Design and synthesis of buckybowls having unique solid-state properties
| Project/Area Number |
26288020
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
SAKURAI HIDEHIRO 大阪大学, 工学(系)研究科(研究院), 教授 (00262147)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2014: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
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| Keywords | バッキーボウル / スマネン / 固体物性 / 内部炭素 / フィリーデルクラフツ反応 / カルベン / 合成化学 / ナノ材料 / 有機工業化学 / 可溶媒分解 / フリーデルクラフツ反応 / カラム状積層構造 / 還元反応 / ヘリングボーン構造 |
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| Outline of Final Research Achievements |
Our aim of this research is to establish a method to precisely control the unique morphology in the solid state of the bowl-shaped conjugate compound "Buckybowl" corresponding to the partial skeleton of fullerenes or the cap structure of carbon nanotubes, and to establish a rational molecular design for expressing various physical properties such as light emitting property and ferroelectric property, and development of a synthesis method thereof.
The most important result of this research is that it succeeded in developing a method for introducing a substituent to Sumanene internal carbon. As a result, we also succeeded in developing a method of aligning curved surfaces of Sumanene skeleton to metal surfaces. Development of chemical sensors utilizing curved / curved surface interaction of curved π plane is expected.
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Report
(4 results)
Research Products
(35 results)
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[Journal Article] Synthesis of Triaryltriazasumanenes2017
Author(s)
P. Kaewmati, Q. Tan, S. Higashibayashi, Y. Yakiyama, H. Sakurai,
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Journal Title
Chem. Lett.
Volume: 46
Issue: 1
Pages: 146-148
DOI
NAID
ISSN
0366-7022, 1348-0715
Related Report
Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
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