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Preparation of polymer particles having changeable properties and control of colloidal structure

Research Project

Project/Area Number 26288103
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionKobe University

Principal Investigator

MINAMI Hideto  神戸大学, 工学(系)研究科(研究院), 准教授 (20283872)

Co-Investigator(Kenkyū-buntansha) 鈴木 登代子  神戸大学, 工学(系)研究科(研究院), 助教 (40314504)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2016: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Keywords微粒子 / ポリイオン液体 / 粒子配列 / 高分子材料合成 / 高分子合成 / 表面・界面物性 / イオン液体 / 表面・界面物性 / イオン液体ポリマー / 粒子材料 / 粒子構造 / ヤヌス粒子 / 鎖状構造体
Outline of Final Research Achievements

Seeded dispersion polymerization of ionic liquid monomer was carried out in the presence of poly(methylmethacrylate) (PMMA) as seed and composite particles with poly(ionic liquid) (PIL) were obtained. Moreover, we showed that anion exchange of the composite particles can be used to modify the properties of only the PIL component of the composite particles. PIL particles with a single-hollow are also prepared by suspension polymerization from monomer droplets consisting of the ionic liquid monomer, ethylene glycol dimethacrylate, and n-butyl acetate. The obtained particles can be changed from hydrophobic to hydrophilic by anion exchange. Moreover, Janus particles with two hemispheres having different stabilizers, a polystyrene (PS) phase stabilized by poly(acrylic acid) and a PMMA phase stabilized by poly(vinyl pyrrolidone), were able to be synthesized. The facile formation of the colloidal chains via hydrogen bonding interaction between different stabilizers were demonstrated.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(40 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (10 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 10 results,  Acknowledgement Compliant: 9 results) Presentation (28 results) (of which Int'l Joint Research: 10 results,  Invited: 5 results)

  • [Int'l Joint Research] University of New South Wales/University of Tasmania(Australia)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University of New South Wales(オーストラリア)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Morphological change of thermosensitive imidazolium-based poly(ionic liquid)/poly (phenylethylmethacrylate) composite particles2017

    • Author(s)
      Masayoshi Tokuda, Toyoko Suzuki, Hideto Minami
    • Journal Title

      Polym. Adv. Technol.

      Volume: 28 Pages: 470-475

    • DOI

      10.1002/pat.3907

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Encapsulation of Either Hydrophilic or Hydrophobic Substances in Spongy Cellulose Particles2017

    • Author(s)
      Taro Omura, Kaori Imagawa, Kyosuke Kono, Toyoko Suzuki, and Hideto Minami
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 9 Pages: 944-949

    • DOI

      10.1021/acsami.6b13261

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Polymeric Nanoparticles Containing Reduced Graphene Oxide Nanosheets Stabilized by Poly(ionic liquid) using Miniemulsion Polymerization2016

    • Author(s)
      Masayoshi Tokuda, Mitsuyoshi Yamane, Stuart C. Thickett, Hideto Minami, Per B. Zetterlund
    • Journal Title

      Soft Matter

      Volume: 12 Pages: 3955-3962

    • DOI

      10.1039/c6sm00269b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Preparation of Poly(ionic liquid) Composite Particles and Function Modification with Anion Exchange2016

    • Author(s)
      Masayoshi Tokuda, Tatsunori Shindo, Toyoko Suzuki, Hideto Minami
    • Journal Title

      RSC Advances

      Volume: 6 Pages: 31574-31579

    • DOI

      10.1039/c6ra00564k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Polymer Particles Containing Reduced Graphene Oxide Nanosheets Using Ionic Liquid Monomer2016

    • Author(s)
      Masayoshi Tokuda, Stuart C. Thickett, Hideto Minami, Per B. Zetterlund
    • Journal Title

      Macromolecules

      Volume: 49 Pages: 1222-1228

    • DOI

      10.1021/acs.macromol.5b02216

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Preparation of Poly(ionic liquid) Hollow Particles with Switchable Permeability2016

    • Author(s)
      Ryuma Nakamura, Masayoshi Tokuda, Toyoko Suzuki, Hideto Minami
    • Journal Title

      Langmuir

      Volume: 32 Pages: 2331-2337

    • DOI

      10.1021/acs.langmuir.6b00263

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of the Molecular-Oriented Structure of Ionic Liquids on the Crystallinity of Aluminum Hydroxide Prepared by a Sol–Gel Process in Ionic Liquids2015

    • Author(s)
      Keigo Kinoshita, Hiroshi Yanagimoto, Toyoko Suzuki, Hideto Minami
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Pages: 18705-18709

