• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Establishment of core technology of embedding heterogeneity materials into high-aspect ratio diffractive grating by using supercritical CO2 fluids

Research Project

Project/Area Number 26289294
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionTohoku University

Principal Investigator

Hojo Daisuke  東北大学, 原子分子材料科学高等研究機構, 助教 (30511919)

Co-Investigator(Kenkyū-buntansha) 矢代 航  東北大学, 多元物質科学研究所, 准教授 (10401233)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2014: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Keywordsナノ粒子超格子 / 中性子位相イメージング / 気・液・固・超臨界流体反応操作
Outline of Final Research Achievements

We proposed chemical fluid deposition (CFD) technique by using supercritical CO2 fluids and are establishing technique to enable to fill Gd materials into high-aspect ratio trench structures for neutron phase imaging. In this research, we try to develop the technique that impregnation of Gd2O3 nanocrystals into the trench to form nanocrystalline supralattice structures by synthesizing supercritical CO2 dispersed Gd2O3 nanocrystals. We deployed 3 step synthesis to obtain those supercritical CO2 dispersed Gd2O3 nanocrystals. First, Gd(III)oleate was synthesized in aqua and then, oleic-acid modified Gd2O3 nanocrystals was synthesized from Gd(III)oleate in Tri-n-octylamine by solvothermal method. Finally, hexafluoroacetylacetone(hfac) modified Gd2O3 nanocrsytals that can be dispersed in supercritical CO2 were obtained by using ligand exchange. Currently, we are developing CFD method that enables to deposit the nanocrystals by decreasing dispersibility with local cooling on substrates.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (17 results)

All 2017 2016 2015 2014

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 4 results) Presentation (13 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results)

  • [Journal Article] One-step nanoporous structure formation using NiO nanoparticles: pore size control and pore size dependence of hydrogen evolution reaction2017

    • Author(s)
      Yoshikazu Ito, Masahiko Izumi, Daisuke Hojo, Mitsuru Wakisaka, Tsutomu Aida, Tadafumi Adschiri
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 2 Pages: 267-270

    • DOI

      10.1246/cl.161017

    • NAID

      130005317050

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Correlation between Chemical Dopants and Topological Defects in Catalytically Active Nanoporous Graphene2016

    • Author(s)
      Yoshikazu Ito, Yuhao Shen, Daisuke Hojo, Yoji Itagaki, Takeshi Fujita, Linghan Chen, Tsutomu Aida, Zheng Tang, Tadafumi Adschiri, Mingwei Chen
    • Journal Title

      Advanced Materials

      Volume: 28 Issue: 48 Pages: 10644-10651

    • DOI

      10.1002/adma.201604318

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electric Properties of Dirac Fermions Captured into 3D Nanoporous Graphene Networks2016

    • Author(s)
      Y. Tanabe, Y. Ito, K. Sugawara, D. Hojo, M. Koshino, T. Fujita, T. Aida, X. Xu, K. K. Huynh, H. Shimotani, T. Adschiri, T. Takahashi, K. Tanigaki, H. Aoki, and M. Chen
    • Journal Title

      Adv. Mater.

      Volume: 28 Issue: 46 Pages: 10304-10304

    • DOI

      10.1002/adma.201601067

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Magneto-optical Kerr effect characterization of a uniform nanocrystalline Fe3O4 monolayer fabricated on a silicon substrate functionalized with catechol groups2016

    • Author(s)
      Daisuke Hojo, Kazuya Z. Suzuki, Shigemi Mizukami, Tadafumi Adschiri
    • Journal Title

      J. Mater. Chem. C

      Volume: 4 Issue: 6 Pages: 1263-1270

    • DOI

      10.1039/c5tc04310g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] レイヤーバイレイヤーセルフアセンブリー法を用いたFe3O4ナノ粒子多層膜の作製とその磁気抵抗評価2017

    • Author(s)
      北條大介、鈴木和也、浅尾直樹、水上茂美、阿尻雅文
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜、横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Surfactant-free Supercritical Hydrothermal Synthesis of high-crystalline Pyrochlore-type La2Zr2O7 Nanoparticles2016

    • Author(s)
      D. Hojo, H. Ohara, T. Aida, T. Noguchi, N. Aoki, G. Seong, S. Takami, and T. Adschiri
    • Organizer
      8th Green Solvents Conference
    • Place of Presentation
      Kiel, German
    • Year and Date
      2016-10-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fe3O4ナノ粒子単層膜および多層膜の磁気光学カー特性評価II2016

    • Author(s)
      北條大介、鈴木和也、浅尾直樹、水上茂美、阿尻雅文
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ、新潟
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fe3O4ナノ粒子単層膜および多層膜の磁気光学カー特性評価2016

    • Author(s)
      北條大介、鈴木和也、浅尾直樹、水上茂美、阿尻雅文
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学 (目黒区・東京都)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高濃度・高分散ナノフルイドのナノテクノロジーへの応用2016

    • Author(s)
      北條大介、阿尻雅文
    • Organizer
      化学工学会 第81年会
    • Place of Presentation
      関西大学 (吹田市・大阪府)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Characterization of nanoscale interfaces of epitaxially grown anatase-type TiO2 on CeO2 nanocubes self-assembled on the substrate2015

    • Author(s)
      D. Hojo
    • Organizer
      Energy Materials Nanotechnology Spain Meeting
    • Place of Presentation
      Donostia-San Sebastian (Spain)
    • Year and Date
      2015-09-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Surfactant-free Supercritical Hydrothermal Synthesis of high-crystalline Pyrochlore-type La2Zr2O7 Nanoparticles for Coating process2015

    • Author(s)
      D. Hojo, H. Ohara, T. Aida, T. Noguchi, N. Aoki, G. Seong, S. Takami, and T. Adschiri
    • Organizer
      7th International Conference on Green and Sustainable Chemistry
    • Place of Presentation
      一橋大学 (千代田区・東京都)
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of nanoscale heterogeneous interfaces between anatase-type TiO2 and CeO2 nanocubes self-assembled on the substrate2015

    • Author(s)
      D. Hojo
    • Organizer
      5th International Colloids Conference
    • Place of Presentation
      Amsterdam (Nederland)
    • Year and Date
      2015-06-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CeO2ナノ粒子上へ選択的結晶成長させたアナターゼ型TiO2の結晶構造2015

    • Author(s)
      北條大介、阿尻雅文
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      平塚
    • Year and Date
      2015-03-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Self-Assembly and Reassembly of Organic-Inorganic Hybrid Nanocrystals synthesized in supercritical hydrothermal condition2014

    • Author(s)
      D. Hojo
    • Organizer
      4th International Solvothermal and Hydrothermal Association Conference
    • Place of Presentation
      フランス
    • Year and Date
      2014-10-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Self-Assembly and Immobilization of Organic-Inorganic Hybrid CeO2 Nanocrystals synthesized in supercritical hydrothermal condition2014

    • Author(s)
      D. Hojo and T. Adschiri
    • Organizer
      7th Green Solvents Conference
    • Place of Presentation
      ドイツ
    • Year and Date
      2014-10-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 単層吸着制御したFe3O4ナノ粒子の磁気光学特性2014

    • Author(s)
      北條大介、水上成美、阿尻雅文
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Self-Assembly of Organic-Inorganic Hybrid Nanocrystals in Highly Ordered Nanocrystalline Monolayer2014

    • Author(s)
      D. Hojo, T. Togashi, and T. Adschiri
    • Organizer
      E-MRS 2014 Spring Meeting
    • Place of Presentation
      フランス
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi