Development of New Transformation Reactions Using Unsaturated Molecules Activated by Silicon Substituents
| Project/Area Number |
26410119
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | ケイ素置換基 / 環化付加 / Lewis酸 / 超共役 / 選択的有機合成 / 1,4-シフト / 酸触媒 / 不飽和炭化水素 / 均一系触媒 / インジウム / 有機ケイ素化合物 / ルイス酸触媒 / 環化付加反応 / 立体選択的合成 |
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| Outline of Final Research Achievements |
In this research, we aimed at the establishment of the new transformation reactions based on understanding the specific features of silicon-containing unsaturated organic molecules by means of the mechanistic and experimental studies on the Lewis acid-catalyzed selective cycloaddition reactions using silicon-containing unsaturated organic molecules. As a result, we have developed some new selective synthetic methods using the effect of silicon substituents. The obtained insights on the effect of silicon substitution towards the synthetic utilities would cause further developments and applications of organic reactions using heteroatom-based unsaturated molecules.
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Report
(4 results)
Research Products
(8 results)