    • DOI

      10.1039/c5cp02015h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Janus particles with different stabilizers and formation of one-dimensional particle arrays2015

    • Author(s)
      S. Onishi, M. Tokuda, T. Suzuki, H. Minami,
    • Journal Title

      Langmuir

      Volume: 31 Pages: 674-678

    • DOI

      10.1021/la504535k

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Submicron-sized Quaternary Ammonium-based Poly (ionic liquid) P articles via Emulsion Polymerization and Switchable Responsiveness of an Emulsi on Film2014

    • Author(s)
      Masayoshi Tokuda, Toshiharu Sanada, Tatsunori Shindo, Toyoko Suzuki, Hideto Minami
    • Journal Title

      Langmuir

      Volume: 30 Pages: 3406-3412

    • DOI

      10.1021/la500282n

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 水素結合を利用した有機/無機複合粒子の作製2014

    • Author(s)
      南 秀人,常 誠,鈴木登代子
    • Journal Title

      色材協会誌

      Volume: 87 Pages: 356-360

    • NAID

      130004736497

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Synthesis of Polymer Particles Containing Reduced Graphene Oxide Utilizing Poly(ionic liquid) as Stabilizer2016

    • Author(s)
      Mitsuyoshi Yamane, Masayoshi Tokuda, Stuart C. Thickett, Per B. Zetterlund, Hideto Minami
    • Organizer
      International Polymer Conference 2016
    • Place of Presentation
      福岡
    • Year and Date
      2016-12-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Silicone Particles via Ring-opening Polymerization of Cyclic Siloxane in Aqueous Medium2016

    • Author(s)
      Hiroki Mitsui, Satoshi Ikubo, Toyoko Suzuki, Hideto Minami
    • Organizer
      International Polymer Conference 2016
    • Place of Presentation
      福岡
    • Year and Date
      2016-12-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Polymeric Particles Containing Reduced Graphene Oxide by Miniemulsion Polymerization2016

    • Author(s)
      Hideto Minami
    • Organizer
      36th Australasian Polymer Symposium
    • Place of Presentation
      Lorne, Australia
    • Year and Date
      2016-11-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 汎用ポリマー/イオン液体ポリマー複合粒子のモルフォロジィ制御2016

    • Author(s)
      大内 卓太,中村 龍真,鈴木 登代子,南 秀人
    • Organizer
      第19回高分子ミクロスフェア討論会
    • Place of Presentation
      千葉
    • Year and Date
      2016-11-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] 溶剤吸収放出法を利用したイオン液体ポリマー複合粒子のモルフォロジィ制御2016

    • Author(s)
      大内 卓太,鈴木 登代子,南 秀人
    • Organizer
      2016年度色材研究発表会
    • Place of Presentation
      大阪
    • Year and Date
      2016-10-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリイオン液体中空粒子を用いた無機物質の導入2016

    • Author(s)
      林 千尋,中村 龍真,鈴木 登代子,南 秀人
    • Organizer
      2016年度色材研究発表会
    • Place of Presentation
      大阪
    • Year and Date
      2016-10-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 磁性を有するポリイオン液体中空粒子の合成2016

    • Author(s)
      林 千尋,中村 龍真,鈴木 登代子,南 秀人
    • Organizer
      第65回高分子学会討論会
    • Place of Presentation
      神奈川
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオン液体ポリマーを分散剤として用いた還元型酸化グラフェン含有汎用性高分子微粒子の合成2016

    • Author(s)
      山根 三慶,徳田 真芳,Stuart C. Thickett,Per B. Zetterlund,南 秀人
    • Organizer
      第65回高分子学会討論会
    • Place of Presentation
      神奈川
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオン液体ポリマーを用いた還元型酸化グラフェン含有高分子微粒子の合成2016

    • Author(s)
      山根 三慶,徳田 真芳,Stuart C. Thickett,Per B. Zetterlund,南 秀人
    • Organizer
      第62回高分子研究発表会(神戸)
    • Place of Presentation
      神戸
    • Year and Date
      2016-07-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Morphology Control of Poly(ionic liquid) Composite Particles2016

    • Author(s)
      Takuto Ouchi, Ryuma Nakamura, Toyoko Suzuki, Hideto Minami
    • Organizer
      Asian Conference on Adhesion 2016
    • Place of Presentation
      東京
    • Year and Date
      2016-06-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 汎用ポリマー/イオン液体ポリマー複合微粒子のモルフォロジィ制御2016

    • Author(s)
      大内 卓太,中村 龍真,鈴木 登代子,南 秀人
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水媒体不均一系での開環重合によるシリコーン粒子の作製2016

    • Author(s)
      三井 宏暉,井久保 智史,鈴木 登代子,南 秀人
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Preparation of functional polymer particles and formation of colloidal structures2016

