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Electrochemical production of useful organic chemicals from CO2 and seawater

Research Project

Project/Area Number 26288109
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionTokyo University of Science

Principal Investigator

Nakata Kazuya  東京理科大学, 理工学部, 准教授 (70514115)

Co-Investigator(Kenkyū-buntansha) 寺島 千晶  東京理科大学, 研究推進機構, 准教授 (00596942)
藤嶋 昭  東京理科大学, 学長室, 学長 (30078307)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2016: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Keywords二酸化炭素排出削減 / 光触媒 / CO2還元 / ボロンドープダイヤモンド / 電解還元
Outline of Final Research Achievements

In this work, we focused on electrochemical reduction using CO2 and seawater as starting chemicals and solar light as an energy to produce useful organic chemicals. We actually used conductive diamond as an electrode, seawater as an electrolyte, and solar cell or photocatalyst as photo-energy conversion materials. Furthermore, we obtained below results: (1) Amine modified diamond electrode showed higher yield production of formic acid. (2) Optimum concentration of NaCl as a electrolyte is 3% for electrochemical reduction to produce useful chemicals. (3) We constructed a system comprising diamond electrode and GaN electrode as a photocatalyst.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(37 results)

All 2017 2016 2015 2014

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (29 results) (of which Int'l Joint Research: 9 results,  Invited: 7 results) Book (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Effect of alkali-metal cations on the electrochemical reduction of carbon dioxide to formic acid using boron-doped diamond electrodes2017

    • Author(s)
      Norihito Ikemiya, Keisuke Natsui, Kazuya Nakata, Yasuaki Einaga
    • Journal Title

      RSC Adv.

      Volume: 7 Pages: 22510-22514

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ionic-Liquid-Assisted Selective and Controlled Electrochemical CO2 Reduction at Cu-Modified Boron-Doped Diamond Electrode2016

    • Author(s)
      Nitish Roy, Yuta Shibano, Chiaki Terashima, Ken-ichi Katsumata, Kazuya Nakata, Takeshi Kondo, Makoto Yuasa, Akira Fujishima
    • Journal Title

      ChemElectroChem

      Volume: 3 Pages: 1044-1047

    • DOI

      10.1002/celc.201600105

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Production of Methanol by the Electrochemical Reduction of CO2 on Boron-Doped Diamond Electrodes in Aqueous Ammonia Solution2016

    • Author(s)
      P. K. Jiwanti, K. Natsui, K. Nakata, Y. Einaga
    • Journal Title

      RSC. Adv.

      Volume: 6 Pages: 102214-102217

    • DOI

      10.1039/c6ra20466j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boron-doped diamond semiconductor electrodes: Efficient photoelectrochemical CO2 reduction through surface modification2016

    • Author(s)
      N. Roy, Y. Hirano, H. Kuriyama, P. Sudhagar, N. Suzuki, K. Katsumata, K. Nakata, T. Kondo, M. Yuasa, I. Serizawa, T. Takayama, A. Kudo, A. Fujishima, and C. Terashima
    • Journal Title

      Sci. Rep.

      Volume: 6

    • DOI

      10.1038/srep38010

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] ダイヤモンド電極を用いたCO2還元によるギ酸生成2017

    • Author(s)
      夏井敬介, 池宮範人, 冨﨑真衣, 岩川ひとみ, 中田一弥, 栄長泰明
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] 銀担持ダイヤモンド光電極を用いた二酸化炭素の還元に関する研究2017

    • Author(s)
      平野裕衣里, ロイ二ティッシュ, 栗山晴男, 中林志達, 寺島千晶, 鈴木孝宗, 中田一弥, 勝又健一, 近藤剛史, 湯浅真, 藤嶋昭
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電気化学的前処理による銀修飾ボロンドープダイヤモンド電極での二酸化炭素還元電位の低減2017

    • Author(s)
      中林志達, 平野裕衣里, 櫻井悠生, 岡崎晟大, 栗山晴男, RoyNitish, 鈴木孝宗, 中田一弥, 勝又健一, 藤嶋昭, 寺島千晶
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] Efficient One Electron Transfer CO2 Reduction at Modified BDD Photoelectrode2016

    • Author(s)
      ロイ二ティッシュ, 平野裕衣里, 栗山晴男, 寺島千晶, 中田一弥, 藤嶋昭
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪・大阪大学吹田キャンパス
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] CO2 Reduction in Aqueous Ammonium Hydroxide Solution2016

    • Author(s)
      プラステイカ・クリスマス・ジワンテイ, 夏井敬介, 中田一弥, 栄長泰明
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪・大阪大学吹田キャンパス
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 銀担持ダイヤモンド光電極を用いた二酸化炭素の光電気化学的還元2016

    • Author(s)
      平野裕衣里, N. Roy, 栗山晴男, 寺島千晶, 鈴木孝宗, 中田一弥, 勝又健一, 近藤剛史, 湯浅真, 藤嶋昭
    • Organizer
      第30回ダイヤモンドシンポジウム
    • Place of Presentation
      東京大学駒場リサーチキャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] 銀担持BDDを用いた紫外線照射による二酸化炭素の光電解還元2016

    • Author(s)
      栗山晴男, R.Nitish, 平野裕衣里, 寺島千晶, 鈴木孝宗, 中田一弥, 勝又健一, 芹澤和泉, 藤嶋昭
    • Organizer
      第23回シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      東京理科大学葛飾キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] One elecctron transfer CO2 photoelectrochemical reduction at metal modified boron doped diamond electrode2016

    • Author(s)
      Nitish Roy, Yuiri Hirano, Haruo Kuriyama, Chiaki Terashima, Kazuya Nakata, Akira Fujishima
    • Organizer
      Carbon Capture and Storage Faraday Discussion
    • Place of Presentation
      University of Sheffield
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoelectrochemical Reduction of Carbon Dioxide at Silver Modified Diamond Semiconductor2016

    • Author(s)
      C. Terashima, N. Roy, Y. Hirano, N. Suzuki, K. Nakata, K. Katsumata, T. Kondo, M. Yuasa, A. Fujishima
    • Organizer
      SIEMME'22
    • Place of Presentation
      Suzhou・Element Suzhou Science and Technology Town
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic reduction of CO2 over Cu2O modified Zn-Cr layered double hydroxides2016

    • Author(s)
      H. Jiang, K. Katsumata, C. Terashima, K. Nakata, N. Matsushita, A. Fujishima
    • Organizer
      SIEMME'22
    • Place of Presentation
      Suzhou・Element Suzhou Science and Technology Town
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CO2 Reduction on Boron-Doped Diamond Electrode in Aqueous Ammonia Solution2016

    • Author(s)
      P. K. Jiwanti, K. Natsui, K. Nakata, Y. Einaga
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu・Hawai'i Convention Center
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Boron doped diamond semiconductor electrode: Surface modification and utilization for efficient photoelectrochemical CO2 reduction2016

    • Author(s)
      Nitish Roy, Chiaki Terashima, Norihiro Suzuki, Ken-ichi Katsumata, Kazuya Nakata, Akira Fujishima
    • Organizer
      International Conference on Advances in Materials Science (ICAMS 2016)
    • Place of Presentation
      India・Raje Ramrao College
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photo-electrochemical reduction of CO2 using photocatalyst anode-boron doped diamond cathode hybrid system2015

    • Author(s)
      N. Chikamori, K. Nakata, C. Terashima, Y. Einaga, A. Kudo, H. Sakai, K. Sakai, A. Fujishima
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      ホノルル・ハワイコンベンション・センター
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reduction of carbon dioxide at boron-doped diamond2015

    • Author(s)
      Kazuya Nakata
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      ホノルル・ハワイコンベンション・センター
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アミン修飾 BDD 電極による CO2の電気化学的還元2015

    • Author(s)
      松本義規, 近森紀誉, 中田一弥, 寺島千晶, 勝又健一, 栄長泰明, 酒井健一, 酒井秀樹, 藤嶋昭
    • Organizer
      第22回シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      千葉・東京理科大学野田キャンパス
    • Year and Date
      2015-12-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光触媒アノードとボロンドープダイヤモンドカソードのハイブリッド化による CO2の光電気化学的還元2015

    • Author(s)
      近森紀誉, 中田一弥, 寺島千晶, 勝又健一, 栄長泰明, 酒井健一, 酒井秀樹, 藤嶋昭
    • Organizer
      第22回シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      千葉・東京理科大学野田キャンパス
    • Year and Date
      2015-12-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] Extending Research on Electrochemical Reduction of CO2 on Boron-Doped Diamond Electrodes2015

    • Author(s)
      D. Luo, K. Nakata, C. Terashima, Y. Einaga, A. Fujishima
    • Organizer
      First International Symposium on Recent Progress of Energy and Environmental Photocatalysis
    • Place of Presentation
      Chiba・Tokyo University of Science
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoelectrochemical Reduction of CO2 Using Photocatalyst Anode - Boron Doped Diamond Cathode Hybrid System2015

    • Author(s)
      N. Chikamori, K. Nakata, C. Terashima, T. Endo, K. Sakai, H. Sakai, Y. Einaga, A. Fujishima
    • Organizer
      First International Symposium on Recent Progress of Energy and Environmental Photocatalysis
    • Place of Presentation
      Chiba・Tokyo University of Science
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Design and Application of Functional Materials for Energy and Material Conversion2015

