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Development of target-molecule-capture type adsorbents composite and its application to gas separation-concentration system

Research Project

Project/Area Number 26340077
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental conscious materials and recycle
Research InstitutionToyohashi University of Technology

Principal Investigator

MATSUMOTO Akihiko  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (90239088)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords吸着 / 消化ガス / ゼオライト / 活性炭 / 真空圧力スイング吸着 / 二酸化炭素 / 硫化水素 / シロキサン / 精製 / 酸化亜鉛 / 四酸化三鉄
Outline of Final Research Achievements

Removal of impurities in biogas, such as carbon dioxide CO2, hydrogen sulfide H2S and siloxane, is absolutely imperative for effective utilization of methane generated by anaerobic fermentation of sewage sludge. This research aimed at development of target-molecule-capture type adsorbents composite and its application to gas separation-concentration system. As a result, a sodium type of a low silica zeolite is the most suitable as an adsorbent of CO2. An active carbon with highly-dispersed transition metal oxide is effective as an adsorbent of H2S. An activated carbon adsorbent with controlled surface polarity and pore sizes has promise as a siloxane adsorbent. A target-molecule-capture type adsorbents composite is developed by combination of these adsorbents.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (20 results)

All 2017 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 5 results) Presentation (15 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results)

  • [Journal Article] EFFICIENT ADSORPTION CONCENTRATION AND PHOTOLYSIS OF ACETALDEHYDE ON TITANIA-MESOPOROUS SILICA COMPOSITE2017

    • Author(s)
      Satoshi Yamaguchi and Akihiko Matsumoto
    • Journal Title

      AIP Proceeding Series

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ROLE OF CATION IN TARGET ADSORPTION OF CARBON DIOXIDE FROM CARBON DIOXIDE-METHANE MIXTURE BY LOW SILICA X2017

    • Author(s)
      Keiichi Hasegawa and Akihiko Matsumoto
    • Journal Title

      AIP Proceeding Series

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] RAPID ADSORPTION REMOVAL OF HYDROGEN SULFIDE BY SURFACE-MODIFIED ACTIVATED CARBON2017

    • Author(s)
      Akane Inoue and Akihiko Matsumoto
    • Journal Title

      AIP Proceeding Series

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Characterization of Carbonized Films Prepared from Polybenzoxazines2015

    • Author(s)
      69. Yoshiki Takahashi, Tsubasa Osawa, Yuji Shibayama, Akihiko Matsumoto and Tsutomu Takeichi
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 28 Pages: 131-135

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Imide-modified Benzoxazine and Characterization of Cured Film2015

    • Author(s)
      68. Tatsuya Nagata, Kosaku Kurowarabi, Takehiro Kawauchi, Akihiko Matsumoto and Tsutomu Takeichi
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 28 Pages: 145-150

    • NAID

      130005093837

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 消化ガス精製のための標的分子捕捉型活性炭の開発と H2S・シロキサンの吸着除去2016

    • Author(s)
      井上あかね,伊藤博光,松本明彦
    • Organizer
      第 30 回日本吸着学会研究発表会
    • Place of Presentation
      長崎大学
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] ゼオライトを用いた CO2 の吸着分離と吸着熱の回収2016

    • Author(s)
      長谷川惠一,長谷川雄士,伊藤博光,松本明彦
    • Organizer
      第 30 回日本吸着学会研究発表会
    • Place of Presentation
      長崎大学
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] (KN3) Adsorption of Fuel Gases on MOFs Characterised by High-Pressure Adsorption Microcalorimetry2016

    • Author(s)
      Akihiko MATSUMOTO
    • Organizer
      2nd International Conference on Advances in Renewable Energy Technologies
    • Place of Presentation
      Putrajaya, Malaysia
    • Year and Date
      2016-02-23
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] (PMP19) Characterization of carbon films prepared from polybenzoxazine films by temperature- controlled carbonization2016

