Development of metal nano particle catalysis toward functional molecular synthesis

• Project/Area Number: 26288051
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Osaka University
• Principal Investigator: ARISAWA Mitsuhiro 大阪大学, 薬学研究科, 准教授 (40312962)
• Project Period (FY): 2014-04-01 – 2019-03-31
• Project Status: Completed (Fiscal Year 2018)
• Budget Amount: ¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000); Fiscal Year 2017: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000); Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000); Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000); Fiscal Year 2014: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
• Keywords: 有機化学 / 薬学 / ナノ材料 / 環境技術 / 合成化学

Outline of Final Research Achievements

The structural analysis of the palladium nanoparticle catalyst SAPdNp developed by the research representatives succeeded, and it turned out that the excellent function of SAPdNp is structurally rational. We also succeeded in developing novel nickel nanoparticle catalysts such as SANiNp as rare element reduction type and alternative type organometallic catalysts. Furthermore, we succeeded in developing a microwave device suitable for metal nanoparticle catalyst. As a result of these research results, we succeeded in finding ligand-free Suzuki-Miyaura coupling of aryl chloride using metal nanoparticle catalyst and continuous irradiation microwave device.

Academic Significance and Societal Importance of the Research Achievements

従来の触媒に比べ、金属ナノパーティクル（Np）は表面積が広く、より高活性であることから、より温和な環境調和的条件で反応が進行する特徴を有している。一方、研究代表者らが開発した硫黄修飾金担持型パラジウムナノ粒子触媒SAPdNpは各種カップリング反応などにリガンドフリーで機能する新触媒であり、産業界でも使用されているが、SAPdNpの構造が不明であることから、より活性の高い触媒や、別の金属ナノ粒子触媒の開発が困難な状況であった。今回、本触媒の構造解析に成功し、新規ニッケルNp触媒SANiNpなどの開発に成功した点で学術的意義がある。また、マイクロウエーブ装置の開発にも成功した点で社会的意義がある。

Research Products

• [Int'l Joint Research] ケンブリッジ大学(英国)
• [Int'l Joint Research] ケンブリッジ大学(英国)
• [Int'l Joint Research] ブリュッセル自由大学(ベルギー)
• [Journal Article] Design and Synthesis of N1,N8-Diacetylspermidine Analogues having a Linker with Desired Functional Groups (2019)
  • Author(s): Reiya Ohta, Akihiro Oguro, Kazuhiro Nishimura, Kenichi Murai, Hiromichi Fujioka, Mitsuhiro Arisawa.
  • Journal Title: Organic & Biomolecular Chemistry Volume: 17 Pages: 867-875
  • DOI: 10.1039/c8ob02900h
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Tricarboxylic acid cycle activity suppresses acetylation of mitochondrial proteins during early embryonic development in Caenorhabditis elegans. (2019)
  • Author(s): Hada Kazumasa、Hirota Keiko、Inanobe Ai、Kako Koichiro、Miyata Mai、Araoi Sho、Matsumoto Masaki、Ohta Reiya、Arisawa Mitsuhiro、Daitoku Hiroaki、Hanada Toshikatsu、Fukamizu Akiyoshi
  • Journal Title: Journal of Biological Chemistry Volume: 294 Pages: 3091-3099
  • DOI: 10.1074/jbc.ra118.004726
  • NAID: 120007133475
  • Peer Reviewed
• [Journal Article] Metal-Free Nitrogen-Containing Polyheterocyclic Near-Infrared (NIR) Absorption Dyes: Synthesis, Absorption Properties, and Theoretical Calculation of Substituted 5-Methylisoindolo[2,1-a]quinolines (2019)
  • Author(s): Fujii Yuki、Suwa Yukinori、Wada Yuki、Takehara Tsunayoshi、Suzuki Takeyuki、Kawashima Yusuke、Kawashita Norihito、Takagi Tatsuya、Fujioka Hiromichi、Arisawa Mitsuhiro
  • Journal Title: ACS Omega Volume: 4 Pages: 5064-5075
  • DOI: 10.1021/acsomega.9b00315
  • Peer Reviewed / Open Access
• [Journal Article] Highly Discriminative and Chemoselective Deprotection/Transformations of Acetals with the Combination of Trialkylsilyl Triflate/2,4,6-Collidine (2018)
  • Author(s): Reiya Ohta, Nao Matsumoto, Yoshifumi Ueyama, Yuichi Kuboki, Hiroshi Aoyama, Kenichi Murai, Mitsuhiro Arisawa, Tomohiro Maegawa, Hiromichi Fujioka
  • Journal Title: The Journal of Organic Chemistry Volume: 83 Pages: 6432-6443
  • DOI: 10.1021/acs.joc.8b00675
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Cascade Multiple Diels?Alder Reactions of Styrene Derivatives with Maleimide or Maleic Anhydride (2018)
  • Author(s): Yoshioka Shohei、Aoyama Hiroshi、Fujioka Hiromichi、Arisawa Mitsuhiro
  • Journal Title: The Journal of Organic Chemistry Volume: 83 Pages: 6599-6606
  • DOI: 10.1021/acs.joc.8b00890
  • Peer Reviewed
• [Journal Article] Synthesis of Chiral cis-Cyclopropane Bearing Indole and Chromone as Potential TNFα Inhibitors (2018)
  • Author(s): Kanada Ryutaro、Tanabe Makoto、Muromoto Ryuta、Sato Yukina、Kuwahara Tomoki、Fukuda Hayato、Arisawa Mitsuhiro、Matsuda Tadashi、Watanabe Mizuki、Shuto Satoshi
  • Journal Title: J. Org. Chem. Volume: 83 Pages: 7672-7682
  • DOI: 10.1021/acs.joc.8b00466
  • Peer Reviewed
• [Journal Article] Design and synthesis of histamine H3/H4 receptor ligands with a cyclopropane scaffold (2018)
  • Author(s): Watanabe Mizuki、Kobayashi Takaaki、Ito Yoshihiko、Fukuda Hayato、Yamada Shizuo、Arisawa Mitsuhiro、Shuto Satoshi
  • Journal Title: Bioorganic & Medicinal Chemistry Letters Volume: 28 Pages: 3630-3633
  • DOI: 10.1016/j.bmcl.2018.10.041
  • Peer Reviewed
• [Journal Article] Reusable Immobilized Iron(II) Nanoparticle Pre-Catalysts for Ligand-Free Kumada Coupling (2018)
  • Author(s): Toshiki Akiyama, Yuki Wada, Kellie Jenkinson, Tetsuo Honma, Kazuki Tsuruta, Yusuke Tamenori, Hitoshi Haneoka, Tsunayoshi Takehara, Takeyuki Suzuki, Kenichi Murai, Hiromichi Fujioka, Yoshihiro Sato, Andrew E. H. Wheatley, Mitsuhiro Arisawa
  • Journal Title: ACS Applied Nano Materials Volume: 1 Pages: 6950-6958
  • DOI: 10.1021/acsanm.8b01742
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Palladium-Catalyzed Seven-Membered Silacycle Construction: 1,7-Enyne Hydroxycyclization To Give a Benzosilepine Skeleton (2018)
  • Author(s): Takamoto Kohei、Yoshioka Shohei、Fujioka Hiromichi、Arisawa Mitsuhiro
  • Journal Title: Organic Letters Volume: 20 Pages: 1773-1776
  • DOI: 10.1021/acs.orglett.8b00271
  • Peer Reviewed
• [Journal Article] Design and Synthesis of Cyclopropane Congeners of Resolvin E2, an Endogenous Proresolving Lipid Mediator, as Its Stable Equivalents (2016)
  • Author(s): Fukuda, H; Muromoto, R.; Takakura, Y.; Ishimura, K.; Kanada, R.; Fushihara, D.; Tanabe, M.; Matsubara, K.; Hirao, T.; Hirashima, K.; Abe, Arisawa, M.; Matsuda, T.; Shuto, S.
