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In-situ generated metal/alloy nanoparticles within monolithic hydridosilica support applied to catalytic reactions

Research Project

Project/Area Number 26288106
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionKyoto University

Principal Investigator

Nakanishi Kazuki  京都大学, 理学(系)研究科(研究院), 准教授 (00188989)

Co-Investigator(Kenkyū-buntansha) 嶋田 豊司  奈良工業高等専門学校, その他部局等, 教授 (20303802)
金森 主祥  京都大学, 理学(系)研究科(研究院), 助教 (60452265)
亀井 稔之  奈良工業高等専門学校, その他部局等, 准教授 (70534452)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2014: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Keywordsヒドリドシリカ / 多孔体 / ナノ粒子 / 還元反応 / モノリス担体 / 触媒反応 / 階層的多孔構造 / 触媒 / 粒径分布 / 流通反応 / モノリス / 合金ナノ粒子 / カップリング反応
Outline of Final Research Achievements

Hydrolysis/polycondensation of trialkoxysilanes was carefully conducted to preserve Si-H ligands followed by the sol-gel transition accompanied by phase separation, which lead to the formation of hierarchically macro/meso-porous hydridosilica monoliths. By introducing noble metals solutions with optimized solvent composition into the hydridosilica monoliths, metal/alloy nanoparticles were formed in a controlled manner. The catalytic performance was evaluated using the monolithic flow-through reactors with embedded metal/alloy nanoparticles as catalysts. Dehydrogenation catalyzed by borane catalyst was also explored to modify silica supports with well-defined pore structure with polymeric reagents bearing Si-H groups. The metal/alloy nanoparticles were produced on the surface of silica support of which catalytic performance was examined in detail.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(34 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (4 results) Journal Article (12 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (17 results) (of which Int'l Joint Research: 12 results,  Invited: 6 results) Book (1 results)

  • [Int'l Joint Research] Rutgers University(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University of Montpellier 2(France)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Rutgars University(米国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] University of Montpellier II(France)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Grafted Polymethylhydrosiloxane on Hierarchically Porous Silica Monoliths: A New Path to Monolith Supported Palladium Nanoparticles for Continuous Flow Catalysis Applications2017

    • Author(s)
      Carl-Hugo Pelisson, Takahiro Nakanishi, Yang Zhu, Kei Morisato, Toshiyuki Kamei, Ayaka Maeno, Hironori Kaji, Shunki Muroyama, Masamoto Tafu, Kazuyoshi Kanamori, Toyoshi Shimada, Kazuki Nakanishi
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: 9 Pages: 406-412

    • DOI

      10.1021/acsami.6b12653

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Amine/hydrido Bifunctional Nanoporous Silica with Small Metal Nanoparticles Made Onsite: Efficient Dehydrogentaion Catalyst2017

    • Author(s)
      Yang Zhu, Takahiro Nakanishi, Kazuyoshi Kanamori, Kazuki Nakanishi*, Shun Ichii, Kohji Iwaida, Yu Masui, Toshiyuki Kamei, Toyoshi Shimada, Akihito Kumamoto, Yumi H. Ikuhara, Mina Jeon, George Hasegawa, Masamoto Tafu, Chang W. Yoon, Tewodros Asefa
    • Journal Title

      ACS Applied Materials and Interfaces

      Volume: 9 Pages: 36-41

    • DOI

      10.1021/acsami.6b12972

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Monolithic Acidic Catalysts for the Dehydration of Xylose into Furfural2016

    • Author(s)
      Yang Zhu, Kazuyoshi Kanamori, Brun Nicolas, Pelisson Carl-Hugo, Moitra Nirmalya, Fajula Francois, Hulea Vasile, Galarneau Anne, Kazuyuki Takeda, Kazuki Nakanishi
    • Journal Title

      Catalysis Communications

      Volume: 87 Pages: 112-115

    • DOI

      10.1016/j.catcom.2016.09.014

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Metal Zirconium Phosphate Macroporous Monoliths: Versatile Synthesis, Thermal Expansion and Mechanical Properties2016

    • Author(s)
      Yang Zhu, Kazuyoshi Kanamori, Nirmalya Moitra, Kohei Kadono, Shugo Ohi, Norimasa Shimobayashi, Kazuki Nakanishi
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 225 Pages: 122-127

