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Multi-dye sensitized high efficiency dye sensitized solar cell

Research Project

Project/Area Number 26288113
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Device related chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

Islam Ashraful  国立研究開発法人物質・材料研究機構, エネルギー・環境材料研究拠点, 主席研究員 (70531177)

Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
Fiscal Year 2016: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2014: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Keywords色素増感 / ペロブスカイト / Sensitized Solar Cell / Multi Dye / Muti Dye
Outline of Final Research Achievements

In this project, I have design and synthesized few potential new dyes covering a short and a long wavelength light based on metal complexes and metal-free organic dyes. Using these new sensitizers, I have successfully fabricated Multi-dye (UV-dye, VIS-dye and NIR-dye) sensitized dye sensitized solar cells with these novel new dyes. Optical and electrical investigation shows that small UV-dyes can suppressed strongly the TiO2 injected electron recombination with the electrolyte(I3-). These triple dye co-sensitized solar cells showed a panchromatic response with an IPCE >70% over the entire visible spectrum extending to the NIR region, suggesting their usage in indoor applications. The research results are presented at 8 international scientific meetings and also published in 17 peer reviewed scientific journals.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report

Research Products

(21 results)

All 2017 2016 2015 2014

All Journal Article (13 results) (of which Int'l Joint Research: 12 results,  Peer Reviewed: 12 results,  Open Access: 3 results,  Acknowledgement Compliant: 6 results) Presentation (8 results) (of which Int'l Joint Research: 6 results,  Invited: 6 results)

  • [Journal Article] Panchromatic absorption of dye sensitized solar cells by co-Sensitization of triple organic dyes2017

    • Author(s)
      Ashraful Islam, CHOWDHURY Towhid Hossain, QIN Chuanjiang, Liyuan HAN, Jae-Joon Lee, Idriss M. Bedja, Md Akhtaruzzaman, Kamaruzzaman Sopian, Antoine Mirloup, Nicolas Leclerc
    • Journal Title

      SUSTAINABLE ENERGY & FUELS

      Volume: 2 Pages: 209-214

    • DOI

      10.1039/c6se00014b

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Heteroleptic Ru(II) cyclometalated complexes derived from benzimidazole-phenyl carbene ligands for dye-sensitized solar cells: an experimental and theoretical approach2017

    • Author(s)
      Tejaswi Jella, Malladi Srikanth, Yarasi Soujanya, Surya Prakash Singh, Lingamallu Giribabu, ISLAMAshraful, Liyuan HAN, Idriss Bedja, Ravindra Kumar Gupta
    • Journal Title

      MATERIALS CHEMISTRY FRONTIERS

      Volume: 1 Pages: 947-957

    • DOI

      10.1039/c6qm00264a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Near-infrared squaraine co-sensitizer for efficiency dye-sensitized solar cells2017

    • Author(s)
      G. Hanumantha Rao, A. Venkateswararao, L. Giribabu, Liyuan Han, Idriss Bedja, Ravindra Kumar Gupta, Ashraful Islam
    • Journal Title

      PHYSICAL CHEMISTRY CHEMICAL PHYSICS

      Volume: 00 Pages: 14279-14285

    • DOI

      10.1039/c6cp01669c

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Cyclometalated ruthenium complexes with 6-(ortho-methoxyphenyl)-2,2′-bipyridine as panchromatic dyes for dye-sensitized solar cells2017

    • Author(s)
      Ryuji Kaneko, Guohua Wua, Kosuke Sugawa, Joe Otsuki, ISLAMAshraful, Liyuan HAN, Idriss Bedja, Ravindra Kumar Gupta
    • Journal Title

      JOURNAL OF ORGANOMETALLIC CHEMISTRY

      Volume: 833 Pages: 61-70

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bulky Nature Phenanthroimidazole-Based Porphyrin Sensitizers for Dye-Sensitized Solar Cell Applications2017

    • Author(s)
      Narra Vamsi Krishna, Jonnadula Venkata Suman Krishna, Surya Prakash Singh, Lingamallu Giribabu, ISLAMAshraful, Idriss Bedja
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY C

      Volume: 121 Pages: 25691-25704

    • DOI

      10.1021/acs.jpcc.7b07692

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thiocyanate-free asymmetric ruthenium(II) dye sensitizers containing azole chromophores with near-IR light-harvesting capacity2016

    • Author(s)
      Guohua Wu, 金子 竜二, ISLAMAshraful, Yaohong Zhang, Kosuke Sugawa, 韓礼元, Qing Shen, Idriss Bedja, Ravindra Kumar Gupta, 大月 穣
    • Journal Title

      Journal of Power Sources

      Volume: 331 Pages: 100-111

    • DOI

      10.1016/j.jpowsour.2016.09.040

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Enhanced Photovoltaic Performances of Dye-Sensitized Solar Cells by Co-Sensitization of enzothiadiazole and Squaraine-Based Dyes2016

    • Author(s)
      Ashraful Islam, Md. Akhtaruzzaman, Towhid H. Chowdhury, Chuanjiang Qin, Liyuan Han, Idriss M. Bedja, Romain Stalder, Kirk S. Schanze, John R. Reynolds
    • Journal Title