  • Journal Title: Organic Letters Volume: 18 Pages: 6224-6227
  • DOI: 10.1021/acs.orglett.6b02612
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Design, Synthesis, and Identification of 4α-azidoethyl-Cyclic ADP-Carbocyclic-Ribose as a Highly Potent Analogue of Cyclic ADP-Ribose a Ca2+-mobilizing Second Messenger (2016)
  • Author(s): Sato, T.; Watanabe, M.; Tsuzuki, T.; Takano, S.; Murayama, T.; Sakurai, T.; Kameda, T.; Arisawa, M.; Fukuda, H.; Shuto, S.
  • Journal Title: J. Med. Chem. Volume: 59 Pages: 7282-7286
  • DOI: 10.1021/acs.jmedchem.6b00437
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Highly Sensitive Measurement of Inositol 1,4,5-Trisphosphate by Using a New Fluorescent Ligand and Ligand Binding Domain Combination (2016)
  • Author(s): Oura, T.; Murata, K.; Morita, T.; Nezu, A.; Arisawa, M.; Shuto, S.; Tanimura, A.
  • Journal Title: Chembiochem, Volume: 17 Pages: 1509-1512
  • DOI: 10.1002/cbic.201600096
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Self-assembled Multi-layer Stabilized Nickel Nanoparticle Catalyst for Ligand-free Cross-coupling Reactions: in situ Metal Nanoparticle and Nanospace Simultaneous Organization (2016)
  • Author(s): Naoyuki Hoshiya, Katsumasa Fujiki, Takahisa Taniguchi, Tetsuo Honma, Yusuke Tamenori, Mincen Xiao, Nozomi Saito, Mami Yokoyama, Akira Ishii, Hiromichi Fujioka, Satoshi Shuto, Yoshihiro Sato, Mitsuhiro Arisawa
  • Journal Title: Adv. Synth. Catal Volume: 358 Pages: 2449-2459
  • DOI: 10.1002/adsc.201600024
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Non-metathesis Heterocycle Formation by Ruthenium-Catalyzed Intramolecular [2+2] Cycloaddition of Allenamide-enes to Azabicyclo[3.1.1]heptanes (2016)
  • Author(s): Tomomi Nada, Yusuke Yoneshige, Yasuhiro Ii, Takashi Matsumoto, Hiromichi Fujioka, Satoshi Shuto, Mitsuhiro Arisawa
  • Journal Title: ACS Catl. Volume: 6 Pages: 3168-3171
  • DOI: 10.1021/acscatal.6b00628
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Identification of a Potent and Selective GPR4 Antagonist as a Drug Lead for the Treatment of Myocardial Infarction (2016)
  • Author(s): Hayato Fukuda, Saki Ito, Kenji Watari, Chihiro Mogi, Mitsuhiro Arisawa, Fumikazu Okajima, Hitoshi Kurose, Satoshi Shuto
  • Journal Title: ACS Medicinal Chemistry Letters Volume: 7 Pages: 493-497
  • DOI: 10.1021/acsmedchemlett.6b00014
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Development of a Sulfur-modified Glass-supported Pd Nanoparticle Catalyst for the Suzuki-Miyaura Coupling (2016)
  • Author(s): Mincen Xiao, Naoyuki Hoshiya, Katsumasa Fujiki, Tetsuo Honma, Yusuke Tamenori, Satoshi Shuto, Hiromichi Fujioka, Mitsuhiro Arisawa
  • Journal Title: Chem. Pharm. Bull.
  • NAID: 130005253911
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Kazuki Urakawa, Michinori Sumimoto, Mitsuhiro Arisawa, Masaki Matsuda, Hayato Ishikawa (2016)
  • Author(s): Redox Switching of Orthoquinone-Containing Aromatic Compounds using Gas Energy
  • Journal Title: Angew. Chem. Int. Ed
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Double Carbonylation of Aryl Iodides with Amines under an Atmospheric Pressure of Carbon Monoxide Using Sulfur- Modified Au-Supported Palladium (2015)
  • Author(s): Nozomi Saito Takahisa Taniguchi, Naoyuki Hoshiya, Satoshi Shuto, Mitsuhiro Arisawa, Yoshihiro Sato
  • Journal Title: Green Chem Volume: 17 Pages: 2358-2361
  • DOI: 10.1039/c4gc02469a
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Safe Removal of the Allyl Protecting Groups of Allyl Esters using a Recyclable, Low-leaching and Ligand-free Palladium Nanoparticle Catalyst (2015)
  • Author(s): Koji Takagi, Hayato Fukuda, Satoshi Shuto, Akira Otaka, Mitsuhiro Arisawa
  • Journal Title: Adv. Synth. Catal Volume: 357 Pages: 2119-2124
  • DOI: 10.1002/adsc.201500055
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Construction of a chiral quaternary carbon center by a radical cyclization/ring-enlargement reaction: synthesis of 4α-azidoethyl carbocyclic ribose, a key unit for the synthesis of cyclic ADP- ribose derivatives of biological importance (2015)
  • Author(s): Takatoshi Sato, Takayoshi Tsuzuki, Satoshi Takano, Kohtaro Kato, Hayato Fukuda, Mitsuhiro Arisawa, Satoshi Shuto
  • Journal Title: Tetrahedron Volume: 71 Pages: 5403-5413
  • DOI: 10.1016/j.tet.2015.05.084
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis of 7-Deaza-cyclic Adenosine-5′-diphosphate-carbocyclic-ribose and Its 7-Bromo Derivative as Intracellular Ca2+-Mobilizing Agents (2015)
  • Author(s): Satoshi Takano, Takayoshi Tsuzuki, Takashi Murayama, Takashi Sakurai, Hayato Fukuda, Mitsuhiro Arisawa, Satoshi Shuto
  • Journal Title: J. Org. Chem Volume: 80 Pages: 6619-6627
  • DOI: 10.1021/acs.joc.5b00723
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Development of Enyne Metathesis/Isomerization/Diels-Alder One-pot Reaction for Novel Near- Infrared (NIR) Dye Core (2015)
  • Author(s): Kohei Yamashita, Yuki Fujii, Shohei Yoshioka, Hiroshi Aoyama, Hirofumi Tsujino, Tadayuki Uno, Hiromichi Fujioka, Mitsuhiro Arisawa
  • Journal Title: Chemistry A European Journal Volume: 23 Pages: 17491-17494
  • DOI: 10.1002/chem.201502313
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] One-pot Olefin Isomerization/ Aliphatic Enamine Ring-closing Metathesis/ Oxidation/ 1,3-Dipolar Cycloaddition for the Synthesis of Isoindolo[1,2-a]isoquinolines (2015)
  • Author(s): Yuki Fujii, Tsunayoshi Takehara, Takeyuki Suzuki, Hiromichi Fujioka, Satoshi Shuto, Mitsuhiro Arisawa
  • Journal Title: Advanced Synthesis & Catalysis Volume: 357 Pages: 4055-4062
  • DOI: 10.1002/adsc.201500680
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Stereoselective Construction of 2,7-Disubstituted fused-Bis Tetrahydrofuran Skeletons: Biomimetic-Type Synthesis and Biological Evaluation of (±)-and (.)-Aplysiallene and Their Derivatives (2015)
