Development of molecular multiferroic materials based on supramolecular cation rotators and porous ferromagnetic metal complexes with chiral space group

• Project/Area Number: 26410083
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Functional solid state chemistry
• Research Institution: Hokkaido University
• Principal Investigator: KUBO Kazuya 北海道大学, 電子科学研究所, 助教 (90391937)
• Co-Investigator(Renkei-kenkyūsha): NAKAMURA Takayoshi 北海道大学, 電子科学研究所, 教授 (60270790)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000); Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2014: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
• Keywords: 分子性物質 / マルチフェロイクス材料 / 強磁性 / 強誘電性 / 金属錯体 / 超分子構造 / 機能性材料 / 複合機能材料 / マルチフェロイックス / 分子性結晶 / 強磁性体 / 強誘電体 / 国際情報交換

Outline of Final Research Achievements

Following results on development of molecular multiferroic materials constructed by supramolecular structures based on organic ammonium cation/crown ether derivatives and porous metal complexes exhibiting ferromagnetic behavior were obtained.
(1) Development of synthetic route for crown ether derivative with various substituents(2) Combined crystals based on the supramolecular structures and the porous metal complexes bridged by dihydroxybenzoquinone derivatives were obtained.(3) Polar ferromagnetic crystal exhibiting large dielectric responses was synthesized by using the supramolecular cation and porous oxalate metal complex.(4) New expansion of development of molecular multiferroic materials based on organic compounds including crown ether and thiadiazole moieties.

Research Products

• [Int'l Joint Research] 東南大学(中国)
• [Journal Article] One-dimensional Supramolecular Columnar Structure of trans-syn-trans-dicyclohexano[18]crown-6 and Organic Ammonium Cations (2016)
  • Author(s): Y. Ohshima, K. Kubo, T. Matsumoto, H. Y. Ye, S. Noro, T. Akutagawa and T. Nakamura
  • Journal Title: CrystEngComn Volume: 18 Issue: 41 Pages: 7959-7964
  • DOI: 10.1039/c6ce00980h
  • NAID: 120005859711
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Self-assembled Structure of Inorganic/Organic Hybrid Crystals Based on Keggin Polyoxometallates [SMo12O402-] and Supramolecular Cations (2016)
  • Author(s): Jun Xiong, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Crystal Growth & Design Volume: 16 Issue: 2 Pages: 800-807
  • DOI: 10.1021/acs.cgd.5b01388
  • Peer Reviewed
• [Journal Article] Structural Design of Coordination Polymers Based on Manganese and Chromium Ions Bridged by Oxalate Ligands (2016)
  • Author(s): Masashi Yoshitake, Kazuya Kubo, Toru Endo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 89 Issue: 3 Pages: 354-360
  • DOI: 10.1246/bcsj.20150373
  • NAID: 130005137575
  • ISSN: 0009-2673, 1348-0634
  • Peer Reviewed / Open Access
• [Journal Article] CH4/CO2 and CH4/C2H6 gas separation using a flexible one-dimensional copper(II) porous coordination polymer (2015)
  • Author(s): Shin-ichiro. Noro, Rika Ochi, Yasutaka. Inubushi, Kazuya. Kubo, Takayoshi. Nakamura
  • Journal Title: Microporous and Mesoporous Materials Volume: 216 Pages: 92-96
  • DOI: 10.1016/j.micromeso.2015.03.021
  • Peer Reviewed
• [Journal Article] Three-dimensional Architectures of [MnIICrIII(oxalate)3]; Complexes with Cage Type Networks Surrounding Supramolecular Cations (2015)
