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Procise fabrication of non-silica-based hybrid mesoporous materials through a molecular design of starting chemicals

Research Project

Project/Area Number 26288110
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

KIMURA Tatsuo  国立研究開発法人産業技術総合研究所, 無機機能材料研究部門, 研究グループ長 (20308191)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Keywords多孔体 / メソポーラス / 無機固体化学 / ナノ機能材料
Outline of Final Research Achievements

To develop a new method to fabricate various mesoporous metal phosphonates, I have proposed the methodology to control the reactivity between metal sources and bisphosphonates precisely. The reactivity to metal sources is adjusted by a partial acidification of bisphosphonates. As a result, combining with the organic synthesis of bisphosphonates, the successful preparation of mesoporous aluminum organophosphonate films having surface structures such as benzene, aniline, and benzene sulfonic acid bridges can be reported, reaching the potential level to investigate unique adsorption and catalytic properties that are induced by the presence of hydrophilic spaces.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Products Report
  • Research Products

    (31 results)

All 2020 2017 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (12 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 6 results,  Open Access: 3 results) Presentation (15 results) (of which Int'l Joint Research: 5 results,  Invited: 7 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] 国立台湾大学(台湾)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Water sorption property controlled by nanoscale pore connectivity of large-sized cage-type mesopores2016

    • Author(s)
      Tatsuo Kimura, Yusuke Yamauchi
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 16 Issue: 9 Pages: 9307-9310

    • DOI

      10.1166/jnn.2016.12913

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Evaporation-induced self-assembly process controlled for obtaining highly ordered mesoporous materials with demanded morphologies2016

    • Author(s)
      Tatsuo Kimura
    • Journal Title

      Chemical Record

      Volume: 16 Issue: 1 Pages: 445-457

    • DOI

      10.1002/tcr.201500262

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Toward compositional design of reticular type porous films by mixing and coating titania-based frameworks with silica2015

    • Author(s)
      Tatsuo Kimura
    • Journal Title

      APL Materials

      Volume: 3 Issue: 12 Pages: 126101-6

    • DOI

      10.1063/1.4936665

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Predictable shrinkage during the precise design of porous materials and nanomaterials2015

    • Author(s)
      Saikat Dutta, Kevin C.-W. Wu, Tatsuo Kimura
    • Journal Title

      Chemistry of Materials

      Volume: 27 Issue: 20 Pages: 6918-6928

    • DOI

      10.1021/acs.chemmater.5b02435

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Electrochemical Synthesis of Mesoporous Gold Films toward Mesospace-Stimulated Optical Properties2015

    • Author(s)
      Cuiling Li, Omer Dag, Thang Duy Dao, Tadaaki Nagao, Yasuhiro Sakamoto, Tatsuo Kimura, Osamu Terasaki, and Yusuke Yamauchi*
    • Journal Title

      Nature Communications

      Volume: 6 Issue: 1 Pages: 6608-6608

    • DOI

      10.1038/ncomms7608

    • NAID

      120006541907

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Asymmetric block copolymers for supramolecular templating of inorganic nanospace materials2015

    • Author(s)
      Bishnu Prasad Bastakoti, Yunqi Li, Tatsuo Kimura, Yusuke Yamauchi
    • Journal Title

      Small

      Volume: 11 Issue: 17 Pages: 1992-2002

    • DOI

      10.1002/smll.201402573

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Trace-level gravimetric detection promoted by surface interactions of mesoporous materials with chemical vapors2014

    • Author(s)
      Tatsuo Kimura, Nagy L. Torad, Yusuke Yamauchi
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 2 Issue: 22 Pages: 8196-8200

    • DOI

      10.1039/c4ta00775a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Towards vaporized molecular discrimination: A quartz crystal microbalance (QCM) sensor system using cobalt-containing mesoporous graphitic carbon2014

    • Author(s)
      Jing Tang, Nagy L. Torad, Rahul R. Salunkhe, Jang-Hee Yoon, Md Shahriar Al Hossain, Shi Xue Dou, Jung Ho Kim, Tatsuo Kimura, Yusuke Yamauchi
    • Journal Title

      Chemistry - An Asian Journal

      Volume: 9 Pages: 3238-3244

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tailored design of functional nanoporous carbon materials toward fuel cell applications2014

    • Author(s)
      Jing Tang, Jian Liu, Nagy L. Torad, Tatsuo Kimura, Yusuke Yamauchi
    • Journal Title

      Nano Today

      Volume: 9 Issue: 3 Pages: 305-323

    • DOI

      10.1016/j.nantod.2014.05.003

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Macrostructure-dependent photocatalytic property of high-surface-area porous titania films2014

    • Author(s)
      Tatsuo Kimura
    • Journal Title

      APL Materials

      Volume: 2 Issue: 11 Pages: 113301-9

    • DOI

      10.1063/1.4897202

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Artificial reticular structure by continuous titanium oxide frameworks2014

    • Author(s)
      Tatsuo Kimura
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 2 Issue: 27 Pages: 10688-10696

    • DOI

      10.1039/c4ta01448k

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In Situ Observation of the Evaporation-Induced Self-Assembling Process of Ps-B-Peo Diblock Copolymers for the Fabrication of Titania Films by Confocal Laser Scanning Microscopy2014