  • Author(s): Maki Yamakawa, Takeshi Kurachi, Yusuke Yoshikawa, Mitsuhiro Arisawa, Yuichiro Okino, Kuniaki Suzuki, and Hiromichi Fujioka
  • Journal Title: Jounal of Organic Chemistry Volume: 80 Pages: 10261-10277
  • DOI: 10.1021/acs.joc.5b01882
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Characterization of Imidazopyridine Compounds as Negative Allosteric Modulators of Proton- Sensing GPR4 in Extracellular Acidification-Induced Responses (2015)
  • Author(s): Ayaka Tobo, Masayuki Tobo, Takashi Nakakura, Masashi Ebara, Hideaki Tomura, Chihiro Mogi, Dong-Soon Im, Naoya Murata, Atsushi Kuwabara, Saki Ito, Hayato Fukuda, Mitsuhiro Arisawa, Satoshi Shuto, Michio Nakaya, Hitoshi Kurose, Koichi Sato, Fumikazu Okajima
  • Journal Title: PLoS ONE Volume: 10
  • DOI: 10.1371/journal.pone.0129334
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Formation of self-assembled multi-layer stable palladium nanoparticles for ligand-free coupling reactions (2015)
  • Author(s): Mitsuhiro Arisawa, Mohammad Al-Amin, Tetsuo Honma, Yusuke Tamenori, Satoshi Arai, Naoyuki Hoshiya, Takatoshi Sato, Mami Yokoyama, Akira Ishii, Masaki Takeguchi, Tsuyoshi Miyazaki, Masashi Takeuchi, Tomohiro Maruko, Satoshi Shuto
  • Journal Title: RSC Advances Volume: 5 Pages: 19-27
  • DOI: 10.1039/c4ra11215f
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Nickel-Catalyzed Suzuki-Miyaura Coupling of a Tertiary Iodocyclopropane with Wide Boronic Acid Substrate Scope: Coupling Reaction Outcome Depends on Radical Species Stability (2015)
  • Author(s): Keisuke Yotsuji, Naoyuki Hoshiya, Takaaki Kobayashi, Hayato Fukuda, Hiroshi Abe, Mitsuhiro Arisawa and Satoshi Shuto
  • Journal Title: Advanced Synthesis & Catalysis Volume: 357 Pages: 1022-1028
  • DOI: 10.1002/adsc.201401000
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] 芳香族エナミドメタセシス反応の開発：生物活性多置換インドール化合物の設計・合成・機能評価 (2015)
  • Author(s): 有澤光弘、西田篤司、周東智
  • Journal Title: 有機合成化学協会誌 Volume: 73 Pages: 254-265
  • NAID: 130005065812
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Safe Removal of the Allyl Protecting Groups of Allyl Esters using a Recyclable, Low-leaching and Ligand-free Palladium Nanoparticle Catalyst (2015)
  • Author(s): Koji Takagi, Hayato Fukuda, Satoshi Shuto, Akira Otaka, Mitsuhiro Arisawa
  • Journal Title: Adv. Synth. Catal. Volume: 357
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Rational hopping of a peptidic scaffold into non-peptidic scaffolds: structurally novel potent proteasome inhibitors derived from a natural product, belactosin A (2014)
  • Author(s): Shuhei Kawamura, Yuka Unno, Takatsugu Hirokawa, Akira Asai, Mitsuhiro Arisawa and Satoshi Shuto
  • Journal Title: Chem. Commun. Volume: 50 Pages: 2445-2447
  • NAID: 120005525210
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Investigation of the Non-Covalent Binding Mode of Covalent Proteasome Inhibitors around the Transition State by Combined Use of Cyclopropylic Strain-Based Conformational Restriction and Computational Modeling (2014)
  • Author(s): Shuhei KAWAMURA
  • Journal Title: Journal of Medicinal Chemistry Volume: 56 Pages: 2726-2735
  • DOI: 10.1021/jm400542h
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Palladium-Nanoparticle-Catalyzed Direct Ethynylation of Aliphatic Carboxylic Acid Derivatives via C(sp3)-H Bond Functionalization (2014)
  • Author(s): Mohammad Al-Amin, Mitsuhiro Arisawa, Satoshi Shuto, Yusuke Ano, Mamoru Tobisu, Naoto Chatani
  • Journal Title: Adv. Synth. Catal. Volume: 356 Pages: 1631-1637
  • DOI: 10.1002/adsc.201301180
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Ligandーfree Suzuki-Miyaura Coupling with Sulfur-modified Gold-supported Palladium in the Synthesis of a Conformationally-Restricted Cyclopropane Compound Library with Three-Dimensional Diversity (2014)
  • Author(s): Mitsuhiro ARISAWA
  • Journal Title: ACS Comb. Sci Volume: 16 Pages: 215-220
  • DOI: 10.1021/co4001138
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Palladium-Nanoparticle-Catalyzed 1,7-Palladium Migration Involving C-H Activation, Followed by Intramolecular Amination: Regioselective Synthesis of N1-Arylbenzotriazoles and an Evaluation of Their Inhibitory Activity Towards Indoleamine 2,3-Dioxygenase (2014)
  • Author(s): Koji Takagi, Mohammad Al-Amin, Naoyuki Hoshiya, Johan Wouters, Hiroshi Sugimoto, Yoshitsugu Shiro, Hayato Fukuda, Satoshi Shuto, Mitsuhiro Arisawa
  • Journal Title: J. Org. Chem. Volume: 79 Pages: 6366-6371
  • DOI: 10.1021/jo5009838
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Development of a New Class of Proteasome Inhibitors with an Epoxyketone Warhead: Rational Hybridization of Non-peptidic Belactosin Derivatives and Peptide Epoxyketones (2014)
  • Author(s): Shuhei Kawamura, Yuka Unno, Akira Asai, Mitsuhiro Arisawa, Satoshi Shuto
  • Journal Title: Bioorg. Med. Chem Volume: 22 Pages: 3091-3095
  • DOI: 10.1016/j.bmc.2014.04.032
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Conformationally Restricted GABA with Bicyclo[3.1.0]hexane Backbone as the First Highly Selective BGT-1 Inhibitor (2014)
  • Author(s): Takaaki Kobayashi, Akihiro Suemasa, Arisa Igawa, Soichiro Ide, Hayato Fukuda, Hiroshi Abe, Mitsuhiro Arisawa, Masabumi Minami, Satoshi Shuto
  • Journal Title: ACS Med. Chem. Lett Volume: 5 Pages: 889-893
  • DOI: 10.1021/ml500134k
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Presentation] Ru-Catalyzed 1,6-Enyne Cycloisomerization of Functionalized Olefin for 2,3-Disubstituted Indole and Benzo[b]furan Synthesis (2018)
  • Author(s): Ohno, S; Takamoto, K.; Fujioka, H.; Arisawa, M.
  • Organizer: XXVIII International Conference on Organometallic Chemistry
  • Int'l Joint Research / Invited
• [Presentation] Iron Nanoparticles-catalyzed Ligand-free Kumada Coupling (2018)
  • Author(s): Akiyama, T.; Honma, T.; Tamenori, Y.; Fujioka, H.; Sato, Y.; Arisawa, M.
  • Organizer: XXVIII International Conference on Organometallic Chemistry
  • Int'l Joint Research
• [Presentation] Development of Transition Metal Catalyzed 7-Membered and 6-Membered Silacyclic Compounds Synthesis (2018)
  • Author(s): Yoshioka, S.; Takamoto, K.; Fujioka, H.; Arisawa, M.
  • Organizer: XXVIII International Conference on Organometallic Chemistry
  • Int'l Joint Research
• [Presentation] Design and Synthesis of Polyamine Analogues to Obtain Their Aptamers (2018)
  • Author(s): Ohta, R.; Oguro, A.; Nishimura, K.; Fujioka, H.; Arisawa, M.
  • Organizer: XXII International Conference on Organic Synthesis
  • Int'l Joint Research
• [Presentation] Selective Transformation of β‐Disubstituted Enones and Ynones in the Presence of β‐Monosubstituted Enones (2018)
  • Author(s): Morita, K.; Ohta, R.; Murai,K.; Arisawa, M.; Fujioka, H.
  • Organizer: XXII International Conference on Organic Synthesis
  • Int'l Joint Research
• [Presentation] Iron(II) Nanoparticle-Catalyzed Ligand-Free Kumada Coupling (2018)
  • Author(s): Akiyama, T.; Honma, T.; Tamenori, Y.; Fujioka, H.; Sato, Y.; Arisawa, M.
  • Organizer: 8th Spanish-Portuguese-Japanese Organic Chemistry Symposium (8th SPJ-OCS)
  • Int'l Joint Research
• [Presentation] Development of Transition Metal Catalyzed 7-Membered and 6-Membered Silacyclic Compounds Synthesis (2018)
  • Author(s): Ohno, S.; Murai, K.; Fujioka, H.; Arisawa, M.
  • Organizer: 8th Spanish-Portuguese-Japanese Organic Chemistry Symposium (8th SPJ-OCS)
  • Int'l Joint Research
• [Presentation] Chemoselective Transformations of Aromatic Methoxymethyl Ethers with Combination of Trialkylsilyl Trifrate and 2,2’-Bipyridyl (2018)
  • Author(s): Yanagihara, M.; Ohta, R.; Murai, K.; Arisawa, M.; Fujioka, H.
  • Organizer: IKCOC-14
  • Int'l Joint Research
• [Presentation] Selective Transformation of β‐Disubstituted Enones and Ynones in the Presence of β‐Monosubstituted Enones (2018)
  • Author(s): Wada, Y.; Fujii, Y.; Takehara, T.; Suzuki, T.; Murai, K.; Fujioka, H.; Arisawa, M.
  • Organizer: IKCOC-14
• [Presentation] Self-assembled Pd-nanoparticles Catalyzed Reactions (2018)
  • Author(s): Hirabayashi, S.; Xiao, M.; Akiyama, T.; Yamada, M.; Murai, K.; Fujioka, H.; Arisawa, M.
  • Organizer: IKCOC-14
• [Presentation] Development of Highly Efficient Metal Nano-particle Catalyst toward Drug Discovery (2017)
  • Author(s): Arisawa, M.
  • Organizer: 日本薬学会第137年会
  • Place of Presentation: 仙台
  • Year and Date: 2017-03-24
  • Invited
• [Presentation] ピリジン環への位置選択的トリフルオロメチル化反 応の開発 (2017)
  • Author(s): kuboki, Y.; Ohta, R.; Arisawa, M.; Fujhioka, H.
  • Organizer: 日本薬学会第137年会
  • Place of Presentation: 仙台
  • Year and Date: 2017-03-24
• [Presentation] 鉄ナノ粒子触媒を用いたリガンドフリー熊田カップ リング反応の開発 (2017)
  • Author(s): Akiyama, T.; Taniguchi, T.; Honma, T.; Tamenori, Y.; Sato, Y.; Fujioka, H.; Arisawa, M.
  • Organizer: 日本薬学会第137年会
  • Place of Presentation: 仙台
  • Year and Date: 2017-03-24
• [Presentation] ホスホニウム塩中間体を用いた one-pot エーテル環 合成法の開発 (2017)
  • Author(s): Morita, K.; Ohta, R.; Aoyama, H.; Arisawa, M.; Fujioka, H.
  • Organizer: 日本薬学会第137年会
  • Place of Presentation: 仙台
  • Year and Date: 2017-03-24
• [Presentation] Palladium-catalyzad migratory cycloisomerization of N-allyl-o-allenylaniline delivatives (2017)
  • Author(s): Ii, Y.; Aoyama, H.; Fujioka, H.; Arisawa, M.
  • Organizer: 19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis, OMCOS 19
  • Int'l Joint Research
• [Presentation] One-pot Enyne metathesis/Diels-Alder/Oxidation to Six-membered Silacycles with a Multi-ring Core: Discovery of a Novel fluorophore (2017)
  • Author(s): Yoshioka, S.; Fujii, Y.; Tsujino, H.; Uno, T.; Fujioka, H.; Arisawa, M.
  • Organizer: 19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis, OMCOS 19
  • Int'l Joint Research
• [Presentation] Recyclable, Low-Leaching, and Ligand-Free Suzuki?Miyaura Coupling Using Ruthenium(0) Nanoparticles (2017)
  • Author(s): Akiyama,T.; Taniguchi, T.; Honma, T.; Tamenori, Y.; Fujioka, H.; Sato, Y.; Arisawa, M.
  • Organizer: 19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis, OMCOS 19
  • Int'l Joint Research
• [Presentation] Synthesis of Novel Nitrogen-containing Polyheterocycles Via Ruthenium-catalyzed One-pot Metathesis / Non-metathesis Reaction (2017)
  • Author(s): Fujii, Y.; Yamashita, K.; Yoshioka, S.; Shuto, S.; Fujioka, H.; Arisawa, M.
  • Organizer: 18th Tetrahedron Symposium - Asia Edition
  • Int'l Joint Research
• [Presentation] Highly Discriminative Two-type Transformations of α,β-Unsaturated Esters in the Presence of Enones and Concise Synthesis of Oxacyclic Compounds (2017)
  • Author(s): Morita, K.; Ohta, R.; Yahata, K.; Arisawa, M.; Fujioka, H.
  • Organizer: 18th Tetrahedron Symposium - Asia Edition
  • Int'l Joint Research
• [Presentation] Design and Synthesis of (+)-Hypusine Analogue to Obtain its RNA Aptamers (2017)
  • Author(s): Ohta, R.; Oguro, A.; Nishimura, K.; Fujioka, H.; Arisawa, M.
  • Organizer: 18th Tetrahedron Symposium - Asia Edition
  • Int'l Joint Research
• [Presentation] 機能性分子合成を指向した有機金属触媒並びにワンポット反応の開発 (2017)
  • Author(s): Arisawa, M.
  • Organizer: 明治薬科大学若手研究者講話会
  • Place of Presentation: 東京
  • Invited
• [Presentation] 機能性分子合成を指向した有機金属触媒並びにワンポット反応の開発 (2017)
  • Author(s): Arisawa, M.
  • Organizer: 日本薬学会東海支部特別講演会
  • Place of Presentation: 岐阜
  • Invited
• [Presentation] Aplysiallene の新規合成法の開発とNa+/K+ ATPase 阻害活性研究 (2016)
  • Author(s): Yoshikawa, Y.; Yamakawa, M.; Kobayashi, T.; Suzuki, K.; Okino, Y.; Arisawa, M.; Fujioka, H.