    • DOI

      10.1016/j.micromeso.2015.12.002

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Hierarchically Porous Titanium Phosphate Monoliths and Their Crystallization Behavior in Ethylene Glycol2016

    • Author(s)
      Yang Zhu, Koji Yoneda, Kazuyoshi Kanamori, Kazuyuki Takeda, Tsutomu Kiyomura, Hiroki Kurata, Kazuki Nakanishi
    • Journal Title

      New Journal of Chemistry

      Volume: - Pages: 4153-4159

    • DOI

      10.1039/c5nj02820e

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] HPLC separation of unsaturated organic compounds by Ag nanoparticles embedded monolithic silica column2015

    • Author(s)
      Yang ZHU, Kei MORISATO, George HASEGAWA, Nirmalya MOITRA, Tsutomu KIYOMURA, Hiroki KURATA, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Journal Title

      Journal of Separation Science

      Volume: 38 Pages: 2841-2847

    • DOI

      10.1002/jssc.201500444

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct preparation and conversion of copper hydroxide-based monolithic xerogels with hierarchical pores2015

    • Author(s)
      Shotaro FUKUMOTO, Kazuki NAKANISHI*, Kazuyoshi KANAMORI
    • Journal Title

      New Journal of Chemistry

      Volume: 39 Pages: 6771-6777

    • DOI

      10.1039/c5nj00479a

    • NAID

      120005676687

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(II) hydroxide-based monoliths.2015

    • Author(s)
      Moitra, N.; Fukumoto, S.; Reboul, J.; Sumida, K.; Zhu, Y.; Nakanishi, K.; Furukawa, S.; Kitagawa, S.; Kanamori, K.
    • Journal Title

      Chemical Communications

      Volume: 51 Pages: 3511-3514

    • DOI

      10.1039/c4cc09694k

    • NAID

      120005555506

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of robust hierarchically porous zirconium phosphate monolith for efficient ion adsorption.2015

    • Author(s)
      Zhu, Y.; Shimizu, T.; Kitashima, T.; Morisato, K.; Moitra, N.; Brun, N.; Kanamori, K.; Takeda, K.; Tafu, M.; Nakanishi, K.
    • Journal Title

      New Journal of Chemistry

      Volume: 39 Pages: 2444-2450

    • DOI

      10.1039/c4nj01749h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reduction on reactive pore surfaces as a practical approach to supported metal alloy nanoparticles.2014

    • Author(s)
      Moitra, N.; Kanamori, K.; Ikuhara, Y. H., Gao, X.; Hasegawa, G.; Takeda, K.; Zhu, Y.; Shimada, T.; Nakanishi, K.
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 2 Pages: 12535-12544

    • DOI

      10.1039/c4ta01767f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface functionalization of silica by Si-H activation of hydrosilanes.2014

    • Author(s)
      Moitra, N.; Ichii, S.; Kamei, T.; Kanamori, K.; Zhu, Y.; Takeda, K.; Nakanishi, K.; Shimada, T.
    • Journal Title

      Journal of American Chemical Society

      Volume: 136 Pages: 11570-11573

    • DOI

      10.1021/ja504115d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A new hierarchically porous Pd@HSQ monolithic catalyst for Mizoroki–Heck cross-coupling reactions2014

    • Author(s)
      N. Moitra, A. Matsushima, T. Kamei, K. Kanamori, Y. H. Ikuhara, X. Gao, K. Takeda, Y.Zhu, K. Nakanishi and T. Shimada
    • Journal Title

      New Journal of Chemistry

      Volume: 38 Pages: 1144-1149

    • DOI

      10.1039/c3nj01433a

    • NAID

      120005595823

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Preparation of hierarchically porous vanadium phosphate monolith2016

    • Author(s)
      Ayumu TANAKA*, Yang ZHU, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      6th International Congress on Ceramics
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of macroporous manganese oxide monolith from manganese salt via epoxide-mediated sol-gel route2016

    • Author(s)
      Keisuke MATSUURA*, Yang ZHU, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      6th International Congress on Ceramics
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Monolithic porous media for separations - and beyond2016

    • Author(s)
      Kazuki NAKANISHI
    • Organizer
      44th International Symposium on High Performance Liquid Phase Separations and Related Techniques
    • Place of Presentation
      San Francisco, California, USA
    • Year and Date
      2016-06-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Metal zirconium phosphate macroporous monoliths: versatile synthesis, thermal expansion and mechanical properties2016

