Construction of Silicon-containing Dehydroannulenes and Their Aromaticity and Antiaromaticity
Project/Area Number |
26410044
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Organic chemistry
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Research Institution | Kyoto University |
Principal Investigator |
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Research Collaborator |
EGAWA Yasunobu 京都大学, 化学研究所, 助教
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Project Period (FY) |
2014-04-01 – 2017-03-31
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Project Status |
Completed (Fiscal Year 2016)
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Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
Keywords | ケイ素 / 芳香族性 / 反芳香族性 / デヒドロアヌレン |
Outline of Final Research Achievements |
In order to establish the effective method of constructing the cyclic cis-dialkynyldisilene moiety, the reductive coupling of ethynyldichlorosilane units and disilane elimination from (2-ethynyl)trisilane units, whose silane units were linked by alkylene or silylene tethers, were performed. The former reaction afforded the 10-membered cyclic disilane, which has hydrogen atoms, convertible substitutent, on each silicon atom. The latter one unexpectedly resulted in the elimination of ethynylsilane.
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Report
(4 results)
Research Products
(41 results)
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[Journal Article] [K(18-crown-6)][FeCp*(CO)2]2016
Author(s)
Yoshiyuki Mizuhata, Tatsuya Yanagisawa, Takahiro Sasamori, Norihiro Tokitoh
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Journal Title
IUCrData
Volume: 1
Pages: x160881
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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