
• [Presentation] Characterization of a zeolite-templated carbon by in situ Raman spectroscopy (2015)
  • Author(s): S. Leyva-García, K. Nueangnoraj, D. Lozano-Castello, H. Nishihara, T. Kyotani, E. Morallon, D. Cazorla-Amoros
  • Organizer: Carbon2015
  • Place of Presentation: Dresden, ドイツ
  • Year and Date: 2015-07-12
  • Int'l Joint Research
• [Presentation] Novel fabrication of micro-supercapacitors through electrospray of nanostructured carbon materials (2015)
  • Author(s): Ramiro R. Ruiz-Rosas, J. M. Rosas-Martinez, Raul Berenguer, Hirotomo Nishihara, Tkashi Kyotani, Jose Rodriguez-Mirasol, Tomas Cordero, Emilia Morallon, Diego Cazorla-Amoros
  • Organizer: Carbon2015
  • Place of Presentation: Dresden, ドイツ
  • Year and Date: 2015-07-12
  • Int'l Joint Research
• [Presentation] Quinone-functionalized zeolite-templated carbon as the electrodes for high energy density redox capacitor (2015)
  • Author(s): Khanin Nueangnoraj, Takaaki Tomai, Hirotomo Nishihara, Takashi Kyotani, Itaru Honma
  • Organizer: Carbon2015
  • Place of Presentation: Dresden, ドイツ
  • Year and Date: 2015-07-12
  • Int'l Joint Research
• [Presentation] Zeolite-Templated Carbons and Their Applications (2015)
  • Author(s): H. Nishihara, T. Kyotani
  • Organizer: International Symposium on Zeolites and MicroPorous Crystals 2015
  • Place of Presentation: Sapporo, 日本
  • Year and Date: 2015-06-28
  • Int'l Joint Research / Invited
• [Presentation] グラフェンから成る多孔体とその酸化特性 (2015)
  • Author(s): 西原洋知
  • Organizer: 第4回酸化グラフェン研究会
  • Place of Presentation: 熊本大学（熊本市）
  • Year and Date: 2015-06-26
  • Invited
• [Presentation] Redox capacitor with high energy density derived from quinone-dopped zeolite-templated carbon (2015)
  • Author(s): Khanin Nueangnoraj, 笘居高明, 西原洋知, 京谷 隆, 本間 格
  • Organizer: 電気化学会第82回大会
  • Place of Presentation: 横浜
  • Year and Date: 2015-03-15 – 2015-03-17
• [Presentation] Nanocarbons and composite materials for energy storage (2015)
  • Author(s): H. Nishihara, T. Kyotani
  • Organizer: Pure and Applied Chemistry International Conference 2015
  • Place of Presentation: Bangkok, Thailand
  • Year and Date: 2015-01-21 – 2015-01-23
  • Invited
• [Presentation] Templated Carbons and Carbon Composite Materials with Their Remarkable Potential in Energy Storage (2015)
  • Author(s): H. Nishihara, T. Kyotani
  • Organizer: Special Seminar at Kasetsart University
  • Place of Presentation: Bangkok, Thailand
  • Year and Date: 2015-01-20
  • Invited
• [Presentation] 有機電解液におけるゼオライト鋳型炭素の疑似容量 (2014)
  • Author(s): 西原洋知、田口海志、Khanin Nueangnoraj、石井孝文、京谷隆
  • Organizer: 第3回酸化グラフェンシンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2014-12-18
• [Presentation] Templated nanocarbons and carbon-coated materials for energy storage (2014)
  • Author(s): Hirotomo Nishihara, Takashi Kyotani
  • Organizer: 第41回炭素材料学会年会
  • Place of Presentation: 福岡
  • Year and Date: 2014-12-08 – 2014-12-10
  • Invited
• [Presentation] Quinone-functionalized zeolite templated-carbon for high energy density capacitors (2014)
  • Author(s): Khanin Nueangnoraj, Takaaki Tomai, Ramiro Ruiz-Rosas, Emilia Morallon, Diego Cazorla-Amoros, Hirotomo Nishihara, Takashi Kyotani, Itaru Honma
  • Organizer: 第55回電池討論会
  • Place of Presentation: 京都