    • Author(s)
      Tsubasa OSAWA, Tsutomu TAKEICHI, Akihiko MATSUMOTO
    • Organizer
      The 3rd International Conference of Global Network for Innovative Technology
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      2016-01-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] (PMN05) Efficient adsorption consentration and photolysis of acetaldehyde on titania-mesoporous silica composite2016

    • Author(s)
      Satoshi Yamaguchi, Akihiko MATSUMOTO
    • Organizer
      The 3rd International Conference of Global Network for Innovative Technology
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      2016-01-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] (PMN06) Rapid adsorption removal of hydrogen sulfide by surface-modified activated carbon2016

    • Author(s)
      Akane INOUE, Akihiko MATSUMOTO
    • Organizer
      The 3rd International Conference of Global Network for Innovative Technology
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      2016-01-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] (PMN03) Role of cation in target adsorption of carbon dioxide from CO2-CH4 mixture by low silica x zeolites2016

    • Author(s)
      Keiichi HASEGAWA, Akihiko MATSUMOTO
    • Organizer
      The 3rd International Conference of Global Network for Innovative Technology
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      2016-01-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] (2-17) ゼオライトを用いた CO 2 吸着分離における陽イオンの影響2015

    • Author(s)
      長谷川惠一,松本明彦
    • Organizer
      Toyohashi University of Technology and Universiti Sains Malaysia
    • Place of Presentation
      徳島大学,徳島
    • Year and Date
      2015-11-19
    • Related Report
      2015 Research-status Report
  • [Presentation] (OD20) Preparation and adsorption characteristics of CID type MOF with different pillar ligands2015

    • Author(s)
      Akihiko MATSUMOTO, Hiroyuki OZEKI, Keisuke MATSUFUJI
    • Organizer
      International Symposium on Zeolite and Microporous Crystals
    • Place of Presentation
      Sapporo convention center, Sapporo,Japan
    • Year and Date
      2015-06-28
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] LSXゼオライト中の陽イオンサイト数とCO2吸着性の相関2015

    • Author(s)
      安藤彰吾,篠木 剛,松本明彦
    • Organizer
      日本材料科学会平成27年度学術講演大会
    • Place of Presentation
      工学院大学,東京
    • Year and Date
      2015-06-05
    • Related Report
      2015 Research-status Report
  • [Presentation] 表面修飾活性炭への吸着を利用した硫化水素の除去2015

    • Author(s)
      井上あかね,松本明彦
    • Organizer
      日本材料科学会平成27年度学術講演大会
    • Place of Presentation
      工学院大学,東京
    • Year and Date
      2015-06-05
    • Related Report
      2015 Research-status Report
  • [Presentation] ミクロカロリメトリーを用いたLSXゼオライトへの二酸化炭素吸着特性化2015

    • Author(s)
      長谷川惠一,松本明彦
    • Organizer
      日本材料科学会平成27年度学術講演大会
    • Place of Presentation
      工学院大学,東京
    • Year and Date
      2015-06-05
    • Related Report
      2015 Research-status Report
  • [Presentation] 周波数応答法によるゼオライト細孔内への気体の拡散・吸着の解析2014

    • Author(s)
      竹口翔太・松本明彦
    • Organizer
      第 45回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      愛知県春日井市 中部大学
    • Year and Date
      2014-11-29 – 2014-11-30
    • Related Report
      2014 Research-status Report
  • [Presentation] 配位子の構造を制御した多孔性カルボキシピラゾール銅錯体の分子吸着性2014

    • Author(s)
      松山雄司・松本明彦
    • Organizer
      第 45回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      愛知県春日井市 中部大学
    • Year and Date
      2014-11-29 – 2014-11-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Adsorption Removal of CO2 in Biogas by LSX Zeolites2014

    • Author(s)
      Yuji HASEGAWA and Akihiko MATSUMOTO
    • Organizer
      The 10th International Conference on Separation Science and Technology
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2014-10-30 – 2014-11-01
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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