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Development of C-H Transformations Using Noncovalent Interactions

Research Project

Project/Area Number 26288014
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionKyushu University (2015-2017)
The University of Tokyo (2014)

Principal Investigator

Kuninobu Yoichiro  九州大学, 先導物質化学研究所, 教授 (40372685)

Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2014: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
KeywordsC-H結合変換 / 非共有結合性相互作用 / 水素結合 / Lewis酸-塩基相互作用 / ボリル化 / シリル化 / メタ位 / オルト位 / 位置選択性
Outline of Final Research Achievements

I conducted researches aimed at developing high regioselective carbon-hydrogen (C-H) bond transformations using noncovalent interactions, such as a Lewis acid-base interaction or a hydrogen bonding. As a result, I developed meta-selective C(sp2)-H bond transformation utilizing the hydrogen bonding and ortho-selective C(sp2)-H bond transformation using the Lewis acid-base interaction. These reactions are the first examples that control the regioselectivity of C-H bond transformations by hydrogen bonding or Lewis acid-base interaction between a ligand of the catalyst and a substrate. In addition, I could achieve to creat a new regiocontrol method in C-H bond transformations.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (83 results)

All 2018 2017 2016 2015 2014 Other

All Journal Article (20 results) (of which Peer Reviewed: 19 results,  Acknowledgement Compliant: 10 results,  Open Access: 2 results) Presentation (54 results) (of which Int'l Joint Research: 16 results,  Invited: 9 results) Book (2 results) Remarks (4 results) Patent(Industrial Property Rights) (3 results) (of which Overseas: 2 results)

  • [Journal Article] Palladium-Catalyzed Synthesis of Diaryl Ketones from Aldehydes and (Hetero)Aryl Halides via C?H Bond Activation2018

    • Author(s)
      Wakaki Takayuki、Togo Takaya、Yoshidome Daisuke、Kuninobu Yoichiro、Kanai Motomu
    • Journal Title

      ACS Catal.

      Volume: 8 Issue: 4 Pages: 3123-3128

    • DOI

      10.1021/acscatal.8b00440

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents2017

    • Author(s)
      Wang Zijia、Kanai Motomu、Kuninobu Yoichiro
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 9 Pages: 2398-2401

    • DOI

      10.1021/acs.orglett.7b00923

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron-Catalyzed ortho-Selective C?H Borylation of 2-Phenylpyridines and Their Analogs2017

    • Author(s)
      Yoshigoe Yusuke、Kuninobu Yoichiro
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 13 Pages: 3450-3453

    • DOI

      10.1021/acs.orglett.7b01423

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iridium/Bipyridine-Catalyzed ortho-Selective C?H Borylation of Phenol and Aniline Derivatives2017

    • Author(s)
      Li Hong-Liang、Kanai Motomu、Kuninobu Yoichiro
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 21 Pages: 5944-5947

    • DOI

      10.1021/acs.orglett.7b02936

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lewis Acid-Base Interaction-Controlled ortho-Selective C-H Borylation of Aryl Sulfides2017

    • Author(s)
      Hong-Liang Li, Yoichiro Kuninobu, Motomu Kanai
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 6 Pages: 1495-1499

    • DOI

      10.1002/anie.201610041

    • Related Report
      2016 Annual Research Report
    • Open Access / Acknowledgement Compliant
  • [Journal Article] Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C-H Bond Activation2016

    • Author(s)
      Sueki, S.; Wang, Z.; Kuninobu, Y.
    • Journal Title

      Org. Lett.

      Volume: 18 Issue: 2 Pages: 304-307

    • DOI

      10.1021/acs.orglett.5b03474

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolines via Insertion of Carbodiimides into a C-H Bond of Aromatic and Heteroaromatic Imidates2016

    • Author(s)
      Zijia Wang, Shunsuke Sueki, Motomu Kanai, Yoichiro Kuninobu
    • Journal Title

      Org. Lett.