  • Organizer: 第34回メディシナルケミストリーシンポジウム
  • Place of Presentation: つくば
  • Year and Date: 2016-11-30
• [Presentation] (+)-Laurenidificin の全合成と構造決定 (2016)
  • Author(s): Yoshikawa, Y.; Yamakawa, M.; Kobayashi, T.; Arisawa, M.; Fujioka, H.
  • Organizer: 第42回反応と合成の進歩シンポジウム
  • Place of Presentation: 静岡
  • Year and Date: 2016-11-07
• [Presentation] 芳香族エナミドの 1,6 －エニン環化異性化反応を用いた多置換インドール合成法の開発 (2016)
  • Author(s): Takamoto, K.; Hyogo, N.; Ohno, S.; Fujioka, H.; Arisawa, M.
  • Organizer: 第42回反応と合成の進歩シンポジウム
  • Place of Presentation: 静岡
  • Year and Date: 2016-11-07
• [Presentation] Palladium Nanoparticle-Catalyzed Carbon(sp＜sup＞2＜sup＞ and sp＜sup＞3＜sup＞)-Hydrogen Bond Functionalizations (2016)
  • Author(s): Takagi, K.; Al-Amin, M.; Hoshiya, N.; Sugimoto, H.; Shiro, Y.; Tobisu, M.; Chatani, N.; Shuto, S.; Arisawa, M.
  • Organizer: International Symposium on C-O Activation (ISCO-2016)
  • Place of Presentation: Himeji,Japan
  • Year and Date: 2016-10-25
  • Int'l Joint Research
• [Presentation] エノン存在下α,β不飽和エステル選択的変換法の開発と環状エーテル合成への応用 (2016)
  • Author(s): Morita, K.; Ohta, R.; Aoyama, H.; Arisawa, M.; Fujioka, H.
  • Organizer: 第46回 複素環化学討論会
  • Place of Presentation: 金沢
  • Year and Date: 2016-09-26
• [Presentation] ルテニウムナノ粒子触媒を用いたリガンドフリー鈴木－宮浦反応の開発 (2016)
  • Author(s): Akiyama, T.; Honma, T.; Fujioka, H.; Sato, Y.; Arisawa, M.
  • Organizer: 第46回 複素環化学討論会
  • Place of Presentation: 金沢
  • Year and Date: 2016-09-26
• [Presentation] ルテニウムヒドリド触媒を用いたエノールエーテ ルの 1,6-エイン環化異性化反応の開発 (2016)
  • Author(s): Ohno, S.; Takamoto, K.; Fujioka, H.; Arisawa, M.
  • Organizer: 第 63 回 有機金属化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2016-09-14
• [Presentation] ノンメタセシス反応を利用したアザビシクロ[3.1.1]ヘプテンの合成;ルテニウム触媒を用いたアレナ ミドーエンの分子内[2+2]環化付加反応 (2016)
  • Author(s): Ii, Y.; Yoneshige, Y.; Nada, T.; Matsumoto, T.; Fujioka, H.; Shuto, S.; Arisawa, M.
  • Organizer: 第 63 回 有機金属化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2016-09-14
• [Presentation] Synthesis of novel polycyclic nitrogen-containing compounds via ruthenium-catalyzed one-pot metathesis / non-metathesis reaction (2016)
  • Author(s): Fujii, Y.; Yamashita, K.; Yoshioka, S.; Shuto, S.; Fujioka, H.; Arisawa, M.
  • Organizer: 27th International Conference on Organometallic Chemistry (ICOMC 2016)
  • Place of Presentation: Melbourne,Australia
  • Year and Date: 2016-07-17
  • Int'l Joint Research
• [Presentation] Nickel-Catalyzed Hydrocarboxylation of Alkynes and Styrenes Using Sulfur-Modified Au-Supported Nickel Nanoparticles Catalyst (2016)
  • Author(s): Taniguchi, T.; Saito, N.; Hoshiya, N.; Fujiki, K.; Shuto, S.; Fujioka, H.; Arisawa M.; Sato, Y.
  • Organizer: 27th International Conference on Organometallic Chemistry (ICOMC 2016)
  • Place of Presentation: Melbourne,Australia
  • Year and Date: 2016-07-17
  • Int'l Joint Research
• [Presentation] Non-metathesis heterocycle formation by ruthenium-catalyzed intramolecular [2+2] cycloaddition of allenamide-enes to azabicyclo[3.1.1]heptanes (2016)
  • Author(s): Arisawa, M.; Yoneshige, Y.; Nada, T.; Shuto, S.; Fujioka, H.
  • Organizer: 27th International Conference on Organometallic Chemistry (ICOMC 2016)
  • Place of Presentation: Melbourne,Australia
  • Year and Date: 2016-07-17
  • Int'l Joint Research
• [Presentation] Ruthenium-Catalyzed 1,6-Enyne Cycloisomerization of Phenyl Enol Ether: Synthesis of 2,3-Disubstituted Benzo[b]furans (2016)
  • Author(s): Ohno, S.; Takamoto, K.; Fujioka, H.; Arisawa, M.
  • Organizer: The 20th International Symposium on Homogeneous Catalysis (ISHC XX)
  • Place of Presentation: Kyoto,Japan
  • Year and Date: 2016-07-10
  • Int'l Joint Research
• [Presentation] Non-Metathesis Heterocycle Formation by Ruthenium-Catalyzed Intramolecular [2+2] Cycloaddition of Allenamide-enes to Azabicyclo[3.1.1]heptanes (2016)
  • Author(s): Arisawa, M.; Yoneshige, Y.; Nada, T.; Ii, Y.; Shuto, S.; Fujioka, H.
  • Organizer: The 20th International Symposium on Homogeneous Catalysis (ISHC XX)
  • Place of Presentation: Kyoto,Japan
  • Year and Date: 2016-07-10
  • Int'l Joint Research
• [Presentation] 硫黄修飾金担持型ニッケル触媒SANiの開発と二酸化炭素固定化反応への利用 (2016)
  • Author(s): Taniguchi, T.; Saito, N.; Hoshiya, N.; Fujiki, K.; Shuto, S.; Fujioka, H.; Arisawa, M.; Sato, Y.
  • Organizer: 第14回次世代を担う有機化学シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2016-05-27
• [Presentation] メタセシス/ノンメタセシス連続反応の開発とそれを用いた新規多環式含窒素ヘテロ環化合物の合成及び機能解析 (2016)
  • Author(s): Fujii, Y.; Yamashita, K.; Yoshioka, S.; Fujioka, H.; Shuto, S.; Arisawa, M.
  • Organizer: 第14回次世代を担う有機化学シンポジウム
  • Place of Presentation: 東京
  • Year and Date: 2016-05-27
• [Presentation] Synthetic Study of Laurenidificin (2016)
  • Author(s): Yoshikawa,Y.; Yamakawa, M.; Kobayashi, T.;Arisawa, M.; Fujioka, H.