    • Author(s)
      Hideto Minami
    • Organizer
      Seminar of Materials Science and Engineering
    • Place of Presentation
      北京,China
    • Year and Date
      2016-04-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation of Janus Particles with Different Stabilizers and Formation of Colloidal Chains2015

    • Author(s)
      Hideto Minami
    • Organizer
      The 5th Asian Symposium on Emulsion Polymerization and Functional Polymeric Microspheres
    • Place of Presentation
      蘇州市(中華人民共和国)
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation of Poly (ionic liquid) Hollow Particles Having Permeability-Switchable Shell2015

    • Author(s)
      Ryuma Nakamura, Masayoshi Tokuda, Toyoko Suzuki, Hideto Minami
    • Organizer
      The 5th Asian Symposium on Emulsion Polymerization and Functional Polymeric Microspheres
    • Place of Presentation
      蘇州市(中華人民共和国)
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Janus particles with different stabilizers and formation of one-dimensional particle chains2015

    • Author(s)
      Hideto Minami
    • Organizer
      International Science & Nature Congress 2015 (ISNaC2015)
    • Place of Presentation
      クアラルンプール(マレーシア)
    • Year and Date
      2015-09-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポリメタクリル酸メチル/ポリイオン液体複合粒子のモルフォロジィ制御2015

    • Author(s)
      大内 卓太, 中村 龍真, 鈴木 登代子, 南 秀人
    • Organizer
      第64回高分子学会討論会
    • Place of Presentation
      東北大学(宮城・仙台)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリイオン液体中空粒子の作製及びカプセル特性評価2015

    • Author(s)
      中村 龍真,徳田 真芳,鈴木 登代子,南 秀人
    • Organizer
      第64回高分子学会討論会
    • Place of Presentation
      東北大学(宮城・仙台)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 汎用ポリマー/イオン液体ポリマー複合粒子のモルフォロジィ制御2015

    • Author(s)
      大内 卓太,中村 龍真,鈴木 登代子,南 秀人
    • Organizer
      第61回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館(兵庫・神戸)
    • Year and Date
      2015-07-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] イオン液体ポリマー中空粒子の作製及びカプセル特性評価2015

    • Author(s)
      中村 龍真,徳田 真芳,鈴木 登代子,南 秀人
    • Organizer
      第61回高分子研究発表会(神戸)
    • Place of Presentation
      神戸兵庫県民会館(兵庫・神戸)
    • Year and Date
      2015-07-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] Colloidal building blocks using hydrogen bonding interactions between stabilizers2015

    • Author(s)
      Hideto Minami
    • Organizer
      IPCG Conference 2015
    • Place of Presentation
      ニューハンプシャー州ダーラム市(アメリカ合衆国)
    • Year and Date
      2015-07-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation of polymer particles containing reduced graphene oxide using ionic liquid monomer2015

    • Author(s)
      Masayoshi Tokuda, Stuart C. Thickett, Per B. Zetterlund, Hideto Minami
    • Organizer
      IPCG Conference
    • Place of Presentation
      ニューハンプシャー州ダーラム市(アメリカ合衆国)
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 異なる分散安定剤を有したヤヌス粒子の作製及び一次元粒子配列制御2015

    • Author(s)
      大西 将平,鈴木 登代子,南 秀人
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌)
    • Year and Date
      2015-05-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 乳化重合を用いたイオン液体ポリマー微粒子の合成とそのフィルム表面物性2015

    • Author(s)
      徳田 真芳,真田 敏春,鈴木 登代子,南 秀人
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道・札幌)
    • Year and Date
      2015-05-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] Preparation of poly(ionic liquid) particles by emulsion polymerization2014

    • Author(s)
      Masayoshi Tokuda, Toshiharu Sanada, Tatsunori Shindo, Toyoko Suzuki, Hideto Minami
    • Organizer
      Workshop on Polymer Nanoparticles, Seil-Assembly and Colloids
    • Place of Presentation
      ニューサウスウェールズ大学,豪
    • Year and Date
      2014-11-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 温度により形状を変化させるイオン液体含有自立ゲル粒子の作製2014

    • Author(s)
      南 秀人,市川 寛子,鈴木 登代子
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 分散安定剤間の水素結合を利用した一次元粒子配列制御2014

    • Author(s)
      大西 昭平,河野 恭介,松永 尚之,鈴木 登代子,南 秀人
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 汎用高分子/イオン液体ポリマー複合微粒子の合成とその構造制御2014

    • Author(s)
      神藤龍仁,徳田真芳,鈴木登代子,南 秀人
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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