      Volume: 18 Issue: 10 Pages: 2459-2462

    • DOI

      10.1021/acs.orglett.6b01012

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] The Development of Novel C-H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules2016

    • Author(s)
      Yoichiro Kuninobu
    • Journal Title

      J. Synth. Org. Chem. Jpn.

      Volume: 74 Pages: 1058-1068

    • NAID

      130005433327

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Iridium-Catalyzed ortho-Selective C-H Silylation of Aromatic Compounds Directed toward the Synthesis of pai-Conjugated Molecules with Lewis Acid-Base Interaction2015

    • Author(s)
      Wakaki, T.; Kanai, M.*; Kuninobu, Y.*
    • Journal Title

      Org. Lett.

      Volume: 17 Issue: 7 Pages: 1758-1761

    • DOI

      10.1021/acs.orglett.5b00529

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copper-Catalyzed Intermolecular C(sp3)-H Bond Functionalization Towards the Synthesis of Tertiary Carbamates2015

    • Author(s)
      Chikkade, Prasanna Kumara; Kuninobu, Yoichiro; Kanai, Motomu
    • Journal Title

      Chem. Sci.

      Volume: 6 Issue: 5 Pages: 3195-3200

    • DOI

      10.1039/c5sc00238a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Rhodium-Catalyzed Synthesis of Multi-Substituted Silylindenes from Aryl Alkynes and Hydrosilanes via C-H Bond Activation2015

    • Author(s)
      Shunsuke Sueki, Yoichiro Kuninobu
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 36 Pages: 7685-7688

    • DOI

      10.1039/c5cc01569c

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Palladium-Catalyzed Construction of Heteroatom-Containing pai-Conjugated Systems by Intramolecular Oxidative C-H/C-H Coupling Reaction2015

    • Author(s)
      Saito, Kenta; Chikkade, Prasanna Kumara; Kanai, Motomu; Kuninobu, Yoichiro
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 23 Pages: 8365-8368

    • DOI

      10.1002/chem.201501116

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C-H Bond Activation2015

    • Author(s)
      Wang, Zhen; Kuninobu, Yoichiro; Kanai, Motomu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 137 Issue: 19 Pages: 6140-6143

    • DOI

      10.1021/jacs.5b02435

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A meta-selective C-H borylation directed by a secondary interaction between ligand and substrate2015

    • Author(s)
      Kuninobu, Y.; Ida, H.; Nishi, M.; Kanai, M
    • Journal Title

      Nat. Chem.

      Volume: 7 Issue: 9 Pages: 712-717

    • DOI

      10.1038/nchem.2322

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C-H Bond Transformations Leading to the Synthesis of Organic Functional Materials2015

    • Author(s)
      Kuninobu, Y.; Sueki, S.
    • Journal Title

      Synthesis

      Volume: 47 Issue: 24 Pages: 3823-3845

    • DOI

      10.1055/s-0035-1560346

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Pyridine N-Oxide-BF2CF3 Complexes and Their Fluorescence Properties2014

    • Author(s)
      Nishida, T.; Fukazawa, A.; Yamaguchi, E.; Oshima, H.; Yamaguchi, S.; Kanai, M.*; Kuninobu, Y.*
    • Journal Title

      Chem. Asian J.

      Volume: 9 Issue: 4 Pages: 1026-1030

    • DOI

      10.1002/asia.201301688

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copper-Catalyzed Benzylic C(sp3)-H Alkoxylation of Heterocyclic Compounds2014

    • Author(s)
      Takemura, N.; Kuninobu, Y.; Kanai, M.
    • Journal Title

      Org. Biomol. Chem.

      Volume: 12 Issue: 16 Pages: 2528-2532

    • DOI

      10.1039/c4ob00215f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Direct C-H Silylation and Germanylation of Benzamides and Carboxamides2014

    • Author(s)
      Kyalo Stephen Kanyiva, Yoichiro Kuninobu, Motomu Kanai
    • Journal Title

      Org. Lett.