    • Author(s)
      Kimura, T., Shintate, M., Miyamoto, N.
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 7 Pages: 1230-1233

    • DOI

      10.1039/c4cc08497g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Porous materials design based on framework shrinkage as the great potential to obtain unique and high-surface-area films2016

    • Author(s)
      Tatsuo Kimura
    • Organizer
      The 2nd Japan-Taiwan Joint Workshop on Nanospace Materials
    • Place of Presentation
      茨城県, 物質・材料研究機構
    • Year and Date
      2016-12-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 平成28年度経済産業政策とファインセラミックス関連産業の今後について2016

    • Author(s)
      木村辰雄
    • Organizer
      日本ゾルゲル学会第13回セミナー
    • Place of Presentation
      東京都, 産総研臨海センター
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Towards in situ observation of the formation process of mesoporous films with surfactant molecules by using confocal laser scanning microscope2015

    • Author(s)
      Tatsuo Kimura, Morio Shintate, Nobuyoshi Miyamoto
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 「ナノテクノロジー・材料分野の展開」~経済産業省の関連施策など~2015

    • Author(s)
      木村辰雄
    • Organizer
      2015年ナノテク革新技術フォーラム
    • Place of Presentation
      京都府, 京都大学
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Compositional design for exploring the possibility of unique reticular type porous structures2015

    • Author(s)
      Tatsuo Kimura
    • Organizer
      9th International Mesostructured Materials Symposium (IMMS 2015)
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      2015-08-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Selective gravimetric detection promoted by interactions at mesopore surfaces with chemical vapors2015

    • Author(s)
      Tatsuo Kimura, Jing Tang, Nagy L. Torad, Yusuke Yamauchi
    • Organizer
      International Symposium on Zeolites and Microporous Crystals 2015 (ZMPC 2015)
    • Place of Presentation
      北海道, 札幌コンベンションセンター
    • Year and Date
      2015-06-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Facile compositional design of unique reticular type porous titania films showing superior functions2015

    • Author(s)
      Tatsuo Kimura
    • Organizer
      International Conference on Nanospace Materials 2015 (ICNM 2015)
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-06-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 多孔性酸化チタンの前駆体薄膜生成過程の共焦点レーザー顕微鏡による直接観察2015

    • Author(s)
      木村辰雄, 新立盛生, 宮元展義
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nanostructural design by combining soft colloidal copolymer templating with shrinkage of oxide frameworks2015

    • Author(s)
      Tatsuo Kimura
    • Organizer
      4th International Conference on Multifunctional, Hybrid and Nanomaterials (Hybrid Materials 2015)
    • Place of Presentation
      Sitges, Spain
    • Year and Date
      2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 超分子鋳型法と酸化物骨格の収縮を組み合わせたナノ構造デザイン2014

    • Author(s)
      木村辰雄
    • Organizer
      第30回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] カネマイトからのKSW-2型Ti含有メソポーラスシリカの合成2014

    • Author(s)
      齋藤友貴, 長田師門, 新井貴子, 木村辰雄, 黒田一幸
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      東京
    • Year and Date
      2014-10-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 層状ケイ酸塩を出発物質としたTi含有メソポーラスシリカの合成2014

    • Author(s)
      齋藤友貴, 長田師門, 新井貴子, 木村辰雄, 黒田一幸
    • Organizer
      第58回粘土科学討論会
    • Place of Presentation
      福島
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸化物骨格の縮合反応が導くナノ構造制御2014

    • Author(s)
      木村辰雄
    • Organizer
      西日本ナノシート研究会サマーキャンプ2014
    • Place of Presentation
      長崎
    • Year and Date
      2014-07-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] TEM observation of uniform mesopores in phenol resin carbonized films2014

    • Author(s)
      Tatsuo Kimura
    • Organizer
      International Symposium on "Nanoporous Materials - 7 (Nano-7)
    • Place of Presentation
      Niagara Falls, Canada
    • Year and Date
      2014-06-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Supramolecular templated synthesis of inorganic materials2014

    • Author(s)
      Tatsuo Kimura
    • Organizer
      A Special Seminar for the Class “Nanoporous Materials”
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2014-05-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Book] ナノ空間材料ハンドブック(担当:第1章1節 メソ多孔体類:総論 pp. 9-23)2016

    • Author(s)
      木村辰雄
    • Total Pages
      548
    • Publisher
      株式会社エヌティーエス
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] (新名称) 金属ホスホン酸塩のナノ構造体薄膜の製造方法とナノ多孔体薄膜の製造方法(旧名称) 金属ホスホン酸塩のナノ構造体薄膜とナノ多孔体薄膜及びその製造方法2020

    • Inventor(s)
      木村 辰雄
    • Industrial Property Rights Holder
      産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-026140
    • Acquisition Date
      2020
    • Related Report
      Products Report
  • [Patent(Industrial Property Rights)] 金属ホスホン酸塩のナノ構造体薄膜とナノ多孔体薄膜及びその製造方法2017

    • Inventor(s)
      木村辰雄
    • Industrial Property Rights Holder
      木村辰雄
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-026140
    • Filing Date
      2017-02-15
    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2022-04-15  

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