Creation of Multifunctional Molecular Assembly from Macrocyclic Conjugated Systems
Project/Area Number |
26288040
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Functional solid state chemistry
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Research Institution | Tokyo Metropolitan University |
Principal Investigator |
Iyoda Masahiko 首都大学東京, 理工学研究科, 客員教授 (50115995)
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Co-Investigator(Kenkyū-buntansha) |
大谷 裕之 横浜国立大学, 大学院環境情報研究院, 教授 (30213763)
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Project Period (FY) |
2014-04-01 – 2017-03-31
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Project Status |
Completed (Fiscal Year 2017)
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Budget Amount *help |
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2015: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
|
Keywords | 超分子機能材料 / ナノ集積体 / 土星型C60錯体 / 有機超分子集積体 / 環状オリゴチオフェン / 超分子 |
Outline of Final Research Achievements |
In this research works, we have constructed novel self-assembled nanostructures of organic pi-electron systems and investigated their functional properties and nanosized effects. Thus, soft structures of Saturn-like complexes were employed as self-assembled mono- and bilayers between an organic solution and graphite to investigate rectification characteristics. Furthermore, we explored novel vapochromic behavior with vapor-induced quasi-reversible shape change of nanofibers of macrocyclic oligothiophenes.
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Report
(4 results)
Research Products
(27 results)
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[Journal Article] 10-Mesityl-1,8-diphenylanthracene Dimer. Synthesis, Structure, and Properties2018
Author(s)
A. Shirai, H. Sano, Y. Nakamura, M. Takashika, H. Otani, M. Hasegawa, S. Kato, M. Iyoda
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Journal Title
J. Org. Chem.
Volume: 83
Issue: 7
Pages: 3857-3863
DOI
Related Report
Peer Reviewed
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[Journal Article] Synthesis, Structures, and Photophysical Properties of pi-Expanded Oligothiophene 8-Mers and Their Saturn-like C60 Complexes2015
Author(s)
H. Shimizu, J. D. Cojal González, M. Hasegawa, T. Nishinaga, T. Haque, M. Takase, H. Otani, J. P. Rabe, M. Iyoda
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Journal Title
J. Am. Chem. Soc.
Volume: 137
Pages: 3877-3885
Related Report
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Synthesis, Structures, and Photophysical Properties of pi-Expanded Oligothiophene 8-Mers and Their Saturn-like C60 Complexes2015
Author(s)
Hideyuki Shimizu, Jose D. Cojal Gonzalez, Masashi Hasegawa, Tohru Nishinaga, Tahmina Haque, Masayoshi Takase, Hiroyuki Otani, Jurgen P. Rabe, Masahiko Iyoda
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Journal Title
J. Am. Chem. Soc.
Volume: 137
Issue: 11
Pages: 3877-3885
DOI
Related Report
Peer Reviewed
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[Journal Article] Multifunctional π-Expanded Macrocyclic Oligothiophene 6-Mers and Related Macrocyclic Oligomers2014
Author(s)
Iyoda, M.; Tanaka, K.; Shimizu, H.; Hasegawa, M.; Nishinaga, T.; Nishiuchi, T.; Kunugi, Y.; Ishida, T.; Otani, H.; Sato, H.; Inukai, K.; Tahara, K.; Tobe, Y.
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Journal Title
J. Am. Chem. Soc.
Volume: 136
Issue: 6
Pages: 2389-2396
DOI
Related Report
Peer Reviewed
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