      Volume: 16 Issue: 7 Pages: 1968-1971

    • DOI

      10.1021/ol500519y

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molybdenum-Mediated Desurfurization of Thiols and Disulfides2014

    • Author(s)
      Wang, Z.; Kuninobu, Y.*; Kanai, M.*
    • Journal Title

      Synlett

      Volume: 25 Issue: 13 Pages: 1869-1872

    • DOI

      10.1055/s-0034-1378315

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Copper-Mediated Direct C(sp3)-H and C(sp2)-H Acetoxylation2014

    • Author(s)
      Wang, Zhen; Kuninobu, Yoichiro; Kanai, Motomu
    • Journal Title

      Organic Letters

      Volume: 16 Issue: 18 Pages: 4790-4793

    • DOI

      10.1021/ol5022542

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Photo-induced Coloring of ortho-Borylated 2-Phenylpyridines2018

    • Author(s)
      Yusuke Yoshigoe, Yuji Suzaki, Kohtaro Osakada, Yoichiro Kuninobu
    • Organizer
      IRCCS-JST CREST Joint Symposium “Chemical Sciences facing a difficult challenge”
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Regioselective C-H Trifluoromethylation of 6-Membered Heteroaromatic Compounds2018

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      International Congress on Pure & Applied Chemistry (ICPAC 2018), Cambodia
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Control of Solid-state Fluorescent Properties of π-Conjugated Molecules by Non-covalent Bonding2018

    • Author(s)
      Yusuke Yoshigoe, Takeshi Yamakawa, Zijia Wan, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] パラジウム触媒によるC-H結合活性化を伴うアルデ ヒドとハロゲン化物からのケトン合成2017

    • Author(s)
      若木 貴行, 藤後 貴也, 吉留 大輔, 國信 洋一郎, 金井 求
    • Organizer
      日本薬学会第137年会
    • Place of Presentation
      仙台国際会議場
    • Year and Date
      2017-03-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] Aβ凝集阻害剤の創出を支援するC-Hカップリング反応の開発2017

    • Author(s)
      藤後 貴也, 新谷 卓士, 相馬 洋平, 國信 洋一郎, 金井 求
    • Organizer
      日本薬学会第137年会
    • Place of Presentation
      仙台国際会議場
    • Year and Date
      2017-03-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] Iron-Catalyzed Oxyalkylation of Styrenes Using Hypervalent Iodine Reagents2017

    • Author(s)
      Zijia Wang, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Development of Iron-Catalyzed C-H Borylation of 2-Phenylpyridines and Their Analogues and Optical Properties of The Products2017

    • Author(s)
      Yusuke Yoshigoe, Yoichiro Kuninobu
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] マンガン触媒を用いたC-H 結合活性化反応に関するDFT 計算2017

    • Author(s)
      飯島千景・坂田健・末木俊輔・國信洋一郎
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] イリジウム触媒を用いるピリジン類の4位選択的なC-H ホウ素化2017

    • Author(s)
      山川健司、國信洋一郎、金井求
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] ortho-Selective C-H Borylation of Aromatic Compounds Using Distal Functional Group2017

    • Author(s)
      Hong-Liang Li, Yoichiro Kuninobu, Motomu Kanai
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Borylation2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      International Symposium on Pure & Applied Chemistry (ISPAC 2017), Viet Num
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Noncovalent Bond-Controlled Regioselective C-H Borylation2017

    • Author(s)
      Yoichiro Kuninobu, Haruka Ida, Hong-Liang Li, Mitsumi Nishi and Motomu Kanai
    • Organizer
      Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS19), Korea
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2017

    • Author(s)
      國信 洋一郎
    • Organizer
      第29回若手研究者のためのセミナー
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 安価な鉄塩によって触媒される2-フェニルピリジンのオルト位選択的C-Hホウ素化2017

    • Author(s)
      吉越裕介, 國信 洋一郎
    • Organizer
      第29回若手研究者のためのセミナー
    • Related Report
      2017 Annual Research Report
  • [Presentation] ピコリン酸アミド配位子をもつパラジウム触媒によるアルデヒドと有機ハロゲン化物からのヘテロアリールケトン合成2017