    • Author(s)
      Yang ZHU*, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      13th International Conference on Ceramic Processing Science
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2016-05-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface-functionalized hierarchically porous oxide monoliths for separation media, catalyst supports and flow-through reactors2016

    • Author(s)
      Kazuki NAKANISHI*, Carl-Hugo PELISSON, Takahiro NAKANISHI, Yang ZHU, Nirmalya MOITRA, Kazuyoshi KANAMORI, Toyoshi SHIMADA
    • Organizer
      13th International Conference on Ceramic Processing Science
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2016-05-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Sol-gel synthesis of porous monolithic phosphate materials2015

    • Author(s)
      Yang ZHU*, Koji YONEDA, Ayumu TANAKA, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      XVIII International Sol-Gel Conference
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation and pore structure control of macroporous SnO2 gel2015

    • Author(s)
      Yoshinao SUZUKI*, Nirmalya MOITRA, Yang ZHU, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      XVIII International Sol-Gel Conference
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of hierarchically macro/mesoporous titanium phosphate monolithic gels2015

    • Author(s)
      Koji YONEDA*, Yang ZHU, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      XVIII International Sol-Gel Conference
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface modification of mesoporous silica with bifunctional hydrosilanes and formation of metal nanoparticles2015

    • Author(s)
      Takahiro NAKANISHI*, Nirmalya MOITRA, Kazuyoshi KANAMORI, Kazuki NAKANISHI, Tewodros ASEFA, Shun ICHII, Toyoshi SHIMADA
    • Organizer
      XVIII International Sol-Gel Conference
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of hierarchically porous vanadium phosphate monolith with controlled pore parameters2015

    • Author(s)
      Ayumu TANAKA*, Yang ZHU, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      XVIII International Sol-Gel Conference
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of macroporous manganese oxide monolith from manganese salt via epoxide-mediated sol-gel route2015

    • Author(s)
      Keisuke MATSUURA*, Yang ZHU, Kazuyoshi KANAMORI, Kazuki NAKANISHI
    • Organizer
      XVIII International Sol-Gel Conference
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 柔軟性を示す多孔体:無機化学からのアプローチ2015

    • Author(s)
      金森主祥
    • Organizer
      高分子加工技術研究会第83回例会
    • Place of Presentation
      京都府京都市
    • Year and Date
      2015-06-23
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Silicon-based hybrid microporous monoliths for heat-insulation, separation media and supported metal/alloy nanoparticles2015

    • Author(s)
      Kazuki NAKANISHI*, Kazuyoshi KANAMORI, Gen HAYASE, Nirmalya MOITRA
    • Organizer
      2015 MRS Spring Meeting & Exhibit
    • Place of Presentation
      San Francisco, CA, USA
    • Year and Date
      2015-04-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Reduction on Reactive Pore Surface as a Versatile Approach to Monolith-Supported Metal Alloy Nanoparticles2014

    • Author(s)
      Kazuki NAKANISHI
    • Organizer
      IUMRS-ICA 2014
    • Place of Presentation
      福岡大学(福岡県)
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Functional porous silsesquioxane monolithic materials from organotrialkoxysilane-derived sol-gel systems2014

    • Author(s)
      Kazuyoshi KANAMORI, Nirmalya MOITRA, Gen HAYASE, Taiyo SHIMIZU, Kazuki NAKANISHI
    • Organizer
      Nanoporous Materials - 7 (NANO-7, )
    • Place of Presentation
      Niagara Falls, (カナダ)
    • Year and Date
      2014-06-22 – 2014-06-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Silicon-based hybrid macroporous monolith for heat insulation, separation media and supported metal nanoparticles2014

    • Author(s)
      Kazuki Nakanishi
    • Organizer
      6th Monolith Summer School & Symposium (MSS2014)
    • Place of Presentation
      ポルトロージュ(スロベニア)
    • Year and Date
      2014-05-30 – 2014-06-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Porous silsesquioxane materials from organotrialkoxysilanes2014

    • Author(s)
      Kazuyoshi KANAMORI
    • Organizer
      2014 MRS Spring Meeting & Exhibit
    • Place of Presentation
      サンフランシスコ(米国)
    • Year and Date
      2014-04-22 – 2014-04-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Book] ナノ材料解析の実際2016

    • Author(s)
      中西和樹・金森主祥
    • Total Pages
      338
    • Publisher
      講談社
    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2022-02-16  

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