  • Year and Date: 2014-11-19 – 2014-11-21
• [Presentation] Templated nanocarbons and carbon-coated materials for energy storage (2014)
  • Author(s): H. Nishihara
  • Organizer: MANA semimar at NIMS
  • Place of Presentation: つくば
  • Year and Date: 2014-10-24
  • Invited
• [Presentation] 黒鉛及び高温処理炭素のエッジ面の分析に基づく構造解析とその応用 (2014)
  • Author(s): 石井孝文，柏原進，大谷尚史，小林俊介，干川康人，西原洋知，京谷隆，鏑木裕，吉田明，菱山幸宥，神成尚克， 尾崎純一，高井和之，榎敏明
  • Organizer: 平成26年度化学系学協会東北大会
  • Place of Presentation: 山形
  • Year and Date: 2014-09-20 – 2014-09-21
• [Presentation] Hybrid aqueous redox capacitor using molecular quinone-doped zeolite templated-carbon as an electrode (2014)
  • Author(s): Khanin Nueangnoraj、小松大輝、笘居高明、西原洋知、京谷隆、本間格
  • Organizer: 第46回化学工学会秋季大会
  • Place of Presentation: 福岡
  • Year and Date: 2014-09-17 – 2014-09-19
• [Presentation] Pseudocapacitance of zeolite-templated carbon in organic electrolytes (2014)
  • Author(s): H. Nishihara
  • Organizer: 2nd Spain-Japan Joint Symposium for Advanced Supercapacitors
  • Place of Presentation: Malaga, Spain
  • Year and Date: 2014-09-17 – 2014-09-19
  • Invited
• [Presentation] Nanocarbons and composite materials for energy applications (2014)
  • Author(s): H. Nishihara, T. Kyotani
  • Organizer: XXIII International Materials Research Congress 2014
  • Place of Presentation: Cancun, Mexico
  • Year and Date: 2014-08-17 – 2014-08-21
  • Invited
• [Presentation] Nanocarbons and composite materials for energy applications (2014)
  • Author(s): H. Nishihara
  • Organizer: Special Seminar at UNIST
  • Place of Presentation: Ulsan, Korea
  • Year and Date: 2014-07-04
  • Invited
• [Presentation] Electrospray and Electrospinning Processing of ZTC and ZTC-Based Composites (2014)
  • Author(s): J.M. Rosas, R. Berenguer, R. Ruiz-Rosas, D. Cazorla-Amoros, E. Morallon, H. Nishihara, T. Kyotani, J. Rodriguez-Mirasol, T. Cordero
  • Organizer: ANQUE ICCE BIOTEC
  • Place of Presentation: Madrid, Spain
  • Year and Date: 2014-07-01 – 2014-07-04
• [Presentation] Enhanced electro-oxidation/corrosion resistance of carbon electrodes induced by phosphorous-containing surface groups (2014)
  • Author(s): Raul Berenguer, Ramiro Ruiz-Rosas, Aurora Gallardo-Fuentes, Diego Cazorla-Amoros, Emilia Morallon, Hirotomo Nishihara, Takashi Kyotani, Jose Rodriguez-Mirasol, Tomas Cordero
  • Organizer: Carbon2014
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2014-06-29 – 2014-07-04
• [Presentation] Unique Redox Behavior of Zeolite-Templated Carbon in Organic Electrolytes (2014)
  • Author(s): Hirotomo Nishihara, Khanin Nueangnoraj, Norihisa Yamamoto, Raul Berenguer, Hiroyuki Itoi, Masashi Ito, Takashi Kyotani
  • Organizer: Carbon2014
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2014-06-29 – 2014-07-04
• [Presentation] エッジにキノンをドープしたゼオライト鋳型炭素の疑似容量 (2014)
  • Author(s): 西原洋知、京谷隆
  • Organizer: 第2回酸化グラフェンシンポジウム
  • Place of Presentation: 熊本
  • Year and Date: 2014-06-24
• [Book] ナノ空間材料ハンドブック (2016)
  • Author(s): 西原洋知, 京谷隆
  • Total Pages: 15
  • Publisher: NTS
• [Remarks] 東北大学 多元物質科学研究所 京谷研究室 西原洋知
  • URL: http://www.tagen.tohoku.ac.jp/labo/kyotani/nishihara/nishihara.html
• [Remarks] 西原洋知 個人のページ
  • URL: http://www.tagen.tohoku.ac.jp/labo/kyotani/nishihara/nishihara.html