    • Author(s)
      若木貴行、藤後貴也、吉留大輔、國信洋一郎、金井求
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      Lecture at Tsinghua University, China
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      Lecture at Peking University, China
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules2017

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      Lecture at Institute of Chemistry, Chinese Academy of Sciences, China
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2017

    • Author(s)
      國信 洋一郎
    • Organizer
      第4回次世代の有機化学・広島シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ホウ素化2‐フェニルピリジン類の固相相転移とその機構解明2017

    • Author(s)
      吉越裕介, 須崎裕司、小坂田耕太郎、國信 洋一郎
    • Organizer
      統合物質創製化学研究推進機構 第3回国内シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機機能性分子合成を志向した新規炭素-水素結合変換反応の開発2017

    • Author(s)
      國信 洋一郎
    • Organizer
      第44回有機典型元素化学討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 鉄触媒によるオルト位選択的なC-Hホウ素化反応の開発2016

    • Author(s)
      吉越 裕介、國信 洋一郎
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      早稲田大学西早稲田キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ピコリン酸アミド配位子をもつパラジウム触媒によるアルデヒドと有機ハロゲン化物からのケトン合成2016

    • Author(s)
      若木 貴行、國信 洋一郎、金井 求
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      早稲田大学西早稲田キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ortho-Selective C-H Borylation of Aromatic Compounds Controlled by Lewis Acid-Base Interaction2016

    • Author(s)
      Hong-Liang Li, Yoichiro Kuninobu, Motomu Kanai
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      早稲田大学西早稲田キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ortho-Selective C-H Borylation of Aromatic Compounds Controlled by Lewis Acid-Base Interaction2016

    • Author(s)
      Hong Liang Li, Yoichiro Kuninobu, Motomu Kanai
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] パラジウム触媒によるアルデヒドとハロゲン化アリールからのケトン合成2016

    • Author(s)
      若木 貴行、國信 洋一郎、金井 求
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] マンガン-ボラン触媒を用いるC-H結合活性化を鍵反応とするイソベンゾフラノン合成法の開発2016

    • Author(s)
      末木 俊輔、王 子嘉、國信 洋一郎
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] A meta-Selective C-H Borylation Directed by Hydrogen Bonds between Ligand and Substrate2016

    • Author(s)
      Mitsumi Nishi, Haruka Ida, Yoichiro Kuninobu, and Motomu Kanai
    • Organizer
      Symposium on Frontiers of Molecular Science and Technology
    • Place of Presentation
      The University of Tokyo, Japan
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Lewis Acid-Base Interaction-Controlled ortho-Selective C-H Borylation of Aryl Sulfides2016

    • Author(s)
      Hong-Liang Li, Yoichiro Kuninobu, Motomu Kanai
    • Organizer
      第60回日本薬学会関東支部大会
    • Place of Presentation
      東京大学本郷キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] Regioselective Trifluoromethylation of 6-Membered Heteroaromatic Compounds2015

    • Author(s)
      Yoichiro Kuninobu, Tomoaki Nishida, Masahiro Magase, Haruka Ida, Motomu Kanai
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen Bond-Controlled meta-Selective C-H Borylation of Aromatic Compounds2015

    • Author(s)
      Yoichiro Kuninobu, Haruka Ida, Mitsumi Nishi, Motomu Kanai
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen Bond-Controlled meta-Selective C-H Borylation of Aromatic Compounds2015

    • Author(s)
      Yoichiro Kuninobu, Haruka Ida, Mitsumi Nishi, Motomu Kanai
    • Organizer
      IKCOK-13
    • Place of Presentation
      京都、リーガロイヤルホテル京都
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水素結合による基質認識を利用した芳香族化合物のメタ位選択的C-Hボリル化反応2015

    • Author(s)
      井田 悠、西 光海、國信 洋一郎、金井 求
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] イリジウム触媒によるLewis酸-塩基相互作用を利用したオルト位選択的なC-Hシリル化反応2015