  • Author(s): Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin-ichiro Noro, Norihisa hoshino, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Journal Title: rystal Growth & Design Volume: 15 Issue: 3 Pages: 1186-1193
  • DOI: 10.1021/cg501560z
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Supramolecular cations of (m-halogenated-anilinium)(dibenzo[18]crown-6) in Keggin [SMo12O402−] polyoxometallates (2015)
  • Author(s): J. Xiong, K. Kubo, S. Noro, T. Akutagawa, and N. Nakamura
  • Journal Title: CrystEngComm. Volume: 17 Issue: 4 Pages: 856-861
  • DOI: 10.1039/c4ce01988a
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand (2015)
  • Author(s): Shin-ichiro Noro, Junya Mizutani, Yuh Hijikata, Ryotaro Matsuda, Hiroshi Sato, Susumu Kitagawa, Kunihisa Sugimoto, Yasutaka Inubushi, Kazuya Kubo, and Takayoshi Nakamura
  • Journal Title: Nature Communications Volume: 6 Issue: 1 Pages: 5851-5851
  • DOI: 10.1038/ncomms6851
  • NAID: 120005745622
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] CH4/CO2 and CH4/C2H6 gas separation using a flexible one-dimensional copper(II) porous coordination polymer (2015)
  • Author(s): Shin-ichiro Noro, Rika Ochi, Yasutaka Inubushi, Kazuya Kubo, Takayoshi Nakamura
  • Journal Title: Microporous & Mesoporous Materials Volume: 未定
• [Presentation] 分子性化合物合成に基づく有機電子材料開発 (2017)
  • Author(s): 久保和也
  • Organizer: 高分子・ハイブリッド材料研究センター（PHyM）若手フォーラム
  • Place of Presentation: 東北大学（宮城県仙台市）
  • Year and Date: 2017-02-27
  • Invited
• [Presentation] Development of Multifunctional Materials based on [MnCr(oxalate)3]- Complexes with Supramolecular Cations (2016)
  • Author(s): K. Kubo, M. Yoshitake, T. Endo, S. Noro, T. Akutagawa, T. Nakamura
  • Organizer: 有機固体の伝導性・光伝導性と関連現象に関する第12回日中合同シンポジウム
  • Place of Presentation: 早稲田大学（東京都新宿区）
  • Year and Date: 2016-10-17
  • Int'l Joint Research
• [Presentation] Relaxer Type Dielectric Response Caused by The Molecular Motion of Supramolecular Cation in the Solid State (2016)
  • Author(s): K. Kubo, Y.-N. Yan, S. Noro, T. Akutagawa, T. Nakamura
  • Organizer: Core-to-Core / Leverhulme Trust 5th Joint Workshop on Organic Electronics of Highly-Correlated Molecular Systems
  • Place of Presentation: Novosibirsk (Russia)
  • Year and Date: 2016-09-28
  • Int'l Joint Research
• [Presentation] Structural Design of Coordination Polymers Based on Manganese and Chromium ions bridged by Oxalate Ligands Including Bulky Organic Cations (2016)
  • Author(s): K. Kubo, M. Yoshitake, T. Endo, S. Noro, T. Akutagawa, T. Nakamura
  • Organizer: The 15th International Conference on Molecule-Based Magnets
  • Place of Presentation: 仙台国際センター (宮城県仙台市)
  • Year and Date: 2016-09-05
  • Int'l Joint Research
• [Presentation] Synthesis and structures of light metal co-ordination polymers using 4-(methylsulfonyl) benzoate (2016)
  • Author(s): Rika Ochi, Shin-ichiro Noro, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス（京都府京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] アダマンチル骨格を有する超分子ローターカチオン結晶の動的構造と誘電性 (2016)
  • Author(s): 大島 雄、久保 和也、野呂 真一郎、芥川 智行、中村 貴義