  • Organizer: Molecular Chirality Asia 2016
  • Place of Presentation: Osaka,Japan
  • Year and Date: 2016-04-20
  • Int'l Joint Research
• [Presentation] GABAトランスポーターサブタイプ特異的な新規阻害薬候補化合物の薬理活性評価 (2016)
  • Author(s): 佐藤孝行,井川ありさ,圓山智嘉史,末政亮大,小林嵩明,有澤光弘,井手聡一郎,周東智,南雅文
  • Organizer: 日本薬学会136年会
  • Place of Presentation: 神奈川県、横浜市（パシフィコ横浜）
  • Year and Date: 2016-03-26
• [Presentation] エインメタセシス/Diels-Alder/酸化の3連続ワンポット反応を用いた新規含ケイ素多環式化合物の合成 (2016)
  • Author(s): 吉岡祥平,藤居由基,藤岡弘道,有澤光弘
  • Organizer: 日本薬学会136年会
  • Place of Presentation: 神奈川県、横浜市（パシフィコ横浜）
  • Year and Date: 2016-03-26
• [Presentation] Microwaveとガラス担持型 Pdナノ粒子触媒を用いたブロモベンゼンの鈴木-宮浦カップリング反応の開発 (2016)
  • Author(s): Mincen Xiao,藤岡弘道,有澤光弘
  • Organizer: 日本薬学会136年会
  • Place of Presentation: 神奈川県、横浜市（パシフィコ横浜）
  • Year and Date: 2016-03-26
• [Presentation] 硫黄修飾金担持型ルテニウム触媒を用いたリガンドフリー鈴木-宮浦反応の開発 (2016)
  • Author(s): 秋山敏毅,藤岡弘道,佐藤美洋,有澤光弘
  • Organizer: 日本薬学会136年会
  • Place of Presentation: 神奈川県、横浜市（パシフィコ横浜）
  • Year and Date: 2016-03-26
• [Presentation] Syntheses of orthoquinone containing aromatic compounds and their redox chromism (2016)
  • Author(s): URAKAWA, Kazuki; SUMIMOTO, Michinori; ARISAWA, Mitsuhiro; MATSUDA, Masaki; ISHIKAWA, Hayato
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 京都府、京田辺市（同志社大学）
  • Year and Date: 2016-03-24
• [Presentation] Development of Sulfur-Modified Au-Supported Nickel Catalyst (SANi) and Its Application to Catalytic Carboxylation of Multiple Bonds (2016)
  • Author(s): TANIGUCHI, Takahisa; SAITO, Nozomi; HOSHIYA, Naoyuki; FUJIKI, Katsumasa; SHUTO, Satoshi; FUJIOKA, Hiromichi; ARISAWA, Mitsuhiro; SATO, Yoshihiro
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 京都府、京田辺市（同志社大学）
  • Year and Date: 2016-03-24
• [Presentation] 機能性分子合成を指向した有機金属触媒並びにワンポット反応の開発 (2016)
  • Author(s): Arisawa, M.
  • Organizer: 熊本大学大学院自然科学研究科特別講演会
  • Place of Presentation: 熊本
  • Invited
• [Presentation] 硫黄修飾金担持型ルテニウムナノ粒子触媒の開発とリガンドフリー鈴木－宮浦反応への応用 (2016)
  • Author(s): Akiyama, T.; Honma, T.; Fujioka, H.; Sato, Y.; Arisawa, M.
  • Organizer: 第36回有機合成若手セミナー「明日の有機合成を担う人のために」
  • Place of Presentation: 京都
• [Presentation] ケトホスホニウム塩形成を利用したエノン存在下でのα，βー不飽和エステルのオレフィン部位選択的変換法の開発 (2016)
  • Author(s): Morita, K.; Ohta, R.; Aoyama, H.; Arisawa, M.; Fujioka, H.
  • Organizer: 第36回有機合成若手セミナー「明日の有機合成を担う人のために」
  • Place of Presentation: 京都
• [Presentation] β 位置換様式の異なるエノン間の識別的変換反応の開発とその応用 (2016)
  • Author(s): Morita, K.; Ohta, R.; Watanabe, K.; Aoyama, H.; Arisawa, M.; Fujioka, H.
  • Organizer: 第66回 日本薬学会近畿支部総会・大会
  • Place of Presentation: 高槻
• [Presentation] 置換オキシインドール及び置換 3,4-ジヒドロキノリノンの合成 (2016)
  • Author(s): Miyata, K.; Xiao, M.; Fujioka, H.; Arisawa, M.
  • Organizer: 第66回 日本薬学会近畿支部総会・大会
  • Place of Presentation: 高槻
• [Presentation] 芳香族エナミドを用いる多置換インドール合成法の開発 (2016)
  • Author(s): Takamoto, K.; Hyogo, N.; Ohno, S.; Fujioka, H.; Arisawa, M.
  • Organizer: 第66回 日本薬学会近畿支部総会・大会
  • Place of Presentation: 高槻
• [Presentation] (-)-Aplysiallene およびその誘導体合成とNa+/K+ ATPase 阻害活性研究 (2015)
  • Author(s): 山川真希,吉川祐介,鈴木邦明,沖野雄一郎,有澤光弘,藤岡弘道
  • Organizer: 第33回メディシナルケミストリーシンポジウム
  • Place of Presentation: 千葉県、千葉市（幕張国際研修センター）
  • Year and Date: 2015-11-25
• [Presentation] A One-Pot Olefin Isomerization / Aliphatic Enamine Ring-Closing Metathesis (RCM) / Oxidation / 1,3-Dipolar Cycloaddition for the Synthesis of Isoindolo[1,2-a] isoquinolines (2015)
  • Author(s): Yuki Fujii, Hiromichi Fujioka, Satoshi Shuto, Mitsuhiro Arisawa
  • Organizer: 第13回国際有機化学京都会議：IKCOC-13
  • Place of Presentation: 京都府、京都市（リーガロイヤルホテル京都）
  • Year and Date: 2015-11-09
  • Int'l Joint Research
• [Presentation] Pd(II)-Catalyzed Directing Group-Mediated Arylation and Alkylation of Tertiary C(sp3)-H Bond on Chiral Cyclopropanes (2015)
  • Author(s): Naoyuki Hoshiya, Kei Takenaka, Mitsuhiro Arisawa, Satoshi Shuto, Jun’ichi Uenishi
  • Organizer: 第13回国際有機化学京都会議：IKCOC-13
  • Place of Presentation: 京都府、京都市（リーガロイヤルホテル京都）
  • Year and Date: 2015-11-09
  • Int'l Joint Research
• [Presentation] Sulfur-Modified Au-Supported Nickel Nanoparticles Catalyst (SANi)-Catalyzed Hydrocarboxylation of Alkynes (2015)
  • Author(s): Takahisa Taniguchi, Nozomi Saito, Naoyuki Hoshiya, Katsumasa Fujiki, Satoshi Shuto, Hiromichi Fujioka, Mitsuhiro Arisawa, Yoshihiro Sato
  • Organizer: 第13回国際有機化学京都会議：IKCOC-13
  • Place of Presentation: 京都府、京都市（リーガロイヤルホテル京都）
  • Year and Date: 2015-11-09
  • Int'l Joint Research
• [Presentation] Ru-Catalyzed 1,6-Enyne Cycloisomerization of Aromatic Enamide, New Strategy toward 2,3Disubstituted Indole (2015)