    • Author(s)
      若木 貴行、金井 求、國信 洋一郎
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] ロジウム触媒を用いたC-H結合活性化を伴う多置換シリルインデン類の合成2015

    • Author(s)
      末木 俊輔、國信 洋一郎
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hydrogen Bond-Controlled meta-Selective C-H Borylation of Aromatic Compounds2015

    • Author(s)
      Yoichiro Kuninobu, Haruka Ida, Mitsumi Nishi, Motomu Kanai
    • Organizer
      OMCOS18
    • Place of Presentation
      Sitges, Barcelona, Spain
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolines via Insertion of Carbodiimides into a C-H Bond2015

    • Author(s)
      Shunsuke Sueki, Zijia Wang, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      OMCOS18
    • Place of Presentation
      Sitges, Barcelona, Spain
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Copper-Catalyzed Intermolecular C(sp3)-H Bond Functionalization Towards the Synthesis of Tertiary Carbamates2015

    • Author(s)
      Prasanna Kumara Chikkade, Yoichiro Kuninobu, Motomu Kanai
    • Organizer
      OMCOS18
    • Place of Presentation
      Sitges, Barcelona, Spain
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Palladium-Catalyzed C(sp2)-C(sp3) Coupling Reaction between Arenes and Oxiranes via C-H Bond Activation2015

    • Author(s)
      Zhen Wang, Yoichiro Kuninobu, Motomu Kanai
    • Organizer
      OMCOS18
    • Place of Presentation
      Sitges, Barcelona, Spain
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Iridium-Catalyzed Regioselective C-H Silylation Controlled by Lewis Acid-Base Interaction2015

    • Author(s)
      Takayuki Wakaki, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      OMCOS18
    • Place of Presentation
      Sitges, Barcelona, Spain
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イリジウム触媒によるLewis酸-塩基相互作用を利用した位置選択的なC-Hシリル化反応2015

    • Author(s)
      若木 貴行、金井 求、國信 洋一郎
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水素結合を利用した芳香族化合物のメタ位選択的なC-Hボリル化反応2015

    • Author(s)
      西 光海、井田 悠、國信 洋一郎、金井 求
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Palladium-Catalyzed C(sp2)-C(sp3) Coupling Reaction between Arenes and Oxiranes via C-H Bond Activation2015

    • Author(s)
      Zhen Wang, Yoichiro Kuninobu, Motomu Kanai
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] C-H結合活性化を鍵反応とするロジウム触媒を用いた多置換シリルインデンの合成とその蛍光特性2015

    • Author(s)
      末木 俊輔、國信 洋一郎
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolinones via C-H Bond Activation2015

    • Author(s)
      Jijia Wang, Shunsuke Sueki, Motomu Kanai, Yoichiro Kuninobu
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] BF2CF3をLewis酸およびトリフルオロメチル化剤として用いた6員環ヘテロ芳香族化合物のベンジル位C(sp3)-Hトリフルオロメチル化反応2015

    • Author(s)
      永瀬 政弘、國信 洋一郎、金井 求
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水素結合を利用した芳香族化合物のメタ位選択的なC-Hホウ素化反応2015

    • Author(s)
      井田 悠、西 光海、國信 洋一郎、金井 求
    • Organizer
      日本薬学会第135年会
    • Place of Presentation
      兵庫医療大学(兵庫県神戸市)
    • Year and Date
      2015-03-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of Novel C-H Bond Transformations Directed Towards Organic Functional Materials2014

    • Author(s)
      Yoichiro Kuninobu
    • Organizer
      8th Singapore International Chemical Conference (SICC-8)
    • Place of Presentation
      National University of Singapore (Singapore)
    • Year and Date
      2014-12-14
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] パラジウム触媒を用いた分子内酸化的C-H/C-Hカップリング反応による含ヘテロ原子π共役系化合物の合成2014