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス（京都府京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] Crystal structure and physical properties of a flexible one-dimensional porous copper complex with bulky fluorinated anions (2016)
  • Author(s): Xin. Zheng, Shin-ichiro Noro, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス（京都府京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] 欠損型ポリオキソメタレートでサンドイッチされた三核ランタノイド錯体の結晶構造および磁気的挙動 (2016)
  • Author(s): 西出 大輔、久保 和也、野呂 真一郎、中村 貴義
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス（京都府京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] 細孔内部にフッ素系アニオンをとりこんだ多孔性銅錯体の構造と吸着特性 (2016)
  • Author(s): 高橋 由紀子、野呂 真一郎、久保 和也、中村 貴義
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学京田辺キャンパス（京都府京田辺市）
  • Year and Date: 2016-03-24
• [Presentation] 欠損型ポリオキソメタレートでサンドイッチされた三核ランタニド錯体の合成 (2016)
  • Author(s): 西出 大輔、久保 和也、野呂 真一郎、中村 貴義
  • Organizer: 化学系学協会北海道支部2016年冬季研究発表会
  • Place of Presentation: 北海道大学（北海道札幌市）
  • Year and Date: 2016-01-19
• [Presentation] Water/alcohol vapor separation using flexible two-dimensional Mg(II) coordination polymer with isonicotinic acid N-oxide ligand (2015)
  • Author(s): Rika Ochi, Shin-ichiro Noro, Yuichi Kamiya, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: he 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Crystal structure and physical properties of (p-phenylenediamine)2(H+)3(DCH[18]crown-6)3 double-decker type supramolecular cation in [Ni(dmit)2] salt (2015)
  • Author(s): Yu Ohshima, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: he 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Structure and physical properties of chiral [MnCr(oxalate)3]- crystals with supramolecular cations (2015)
  • Author(s): Masashi Yoshitake, Kazuka Kubo, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura
  • Organizer: he 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem2015)
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Design of POMs-based self-assembled chiral crystals by induced crown ether supramolecular cations (2015)
  • Author(s): Jun Xiong, Kazuya Kubo, Shin-ichiro Noro, Takayoshi Nakamura
  • Organizer: The International Chemical Congress of Pacific Basin Societies 2015 (Pacifichem2015)
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Molecular Motions Causing Exiotic Dielectric Phenomena in The Solid State (2015)
  • Author(s): Kazuya Kubo
  • Organizer: World Congress and Expo on Materials Science & Polymer Engineering
  • Place of Presentation: Dubai, UAE
  • Year and Date: 2015-11-27
  • Int'l Joint Research / Invited
• [Presentation] 分子回転を利用した強誘電性分子性材料の開拓 (2015)
  • Author(s): 中村 貴義、久保 和也、野呂 真一郎、芥川 智行
  • Organizer: 電気情報通信学会 有機エレクトロニクス研究会(OME)
  • Place of Presentation: 機械振興会館（東京都港区）
  • Year and Date: 2015-11-06
• [Presentation] Novel functional crystals of supramolecular cations and two-dimensional ferromagnetic metal-oxalate anion (2015)
  • Author(s): Kazuya Kubo, Takayoshi Nakamura
  • Organizer: Core-to-Core/Leverhulme Trust Joint Workshop, Moscow 2015 “Organic Electronics of High-ly-Correlated Molecular Systems”
  • Place of Presentation: Moscow, Russia
  • Year and Date: 2015-10-08
  • Int'l Joint Research
• [Presentation] Synthesis of Oligosaccharides from Unprotected Monosaccharides Using Porous Coordination Polymers (2015)