  • Author(s): Kohei Takamoto, Norimichi Hyogo, Hiromichi Fujioka, Mitsuhiro Arisawa
  • Organizer: 第13回国際有機化学京都会議：IKCOC-13
  • Place of Presentation: 京都府、京都市（リーガロイヤルホテル京都）
  • Year and Date: 2015-11-09
  • Int'l Joint Research
• [Presentation] 1,6-エイン環化異性化反応を用いた2,3-二置換インドール合成法の開発 (2015)
  • Author(s): 高本康平、兵後訓道、大野祥平、藤岡弘道、有澤光弘
  • Organizer: 第108回有機合成シンポジウム
  • Place of Presentation: 東京都、新宿区（早稲田大学）
  • Year and Date: 2015-11-05
• [Presentation] エインメタセシス/異性化/Diels-Alderワンポット反応を用いた新規含窒素多環式化合物の合成とその機能解析 (2015)
  • Author(s): 山下航平，藤居由基，吉岡祥平，藤岡弘道，有澤光弘
  • Organizer: 第41回反応と合成の進歩シンポジウム
  • Place of Presentation: 大阪府、東大阪市（近畿大学）
  • Year and Date: 2015-10-26
• [Presentation] 生体内ポリアミン標的RNAアプタマーの取得に向けたハイプシン誘導体の合成 (2015)
  • Author(s): 太田礼伊也，阿部敬介，小黒明広，西村和洋，有澤光弘，藤岡弘道
  • Organizer: 第41回反応と合成の進歩シンポジウム
  • Place of Presentation: 大阪府、東大阪市（近畿大学）
  • Year and Date: 2015-10-26
• [Presentation] エノールエーテルの 1,6-エイン環化異性化反応の開発 2,3-二置換ベンゾフランの新規合成法 (2015)
  • Author(s): 大野祥平、高本康平、藤岡弘道、有澤光弘
  • Organizer: 第65回 日本薬学会近畿支部総会
  • Place of Presentation: 大阪府、富田林市（大阪大谷大学）
  • Year and Date: 2015-10-17
• [Presentation] Grubbs触媒を用いたN-アレニル -o-ビニルアニリン誘導体の分子内[2+2]環化反応新規含窒素複素環骨格アザビシクロ [3.1.1]ヘプタン骨格の構築とその化学変換 (2015)
  • Author(s): 米重勇祐、名田智美、周東智、藤岡弘道、有澤光弘
  • Organizer: 第65回 日本薬学会近畿支部総会
  • Place of Presentation: 大阪府、富田林市（大阪大谷大学）
  • Year and Date: 2015-10-17
• [Presentation] ルテニウムヒドリドを用いた複素環化合物の合成 (2015)
  • Author(s): 有澤光弘、高本康平、大野祥平、兵後訓道、藤岡弘道
  • Organizer: 平成27年度有機合成化学北陸セミナー
  • Place of Presentation: 富山県、富山市（富山観光ホテル）
  • Year and Date: 2015-10-02
• [Presentation] 硫黄修飾された金担持型ニッケルナノパーティクルの開発とその有機合成への応用 (2015)
  • Author(s): 星谷尚亨・藤木勝将・谷口敬寿・周東智・藤岡弘道・齋藤望・佐藤美洋・ 有澤光弘
  • Organizer: 第62回有機金属化学討論会
  • Place of Presentation: 大阪府、吹田市（関西大学）
  • Year and Date: 2015-09-07
• [Presentation] 新規オレフィン異性化 /エナミン閉環メタセシス (RCM)/1,3-双極子付加環化ワンポット反応の開発とそれを用いたイソインドロ[1,2-a]イソキノリンの合成 (2015)
  • Author(s): 藤居由基・嵩原綱吉・鈴木健之・藤岡弘道・周東智・有澤光弘
  • Organizer: 第62回有機金属化学討論会
  • Place of Presentation: 大阪府、吹田市（関西大学）
  • Year and Date: 2015-09-07
• [Presentation] 1,6-Cycloisomerization to give 2,3-disubstituted indole catalyzed by ruthenium hydride with N- heterocyclic carbene ligand (2015)
  • Author(s): Kohei, Takamoto, Norimichi Hyogo, Hiromichi Fujioka, Mitsuhiro Arisawa
  • Organizer: 第250回アメリカ化学会 ACS National Meeting & Exposition
  • Place of Presentation: アメリカ合衆国、ボストン
  • Year and Date: 2015-08-16
  • Int'l Joint Research
• [Presentation] Development of One-pot Ring-closing(RCM)/ 1,3-Dipolar Reaction Using Ruthenium Carbene Catalysts and Its Application to the Synthesis of Novel Polycyclic Heterocycle (2015)
  • Author(s): Yuki Fujii, Hiromichi Fujioka, Satoshi Shuto, and Mitsuhiro Arisawa
  • Organizer: 21st International Symposium on Olefin Metathesis and RelatedChemistry (ISOM XXI)
  • Place of Presentation: オーストリア、グラーツ
  • Year and Date: 2015-07-12
  • Int'l Joint Research
• [Presentation] Development of enyne metathesis / isomerization / Diels-Alder one-pot reaction for novel NIR dye (2015)
  • Author(s): Kohei Yamashita, Hiroshi Aoyama, Hiromichi Fujioka, and Mitsuhiro Arisawa
  • Organizer: 21st International Symposium on Olefin Metathesis and RelatedChemistry (ISOM XXI)
  • Place of Presentation: オーストリア、グラーツ
  • Year and Date: 2015-07-12
  • Int'l Joint Research
• [Presentation] Nickel-Catalyzed Carboxylation of Alkynes Using Sulfur-Modified Au-Supported Nickel Nanoparticles Catalyst (SANi) (2015)
  • Author(s): Takahisa Taniguchi, Nozomi Saito, Naoyuki Hoshiya, Katsumasa Fujiki, Satoshi Shuto, Tetsuo Honma, Hiromichi Fujioka, Mitsuhiro Arisawa and Yoshihiro Sato
  • Organizer: 18th IUPAC International Symposium on Organometallic ChemistryDirected Towards Organic Synthesis (OMCOS 18)
  • Place of Presentation: スペイン、バルセロナ
  • Year and Date: 2015-06-28
  • Int'l Joint Research
• [Presentation] ハイプシン結合RNAアプタマー取得を目的とするハイプシン誘導体の設計と合成 (2015)
  • Author(s): 阿部 敬介, 小黒 明広, 西村 和洋, 市川 哲也, 藤岡 弘道, 有澤 光弘
  • Organizer: 日本薬学会第135年会
  • Place of Presentation: 神戸学院大学（神戸市）
  • Year and Date: 2015-03-28
• [Presentation] 硫黄修飾金担持型ニッケル触媒の開発とアルキンへの二酸化炭素固定化反応の利用 (2015)
  • Author(s): 谷口 敬寿, 齋藤 望, 星谷 尚亨, 周東 智, 本間 徹生, 藤岡 弘道, 有澤 光弘, 佐藤美洋
  • Organizer: 日本薬学会第135年会
  • Place of Presentation: 神戸学院大学（神戸市）
  • Year and Date: 2015-03-26
• [Presentation] 硫黄修飾金担持型ニッケル触媒を用いたリガンドフリークロスカップリング反応の開発 (2015)
  • Author(s): 藤木 勝将, 星谷 尚亨, 谷口 敬寿, 周東 智, 藤岡 弘道, 斎藤 望, 佐藤 美洋, 有澤光弘
  • Organizer: 日本薬学会第135年会
  • Place of Presentation: 神戸学院大学（神戸市）
  • Year and Date: 2015-03-26