    • Author(s)
      斉藤 健太、金井 求、國信 洋一郎
    • Organizer
      第58回日本薬学会関東支部大会
    • Place of Presentation
      昭和薬科大学(東京都町田市)
    • Year and Date
      2014-10-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] レニウム触媒を用いた3-イミノ-および1,3-ジイミノイソインドリノンの合成法の開発およびその応用2014

    • Author(s)
      末木 俊輔、王 子嘉、郭 遠芳、金井 求、國信 洋一郎
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学病院キャンパス(福岡県福岡市東区)
    • Year and Date
      2014-09-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] OBF2CF3基による活性化を用いる含窒素ヘテロ芳香族化合物の位置選択的トリフルオロメチル化反応2014

    • Author(s)
      井田 悠、西田 友明、國信 洋一郎、金井 求
    • Organizer
      第61回有機金属化学討論会
    • Place of Presentation
      九州大学病院キャンパス(福岡県福岡市東区)
    • Year and Date
      2014-09-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] ボランによる求電子的な活性化を利用した含窒素ヘテロ芳香族化合物の位置選択的なトリフルオロメチル化反応2014

    • Author(s)
      井田 悠、西田 友明、國信 洋一郎、金井 求
    • Organizer
      日本プロセス化学会2014サマーシンポジウム
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2014-07-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Rhenium-Catalyzed Synthesis of 3-Imino-1-isoindolinones via C-H Functionalization and Application to Synthesis of Polyimide Derivatives2014

    • Author(s)
      Shunsuke Sueki, Yuanfang Guo, Motomu Kanai and Yoichiro Kuninobu
    • Organizer
      XXVI International Conference on Organometallic Chemistry (ICOMC2014)
    • Place of Presentation
      Royton Sapporo (Sapporo, Japan)
    • Year and Date
      2014-07-13
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Regioselective Trifluoromethylation of N-Heteroaromatic Compounds using BF2CF3 Activator2014

    • Author(s)
      Yoichiro Kuninobu, Tomoaki Nishida, Haruka Ida, Motomu Kanai
    • Organizer
      20th International Conference on Organic Synthesis (ICOS-20)
    • Place of Presentation
      Budapest, Hungary
    • Year and Date
      2014-06-29
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Book] ChemGrowing2017

    • Author(s)
      國信洋一郎
    • Total Pages
      4
    • Publisher
      和光純薬
    • Related Report
      2017 Annual Research Report
  • [Book] 有機合成実験法ハンドブック 第2版2015

    • Author(s)
      國信洋一郎
    • Total Pages
      1194
    • Publisher
      丸善出版
    • Related Report
      2015 Annual Research Report
  • [Remarks] 國信研究室HP(日本語)

    • URL

      http://kuninobu-lab.cm.kyushu-u.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 國信研究室HP(英語)

    • URL

      http://kuninobu-lab-english.cm.kyushu-u.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 國信研究室HP

    • URL

      http://kuninobu-lab.cm.kyushu-u.ac.jp/

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
  • [Remarks]

    • URL

      http://www.jst.go.jp/erato/kanai/images/members/PubList_Yoichiro_Kuninobu.pdf

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 蛍光を有する複合体2017

    • Inventor(s)
      國信 洋一郎、金井 求、山川 健司、王 子嘉、吉越 裕介
    • Industrial Property Rights Holder
      國信 洋一郎、金井 求、山川 健司、王 子嘉、吉越 裕介
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-161912
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] ビピリジル化合物2015

    • Inventor(s)
      國信 洋一郎、金井 求、井田 悠、西 光海
    • Industrial Property Rights Holder
      國信 洋一郎、金井 求、井田 悠、西 光海
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-01-29
    • Related Report
      2014 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] イミノ基を有する可溶性ポリイミド系重合体、及びその製造方法2014

    • Inventor(s)
      國信 洋一郎、末木 俊輔
    • Industrial Property Rights Holder
      國信 洋一郎、末木 俊輔
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-07-03
    • Related Report
      2014 Annual Research Report
    • Overseas

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Published: 2014-04-04   Modified: 2019-03-29  

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