  • Author(s): Rika Ochi, Shin-ichiro Noro, Nobuo Uotani, Yukiko Takahashi, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: 錯体化学会第65回討論会
  • Place of Presentation: 奈良女子大学（奈良県奈良市）
  • Year and Date: 2015-09-21
• [Presentation] Systematic Control of Hydrocarbon Adsorp-tion/Separation Properties Using Solid Solution Type One-Dimensional Cu(II) Coordination Polymers (2015)
  • Author(s): Shin-ichiro Noro, Yukiko Takahashi, Susumu Kitagawa, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: 錯体化学会第65回討論会
  • Place of Presentation: 奈良女子大学（奈良県奈良市）
  • Year and Date: 2015-09-21
• [Presentation] アキシャル位にCH3BF3-持つ[Cu(A)2(py)4]型錯体の合成と構造 (2015)
  • Author(s): 兼頭 寛光、野呂 真一郎、久保 和也、中村 貴義、綱島 亮
  • Organizer: 第9回分子科学討論会2015
  • Place of Presentation: 東京工業大学大岡山キャンパス（東京都目黒区）
  • Year and Date: 2015-09-16
• [Presentation] ダブルデッカー型超分子カチオン(p-phenylenediamine)2(H+)3(dicyclohexano[18]crown-6)3結晶の動的構造 (2015)
  • Author(s): 大島 雄、久保 和也、野呂 真一郎、芥川 智行、中村 貴義
  • Organizer: 第9回分子科学討論会2015
  • Place of Presentation: 東京工業大学大岡山キャンパス（東京都目黒区）
  • Year and Date: 2015-09-16
• [Presentation] 金属錯体単結晶を用いたフッ素系アニオン－ゲスト分子間相互作用の可視化 (2015)
  • Author(s): 高橋 由紀子、野呂 真一郎、杉本 邦久、久保 和也、中村 貴義
  • Organizer: 第66回コロイドおよび界面化学討論会
  • Place of Presentation: 鹿児島大学郡元キャンパス（鹿児島県鹿児島市）
  • Year and Date: 2015-09-10
• [Presentation] Structure and Dielectric Properties of (naphtha-le-ne-1-aminium+)(dibenzo[18]crown-6)[Ni(dmit)2] showing pendulum motions (2015)
  • Author(s): Kazuya Kubo, Yin-Nan Yan, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: 1th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2015)
  • Place of Presentation: Bad Gogging, Germany
  • Year and Date: 2015-09-06
• [Presentation] Self-assembled structure of inorganic-organic hybrid crystals based on Keggin polyoxomet-allates [SMo12O402-] and supramolecular cations (2015)
  • Author(s): 熊 俊、久保 和也、野呂 真一郎、中村 貴義
  • Organizer: 日本化学会北海道支部2015年夏季研究発表会
  • Place of Presentation: 北海道教育大学函館校（北海道函館市）
  • Year and Date: 2015-07-18
• [Presentation] (3-Fluoroadamantylammonium)([18]crown-6誘導体)[Ni(dmit)2]超分子結晶における分子運動 (2015)
  • Author(s): 大島 雄、久保 和也、野呂 真一郎、芥川 智行、中村 貴義
  • Organizer: 日本化学会北海道支部2015年夏季研究発表会
  • Place of Presentation: 北海道教育大学函館校（北海道函館市）
  • Year and Date: 2015-07-18
• [Presentation] Development of Functional Light Metal Porous Coordination Polymers Using Pyridine-N-Oxide Type Ligands (2015)
  • Author(s): Shin-ichiro Noro, Rika Ochi, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: 5th Asian Conference on Coordination Chemistry (ACCC5)
  • Place of Presentation: Hong Kong, China
  • Year and Date: 2015-07-12
  • Int'l Joint Research
• [Presentation] Flexible two-dimensional Mg(II) porous coor-dination polymer with isonicotinate N-oxide ligand capable of H2O/alcohol vapor separa-tion (2015)
  • Author(s): Rika Ochi, Shin-ichiro Noro, Yuichi Kamiya, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: International Symposium on Zeolite and Mi-croporous Crystal 2015 (ZMPC2015)
  • Place of Presentation: 札幌コンベンションセンター （北海道札幌市）
  • Year and Date: 2015-06-28
  • Int'l Joint Research
• [Presentation] 多孔性金属錯体の細孔を反応場とする新規糖鎖合成法の開発 (2015)
  • Author(s): 越智 里香、野呂 真一郎、魚谷 信夫、高橋 由紀子、久保 和也、中村 貴義
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学（千葉県船橋市）
  • Year and Date: 2015-03-28