• [Presentation] エインメタセシス/異性化/Diels-Alder ワンポット反応の開発 (2015)
  • Author(s): 山下 航平, 藤岡 弘道, 有澤 光弘
  • Organizer: 日本薬学会第135年会
  • Place of Presentation: 神戸学院大学（神戸市）
  • Year and Date: 2015-03-26
• [Presentation] Pd および Ni 触媒によるシクロプロパン第三級炭素上への芳香環導入反応 ―効率的化学空間探索型創薬ライブラリーの構築を目指して― (2014)
  • Author(s): 星谷尚亨,四辻慶佑,小林嵩明,福田 隼,阿部 洋,有澤光弘,周東 智
  • Organizer: 第40回反応と合成の進歩シンポジウム
  • Place of Presentation: 東北大学萩ホール（仙台市）
  • Year and Date: 2014-11-11
• [Presentation] Pd ナノ粒子触媒 SAPd を用いたアリルエステルの脱アリル化反応の開発 (2014)
  • Author(s): 高木耕治,福田 隼,阿部 洋,周東 智,大高 章,有澤光弘
  • Organizer: 第40回反応と合成の進歩シンポジウム
  • Place of Presentation: 東北大学萩ホール（仙台市）
  • Year and Date: 2014-11-11
• [Presentation] Ligand-free Suzuki-Miyaura Coupling with Sulfur-modified Gold-supported Palladium in the Synthesis of a Conformationally-Restricted Cyclopropane Compound Library with Three-Dimensional Diversity (2014)
  • Author(s): Mitsuhiro Arisawa, Takatoshi Sato, Naoyuki Hoshiya, Mohammad Al-Amin, Yuji Kogami and Satoshi Shuto
  • Organizer: The 2nd International Conference on Organometallics and Catalysis
  • Place of Presentation: Todaiji Temple Cultural Center（奈良市）
  • Year and Date: 2014-10-27
• [Presentation] 有機金属触媒を用いた機能性分子の創製 (2014)
  • Author(s): 有澤光弘
  • Organizer: 名城大学特別講演会
  • Place of Presentation: 名城大学（名古屋市）
  • Year and Date: 2014-10-10
  • Invited
• [Presentation] 硫黄修飾ガラス担持型パラジウムの開発:リガンドフリーBuchwald-Hartwig 反応 (2014)
  • Author(s): XiaoMincen、星谷尚亨、周東 智、藤岡弘道、 有澤光弘
  • Organizer: 第64回 日本薬学会近畿支部総会・大会
  • Place of Presentation: 京都薬科大学（京都市）
  • Year and Date: 2014-10-10
• [Presentation] Ring-closing metathesis (RCM)/1,3-dipolar cycloaddition for the synthesis of isoindolo[2,1-a]quinolone structure dye (2014)
  • Author(s): Mitsuhiro Arisawa
  • Organizer: ETH Zürich – Osaka University Joint-symposium
  • Place of Presentation: 大阪大学基礎工学部Σホール（豊中市）
  • Year and Date: 2014-10-09
  • Invited
• [Presentation] 硫黄修飾ガラス担持型パラジウムの開発:リガン ドフリーBuchwald-Hartwig 反応 (2014)
  • Author(s): 肖 玟岑・星谷 尚亨・周東 智・藤岡 弘 道・有澤 光弘
  • Organizer: 第61回有機金属化学討論会
  • Place of Presentation: 九州大学病院キャンパス 医学部 百年講堂（福岡市）
  • Year and Date: 2014-09-25
• [Presentation] Grubbs 触媒を用いたアレンーエンの分子内[2+2]環 化反応:アザビシクロ[3.1.1]ヘプタン骨格の合成 (2014)
  • Author(s): 米重 勇祐・名田 智美・周東 智・ 藤岡 弘道・有澤 光弘
  • Organizer: 第61回有機金属化学討論会
  • Place of Presentation: 九州大学病院キャンパス 医学部 百年講堂（福岡市）
  • Year and Date: 2014-09-24
• [Presentation] ルテニウムカルベン錯体を用いたワンポット反応の開発と新規多環性複素環骨格の構築 (2014)
  • Author(s): 藤居 由基 ・加藤 宏茂・福田 隼・阿部 洋 ・藤岡 弘道 ・周東 智 ・有澤 光弘
  • Organizer: 第 44 回 複素環化学討論会
  • Place of Presentation: 札幌市民ホール（札幌市）
  • Year and Date: 2014-09-10
• [Presentation] 硫黄修飾金に担持した有機合成用金属ナノ粒子触媒の開発 (2014)
  • Author(s): 有澤光弘
  • Organizer: 第11回Spring-8産業利用報告会
  • Place of Presentation: 姫路商工会議所（姫路市）
  • Year and Date: 2014-09-04
  • Invited
• [Presentation] 硫黄修飾金に担持したニッ ケルナノ粒子触媒の開発 (2014)
  • Author(s): 藤木勝将、星谷尚之、谷口敬寿、 藤岡弘道、周東智、齋藤望、佐藤美洋、有澤光弘
  • Organizer: 第３４回有機合成若手セミナー「明日の有機合成を担う人のために」
  • Place of Presentation: 大阪大学会館（豊中市）
  • Year and Date: 2014-08-05
• [Presentation] One-Pot Ring-Closing Metathesis (RCM)/1,3-Dipolar Cycloaddition by an Assisted Tandem Ruthenium Catalysis for the Synthesis of an Isoindolo[2,1-a]quinoline Structure Dye (2014)
  • Author(s): Mitsuhiro Arisawa, Yuki Fujii, Hiroshige Kato, Hayato Fukuda, Hiroshi Abe, Hiromichi Fujioka, Satoshi Shuto
  • Organizer: XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
  • Place of Presentation: ロイトン札幌（札幌市）
  • Year and Date: 2014-07-14
• [Presentation] レゾルビンE2の安定化を指向した構造活性相関研究 (2014)
  • Author(s): 高倉 夕季 福田 隼 石村 航平 田辺 真人 有澤 光弘 周東 智
  • Organizer: 日本薬学会北海道支部 第141回例会
  • Place of Presentation: 札幌コンベンションセンター（札幌市）
  • Year and Date: 2014-05-24
• [Book] 天然有機分子の構築 (2018)
  • Author(s): 日本化学会、中川 昌子、有澤 光弘
  • Total Pages: 148
  • Publisher: 共立出版
  • ISBN: 9784320044678
• [Book] ヘテロ環の化学: 基礎と応用 (2016)
  • Author(s): Nakagawa, M.; Arisawa, M.
  • Total Pages: 256
  • Publisher: 東京化学同人
• [Book] ヘテロ環の化学:基礎と応用 (2016)
  • Author(s): 中川昌子、有澤光弘
  • Total Pages: 256
  • Publisher: 東京化学同人
• [Remarks] 大阪大学・大学院薬学研究科 分子合成化学分野
  • URL: http://gosei.sakura.ne.jp/gosei/
• [Remarks] 大阪大学大学院薬学研究科分子合成化学分野
  • URL: http://gosei.sakura.ne.jp/gosei/
• [Patent(Industrial Property Rights)] Composite containing catalytic metal nanoparticles, and use for same (2016)
  • Inventor(s): Arisawa,M.;Shuto,S.;Hoshiya,N.
  • Industrial Property Rights Holder: Arisawa,M.;Shuto,S.;Hoshiya,N.
  • Industrial Property Rights Type: 特許
  • Filing Date: 2016-06-09
  • Acquisition Date: 2016-12-22