      ACS APPLIED MATERIALS & INTERFACES

      Volume: 8 Pages: 4616-4623

    • DOI

      10.1021/acsami.5b11134

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Neutral and anionic tetrazole-based ligands in designing novel ruthenium dyes for dye-sensitized solar cells2016

    • Author(s)
      Guohua Wu, Ryuji Kaneko, Yaohong Zhang, Yoshinao Shinozaki, Kosuke Sugawa,Ashraful Islam, Liyuna Han, Idriss Bedja, Ravindra Kumar Gupta, Qing Shen, Joe Otsuki
    • Journal Title

      Journal of Power Sources

      Volume: 307 Pages: 416-425

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] New heteroleptic benzimidazole functionalized Ru-sensitizer showing the highest efficiency for dye-sensitized solar cells2015

    • Author(s)
      T. Swetha, S. Niveditha, K. Bhanuprakash, Ashraful Islam, Liyuan Han, Idriss M. Bedja, Reza Fallahpour, Surya Prakash Singh
    • Journal Title

      Inorganic Chemistry Communications

      Volume: 51 Pages: 61-65

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Efficient thieno[32-a]carbazole-based organic dyes for dye-sensitized solar cells2015

    • Author(s)
      Hua Jiang, Kazuaki Oniwa, Jian Zhao, Ashraful Islam, Liyuan HANYing-J Ming Baoi Su Naoki AsaonYoshinori Yamamoto,Tienan Jin
    • Journal Title

      Tetrahedron

      Volume: 71 Pages: 6534-6540

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Tieno[2,3,a]carbazole donor-based organic dyes for high efficiency dye-sensitized solar cells2015

    • Author(s)
      Jian Zhao,Kazuaki Oniwa, ISLAMAshrafu, QIN Chuanjiang, Naoki AsaLiyuan HANo Yoshinori YamamoTienan Jinto,
    • Journal Title

      ORGANIC CHEMISTRY FRONTIERS

      Volume: 2 Pages: 253-258

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Tuning of spectral response by co-sensitization in black-dte based dye-sensitized solar cell2015

    • Author(s)
      Ashraful Islam, T. Swetha, Mohammad Rezaul Karim, Md. Akhtaruzzaman, Liyuan Han, Surya Prakash Singh
    • Journal Title

      Physical Status Solidi A

      Volume: 3 Pages: 651-656

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] More stable and more efficient alternatives of Z-907: carbazole-based amphiphilic Ru(II) sensitizers for dye-sensitized solar cells2014

    • Author(s)
      Cheema, Hammad, ISLAMAshraful, Younts Robert, Gautam Bhoj, Idriss Bedja,Ravindra Kumar Gupta, Liyuan HAN, Kenan Gundogdu, Kenan Gundogdu, Ahmed El-Shafei
    • Journal Title

      PHYSICAL CHEMISTRY CHEMICAL PHYSICS

      Volume: 16 Pages: 27078-27087

    • DOI

      10.1039/c4cp04120h

    • Related Report
      2014 Annual Research Report
  • [Presentation] Perovskite Solar Cell for Next Generation Photovoltaics2017

    • Author(s)
      SLAMAshrafu, Wu Yongzhen, 韓礼元
    • Organizer
      GPVC2017
    • Place of Presentation
      Kimdaejung Convention Center
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High Efficiency Dye-sensitized And Perovskite Based Solar Cells2017

    • Author(s)
      ISLAMAshrafu
    • Organizer
      International Conference on Chemical Science 6 technology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Perovskite Solar Cell for Next Generation Photovoltaics2017

    • Author(s)
      ISLAMAshrafu
    • Organizer
      2018Joint Symposium on Energy Materials Science and Technology
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] HIGH EFFICIENCY DYE-SENSITIZED AND PEROVSKITE BASED SOLAR CELLS2017

    • Author(s)
      ISLAMAshraful
    • Organizer
      Global Photovoltaic Conference 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dye-Sensitized and Perovskite Solar Cell for Next Generation Photovoltaics2016

    • Author(s)
      ISLAMAshrafu, WUYongzhen, 韓礼元
    • Organizer
      ICMME-2016
    • Place of Presentation
      Pilot Plant & Process Development Centre
    • Year and Date
      2016-12-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] HIGH EFFICIENCY DYE-SENSITIZED AND PEROVSKITE BASED SOLAR CELLS2016

    • Author(s)
      SLAMAshrafu
    • Organizer
      16th Asian Chemical Congress
    • Place of Presentation
      University of Bangladesh,Dhaka,Bangladesh
    • Year and Date
      2016-03-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dye-Sensitized solar cells: Sensitized with triple dyes in ultraviolet to near infrared2016

    • Author(s)
      ISLAMAshrafu
    • Organizer
      ICDRET 2016
    • Place of Presentation
      United International University,Dhaka,Bamgladesh
    • Year and Date
      2016-01-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystallization and morphology controlling of organic-inorganic perovskite for highly reproducible photovoltaic devices2014

    • Author(s)
      ISLAMAshraful
    • Organizer
      2014 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Hynes Convention Center
    • Year and Date
      2014-11-30
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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