• [Presentation] 有機アンモニウム / クラウンエーテル誘導体超分子カチオンが誘起する[MnCr(oxalate)3]-キラル結晶の磁気挙動 (2015)
  • Author(s): 吉竹 理、久保 和也、西原 禎文、井上 克也、芥川 智行、野呂 真一郎、中村 貴義
  • Organizer: 日本化学会北海道支部2015年冬季研究発表会
  • Place of Presentation: 北海道大学（北海道札幌市）
  • Year and Date: 2015-01-28
• [Presentation] Structure and dielectric properties of supramolecular rotators composed of trans-syn-trans-dicyclohexano[18]crown-6 and alkyl and aryl ammonium derivatives (2014)
  • Author(s): Yu Ohshima, Kazuya Kubo, Shin-Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: The 15th Ries-Hokudai International Symposium 2014年電子研国際シンポジウム"響"
  • Place of Presentation: ガトーキングダム札幌（北海道札幌市）
  • Year and Date: 2014-12-16
• [Presentation] Designing ferroelectric materials by modulating polyoxometallates and supramolecular cations (2014)
  • Author(s): Jun Xiong, Daigoro Endo, Kazuya Kubo, Shin-Ichiro Noro, Takayoshi Nakamura
  • Organizer: The 15th Ries-Hokudai International Symposium 2014年電子研国際シンポジウム"響"
  • Place of Presentation: ガトーキングダム札幌（北海道札幌市）
  • Year and Date: 2014-12-16
• [Presentation] Crystal structure and physical properties of [MnCr(oxalate)3]- salts with supramolecular cations (2014)
  • Author(s): Masashi Yoshitake, Kazuya Kubo, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, Shin-Ichiro Noro,Takayoshi Nakamura
  • Organizer: The 15th Ries-Hokudai International Symposium 2014年電子研国際シンポジウム"響"
  • Place of Presentation: ガトーキングダム札幌（北海道札幌市）
  • Year and Date: 2014-12-16
• [Presentation] Synthesis, structure, and host-guest properties of light metal coordination polymer using pyridine-N-oxide-based ligand (2014)
  • Author(s): Rika Ochi, Shin-Ichiro Noro, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: The 15th Ries-Hokudai International Symposium 2014年電子研国際シンポジウム"響"
  • Place of Presentation: ガトーキングダム札幌（北海道札幌市）
  • Year and Date: 2014-12-16
• [Presentation] 結晶内分子ローター/プロトン移動共存系超分子結晶開発 (2014)
  • Author(s): 久保和也、劉尊奇、山田晃弘、野呂真一郎、芥川智行、中村貴義
  • Organizer: 附置研究所間アライアンス第二回若手研究会
  • Place of Presentation: 大阪大学（大阪府吹田市）
  • Year and Date: 2014-11-26
• [Presentation] Structure and Dielectric Properties of the Crystals Composed of Supramolecular Cations Having Multi Hydrogen Bonding Sites (2014)
  • Author(s): Akihiro Yamada, Kazuya Kubo, Norihisa Hoshino, Tomoyuki Akutagawa, Shin-Ichiro Noro, Takayoshi Nakamura
  • Organizer: Core-to-Core/Leverhulme Trust Joint Workshop, Otaru 2014 “Organic Electronics of Highly-Correlated Molecular Systems”
  • Place of Presentation: グランドパーク小樽（北海道小樽市）
  • Year and Date: 2014-10-24
• [Presentation] Substituent Effect on Molecular Motions in Supramolecular Crystals of (Anilinium Derivatives)(Dibenzo[18]crown-6)[Ni(dmit)2] (2014)
  • Author(s): Shota Nakagawa, Kazuya Kubo, Shin-Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: Core-to-Core/Leverhulme Trust Joint Workshop, Otaru 2014 “Organic Electronics of Highly-Correlated Molecular Systems”
  • Place of Presentation: グランドパーク小樽（北海道小樽市）
  • Year and Date: 2014-10-24
• [Presentation] Designing ferroelectric materials by modulating polyoxometallates and supramolecular cations (2014)
  • Author(s): Jun Xiong, Daigoro Endo, Kazuya Kubo, Shin-Ichiro Noro, Takayoshi Nakamura
  • Organizer: Core-to-Core/Leverhulme Trust Joint Workshop, Otaru 2014 “Organic Electronics of Highly-Correlated Molecular Systems”