    • Author(s)
      中田一弥
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉・日本大学理工学部 船橋キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ボロンドープダイヤモンドによるCO2還元2015

    • Author(s)
      中田一弥
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉・日本大学理工学部 船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 光触媒アノードとボロンドープダイヤモンドカソードのハイブリッド化によるCO2の光電気化学的還元2015

    • Author(s)
      近森紀誉, 中田一弥, 寺島千晶, 栄長泰明, 工藤昭彦, 酒井健一, 酒井秀樹, 阿部正彦, 藤嶋昭
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜・横浜国立大学
    • Year and Date
      2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] ダイヤモンド電極を用いた電解還元による二酸化炭素の資源化2015

    • Author(s)
      中田一弥
    • Organizer
      ニューダイヤモンドフォーラム 平成26年度第3回研究会
    • Place of Presentation
      東京・東京大学駒場リサーチキャンパス
    • Year and Date
      2015-01-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ダイヤモンド電極を用いた二酸化炭素の電気化学的還元2015

    • Author(s)
      中田一弥
    • Organizer
      ACT-C CO2還元・資源化ワークショップ
    • Place of Presentation
      東京・富士ソフト アキバプラザ
    • Year and Date
      2015-01-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 光触媒アノードとボロンドープダイヤモンドカソードのハイブリッド化によるCO2の光電気化学的還元2014

    • Author(s)
      近森紀誉, 中田一弥, 寺島千晶, 栄長泰明, 工藤昭彦, 酒井秀樹, 阿部正彦, 藤嶋昭
    • Organizer
      第21回シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      東京・東京大学生産技術研究所コンベンションホール
    • Year and Date
      2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 多孔質ホウ素ドープダイヤモンド電極を用いた二酸化炭素電解還元2014

    • Author(s)
      今村博文, 中田一弥, 寺島千晶, 近藤剛史, 栄長泰明, 湯浅真, 藤嶋昭
    • Organizer
      第21回シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      東京・東京大学生産技術研究所コンベンションホール
    • Year and Date
      2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] ボロンドープダイヤモンド(BDD)電極を用いたCO2還元の高効率化2014

    • Author(s)
      瀧澤大, 近森紀誉, 中田一弥, 寺島千晶, 酒井秀樹, 藤嶋昭
    • Organizer
      第21回シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      東京・東京大学生産技術研究所コンベンションホール
    • Year and Date
      2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] High yield electrochemical production of formaldehyde from CO2 and seawater at boron-doped diamond electrode2014

    • Author(s)
      K. Nakata, C. Terashima, Y. Einaga, A. Fujishima
    • Organizer
      ICARP2014
    • Place of Presentation
      淡路・国際会議場
    • Year and Date
      2014-11-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 機能性材料を用いたエネルギー・物質変換2014

    • Author(s)
      中田一弥
    • Organizer
      次世代産業カレッジ
    • Place of Presentation
      東京・東京理科大学森戸記念館
    • Year and Date
      2014-10-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Reduction of CO2 at Boron-Doped-Diamond Electrode2014

    • Author(s)
      中田一弥
    • Organizer
      SIEMME'20
    • Place of Presentation
      中国・成都
    • Year and Date
      2014-09-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Book] 二酸化炭素を用いた化学品製造技術2016

    • Author(s)
      中田一弥, 寺島千晶, 勝又健一, 藤嶋昭, 栄長泰明
    • Total Pages
      305
    • Publisher
      S&T出版
    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
  • [Book] Photoelectrochemical Solar Fuel Production2016

    • Author(s)
      Pitchaimuthu Sudhagar, Nitish Roy, Raman Vedarajan, Anitha Devadoss, Chiaki Terashima, Kazuya Nakata, Akira Fujishima
    • Total Pages
      559
    • Publisher
      Springer International Publishing
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 導電性ダイヤモンド電極を用いたギ酸製造方法及び装置2017

    • Inventor(s)
      池宮範人, 夏井敬介, 栄長泰明, 中田一弥
    • Industrial Property Rights Holder
      池宮範人, 夏井敬介, 栄長泰明, 中田一弥
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-037580
    • Filing Date
      2017-02-28
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 二酸化炭素還元装置および還元方法2016

    • Inventor(s)
      寺島千晶, 平野裕衣里, ロイニティッシュ, 中田一弥, 他7名
    • Industrial Property Rights Holder
      寺島千晶, 平野裕衣里, ロイニティッシュ, 中田一弥, 他7名
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-150546
    • Filing Date
      2016-07-29
    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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