  • Place of Presentation: グランドパーク小樽（北海道小樽市）
  • Year and Date: 2014-10-24
• [Presentation] Crystal structure and physical properties of [MnCr(oxalate)3]- complexes with supramolecular cations (2014)
  • Author(s): Masashi Yoshitake, Kazuya Kubo, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, Shin-Ichiro Noro,Takayoshi Nakamura
  • Organizer: Core-to-Core/Leverhulme Trust Joint Workshop, Otaru 2014 “Organic Electronics of Highly-Correlated Molecular Systems”
  • Place of Presentation: グランドパーク小樽（北海道小樽市）
  • Year and Date: 2014-10-24
• [Presentation] Structure and Physical Properties of (Fluoroadamantylammonium)(Dicyclohexano[18]crown-6) Supramolecular Cation in [Ni(dmit)2] Crystal (2014)
  • Author(s): Yu Ohshima, Kazuya Kubo, Shin-Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: Core-to-Core/Leverhulme Trust Joint Workshop, Otaru 2014 “Organic Electronics of Highly-Correlated Molecular Systems”
  • Place of Presentation: グランドパーク小樽（北海道小樽市）
  • Year and Date: 2014-10-24
• [Presentation] Designing ferroelectric materials by modulating polyoxometallates and supramolecular cations (2014)
  • Author(s): Jun Xiong, Daigoro Endo, Kazuya Kubo, Shin-Ichiro Noro, Takayoshi Nakamura
  • Organizer: 10th IUPAC International Conference on Novel Materials
  • Place of Presentation: Zhengzhou (China)
  • Year and Date: 2014-10-10
• [Presentation] Structures and Physical Properties of Ferromagnetic Crystals with Supramolecular Cations (2014)
  • Author(s): Kazuya Kubo, Toru Endo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagwa, Takayoshi Nakamura
  • Organizer: 3rd International Conference and Exhibition on Materials Science & Engineering
  • Place of Presentation: San Antonio （米国）
  • Year and Date: 2014-10-06
  • Invited
• [Presentation] Porous Light Metal Coordination Polymers with Charge-Polarized Neutral Ligand (2014)
  • Author(s): Shin-ichiro Noro, Junya Mizutani, Yuh Hijikata, Kazuya Kubo, Takayoshi Nakamura
  • Organizer: MOF2014
  • Place of Presentation: 神戸コンベンションセンター（兵庫県神戸市）
  • Year and Date: 2014-09-30
• [Presentation] アニリニウム誘導体/ジベンゾ[18]クラウン-6超分子ローター構造を有する混晶の合成と物性評価 (2014)
  • Author(s): 中川 翔太,久保 和也,野呂 真一郎,芥川 智行,中村 貴義
  • Organizer: 第8回分子科学討論会
  • Place of Presentation: 広島大学（広島県東広島市）
  • Year and Date: 2014-09-24
• [Presentation] 2,6-ジアミノピリジンおよび2-アミノピリミジンとクラウンエーテル誘導体からなる超分子カチオン結晶の誘電応答 (2014)
  • Author(s): 久保 和也、劉 尊奇,山田 晃弘,野呂 真一郎,芥川 智行,中村 貴義
  • Organizer: 第8回分子科学討論会
  • Place of Presentation: 広島大学（広島県東広島市）
  • Year and Date: 2014-09-24
• [Presentation] アミノピリジニウム/キラルクラウンエーテル誘導体カチオンを導入した[Ni(dmit)2]-錯体結晶の合成と物性 (2014)
  • Author(s): 渡辺 大樹、久保 和也、星野 哲久、芥川 智行、野呂 真一郎、中村 貴義
  • Organizer: 第8回分子科学討論会
  • Place of Presentation: 広島大学（広島県東広島市）
  • Year and Date: 2014-09-21
• [Presentation] 電荷分極したピリジン‐N‐オキシド構造を有する配位子を用いた高分子状軽金属錯体の合成と構造 (2014)
  • Author(s): 越智 里香、野呂 真一郎、久保 和也、中村 貴義
  • Organizer: 錯体化学会第64回討論会
  • Place of Presentation: 中央大学（東京都文京区）
  • Year and Date: 2014-09-09
• [Presentation] 結晶性分子ローターの置換基交換による誘電応答の変化 (2014)
  • Author(s): 中川翔太、久保和也、野呂真一郎、芥川智行、中村貴義
  • Organizer: 日本化学会北海道支部 ２０１４年 夏季研究発表会
  • Place of Presentation: 苫小牧高専（北海道苫小牧市）
  • Year and Date: 2014-07-12
• [Presentation] 4-aminopyridinium/crown ether 超分子結晶における水素結合と誘電性 (2014)
  • Author(s): 大島 雄、久保和也、野呂真一郎、芥川智行、中村貴義
  • Organizer: 日本化学会北海道支部 ２０１４年 夏季研究発表会
  • Place of Presentation: 苫小牧高専（北海道苫小牧市）
  • Year and Date: 2014-07-12
• [Presentation] キラル超分子カチオンを導入した[MnCr(oxalate)3]-結晶の磁気挙動 (2014)
  • Author(s): 吉竹 理、久保和也、西原禎文、井上克也、芥川智行、野呂真一郎、中村 貴義
  • Organizer: 日本化学会北海道支部 ２０１４年 夏季研究発表会
  • Place of Presentation: 苫小牧高専（北海道苫小牧市）
  • Year and Date: 2014-07-12
• [Presentation] Mixed-valence [S2Mo18O62]n-(n = 4, 5, 6) and [Ln(Mo8O26)2]5-(Ln = Gd, Tb, Dy, Ho, Er), as magnetic counter anions for supramolecular rotators. (2014)
  • Author(s): Jun Xiong, Daigoro Endo, Kazuya Kubo, Shin-Ichiro Noro, Takayoshi Nakamura
  • Organizer: The 14th International Conference on Molecule-Based Magnets （ICMM2014）
  • Place of Presentation: Saint Petersburg (Russia)
  • Year and Date: 2014-07-08
• [Presentation] CRYSTAL STRUCTURE AND DIELECTRIC PROPERTIES OF (4-AMINOPYRIDINIUM+)(TRANS-ANTI-TRANS- DICYCLOHEXANO[18]CROWN-6)[Ni(DMIT)2]- (2014)
  • Author(s): Daiki Watanabe, Kazuya Kubo, Norihisa Hoshino, Tomoyuki Akutagawa, Shin-Ichiro Noro, Takayoshi Nakamura
  • Organizer: International Conference of Synthetic Metals (ICSM2014)
  • Place of Presentation: Turku (Finland)
  • Year and Date: 2014-07-02
• [Presentation] DIELECTRIC PROPERTIES OF [Ni(DMIT)2]- CRYSTALS WITH (AMINOPYRIDINIUM DERIVATIVES)(DICYCLOHEXANO[18]CROWN-6) SUPRAMOLECULAR CATIONS (2014)
  • Author(s): Akihiro Yamada, Kazuya Kubo, Norihisa Hoshino, Tomoyuki Akutagawa, Shin-Ichiro Noro, Takayoshi Nakamura
  • Organizer: International Conference of Synthetic Metals (ICSM2014)
  • Place of Presentation: Turku (Finland)
  • Year and Date: 2014-07-01
• [Presentation] SUBSTITUENT EFFECTS ON THE DIELECTRIC RESPONSE AND MOLECULAR MOTIONS IN THE SUPRAMOLECULAR CRYSTALS (2014)
  • Author(s): Shota Nakagawa, Kazuya Kubo, Shin-Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: International Conference of Synthetic Metals (ICSM2014)
  • Place of Presentation: Turku (Finland)
  • Year and Date: 2014-07-01
• [Presentation] Proton Transfer and Dielectric Properties of 4- Aminopyridinium/Crown Ether Supramolecular Crystals (2014)
  • Author(s): Yu Ohshima, Kazuya Kubo, Shin-Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
  • Organizer: International Conference of Synthetic Metals (ICSM2014)
  • Place of Presentation: Turku (Finland)
  • Year and Date: 2014-07-01
• [Presentation] MAGNETIC PROPERTIES OF A [MnCr(OXALATE)3]- SALT WITH CHIRAL SUPRAMOLECULAR CATION (2014)
  • Author(s): Masashi Yoshitake, Kazuya Kubo, Sadafumi Nishihara, Katsuya Inoue, Tomoyuki Akutagawa, Shin-Ichiro Noro,Takayoshi Nakamura
  • Organizer: International Conference of Synthetic Metals (ICSM2014)
  • Place of Presentation: Turku (Finland)
  • Year and Date: 2014-07-01
• [Book] 元素ブロック高分子 (2016)
  • Author(s): 久保和也、中村貴義
  • Total Pages: 8
  • Publisher: シーエムシー出版
• [Remarks] 北海道大学電子科学研究所 附属グリーンナノテクノロジー研究センター ナノアセンブリ材料研究分野
  • URL: http://fnm.es.hokudai.ac.jp/
• [Remarks] 北海道大学電子科学研究所
  • URL: http://www.es.hokudai.ac.jp/
• [Remarks] 北海道大学電子科学研究所附属グリーンナノテクノロジー研究センターナノアセンブリ研究分野
  • URL: http://www.hucc.hokudai.ac.jp/~i21625/index.html
• [Remarks] 電子科学研究所 付属グリーンナノテクノロジー研究センター ナノアセンブリ材料研究分野
  • URL: http://www.hucc.hokudai.ac.jp/~i21625/index.html