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Precise Structure Analysis of Multi-Components Origanic Thin Films by Grazing Incidence X-ray Scattering utilizing Wide Energy X-rays

Research Project

Project/Area Number 26410132
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionNagoya Institute of Technology

Principal Investigator

Yamamoto Katsuhiro  名古屋工業大学, 工学(系)研究科(研究院), 准教授 (30314082)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords斜入射小角X線散乱 / 高分子薄膜 / 相分離構造 / テンダーX線 / 異常小角散乱 / ブロック共重合体 / 高分子構造 / 深さ分解 / 低エネルギーX線 / ミクロ相分離構図 / 深さ分解構造解析 / 表面 / 界面 / 微小角入射小角X線散乱 / 薄膜 / ミクロ相分離構造
Outline of Final Research Achievements

Grazing Incidence X-ray Scattering (GISAXS) method is powerful tool to analyze mesoscpic structures in organic (polymer) thin films. Ordinaly, hard X-rays (1-1.5A) are often used for GISAXS method. In recent, wide ragne of X-ray between 2 to 14 keV has been deveploed and normally available for GISAXS in the Japanese synchrotron facility. Utilizing X-rays near the adorption edge of taget elements revealed spacial distribution of the target elements in thin films. Tender X-rays enebles to analyze tepth-resolved structure in the thin films. We found that different between the nano-structures near the surface and in vicinity of the substrate.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (24 results)

All 2017 2016 2015 2014 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 5 results) Presentation (16 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Phase Separated Structure and Its Orientation Behavior of Polystyrene<i>-b-</i>Partially Quaternized Poly(2-Vinylpyridine) Thin Films Investigated by Grazing Incidence Small Angle X-ray Scattering2017

    • Author(s)
      Katsuhiro Yamamoto*, Takafumi Okamoto, Itsuki Saito
    • Journal Title

      Journal of the Society of Materials Science, Japan

      Volume: 66 Issue: 1 Pages: 18-22

    • DOI

      10.2472/jsms.66.18

    • NAID

      130005289677

    • ISSN
      0514-5163, 1880-7488
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Orientation and relaxation behaviors of lamellar micro-domains of poly(methyl methacrylate)-b-poly(n-butyl acrylate) thin film as revealed by grazing-incidence small angle X-ray scattering2016

    • Author(s)
      Itsuki Saito, Daiki Shimada, Mayu Aikawa, Tsukasa Miyazaki, Keisuke Shimokita, Hideaki Takagi and Katsuhiro Yamamoto
    • Journal Title

      Polymer Journal

      Volume: 48 Issue: 4 Pages: 399-406

    • DOI

      10.1038/pj.2016.2

    • NAID

      40020778234

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Evaluations of Mesogen Orientation near the Substrate Surface in Thin Films of Polyacrylate with Cyanobiphenyl Side Chain2016

    • Author(s)
      Daisuke Tanaka, Takumi Mizuno, Mitsuo Hara, Shusaku Nagano, Itsuki Saito, Katsuhiro Yamamoto, Takahiro Seki
    • Journal Title

      Langmuir

      Volume: 32 Issue: 15 Pages: 3737-3745

    • DOI

      10.1021/acs.langmuir.6b00538

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Depth-Resolved Strucutre Analysis of Cylindrical Microdomain in Block Copolymer Thin Film by Grazing-Incidnece Small-Angle X-ray Scattering Utilizing Low-Energy X-rays2015

    • Author(s)
      Itsuki Saito, Tsukasa Miyazaki, and Katsuhiro Yamamoto
    • Journal Title

      Macromolecules

      Volume: 42 Issue: 22 Pages: 8190-8196

    • DOI

      10.1021/acs.macromol.5b01883

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Macroscopic Alignment of Cylinders via Directional Coalescence of Spheres along Annealing Solvent Permeation Directions in Block Copolymer Thick Films2014

    • Author(s)
      Guanghui Cui, Masamichi Fujikawa, Shusaku Nagano, keisuke Shimokita, Tsukasa Miyazaki, Shinichi Sakurai, and Katsuhiro Yamamoto
    • Journal Title

      Macromolecules

      Volume: 47 Pages: 5989-5999

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 鉄イオンをドープしたポリスチレン-b-ポリ2-ビニルピリジン薄膜中のシリンダー構造の自発的垂直配向化2014

    • Author(s)
      Itsuki Saito, Takashi Okamoto, Keisuke Shimokita, Tsukasa Miyazaki and Katsuhiro Yamamoto
    • Journal Title

      高分子論文集

      Volume: 71 Pages: 586-592

    • NAID

      130004705557

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 斜入射小角 X 線散乱を用いたブロック共重合体薄膜の相分離構造の配向挙動の深さ分解解析2016

    • Author(s)
      相川真夕, 山本勝宏
    • Organizer
      第65回 高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリメタクリル酸メチル-b-ポリアクリル酸n-ブチル共重合体薄膜の相分離構造の配向挙動の深さ分解解析2016

    • Author(s)
      相川真夕・島田大輝・山本勝宏
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 斜入射小角X線散乱法によるポリスチレン-b-部分四級化ポリ(2-ビニルピリジン)薄膜の相分離構造とその配向挙動の研究2016

    • Author(s)
      岡本貴史・山本勝宏
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 新設BL15A2における微小角入射X線散乱法による高分子薄膜の深さ分解構造解析2016

    • Author(s)
      山本勝宏
    • Organizer
      PF研究会
    • Place of Presentation
      高エネルギー加速器研究機構
    • Year and Date
      2016-03-30
    • Related Report
      2015 Research-status Report
  • [Presentation] Lattice Deformation of Micro-Phase Separated Structure in Thin Film revealed by Low Energy GISAXS2015

    • Author(s)
      Itsuki Saito, Katsuhiro Yamamoto
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ハワイコンベンションセンター
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 低エネルギーX線を用いた斜入射小角X線散乱法による自ブロック共重合体薄膜中の相分離構造の配向挙動の調査2015

    • Author(s)
      斎藤樹、山本勝宏
    • Organizer
      高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] Depth Dependence of Lattice Deformation of Cylindrical Microdomain of Polystyrene-b-poly(2-vinylpyridine) Thin Film Investigated by Low Energy GISAXS2015

    • Author(s)
      Itsuki Saito, Katsuhiro Yamamoto
    • Organizer
      Synchrotron Radiation in Polymer Science 6
    • Place of Presentation
      Madrid
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anomalous Small-angle X-ray Scattering Study on Distribution of Homopolymer in Block Copolymer / Homopolymer Blend2015

    • Author(s)
      Katsuhiro Yamamoto, Kazuma Kanayama, Isamu Akiba
    • Organizer
      Synchrotron Radiation in Polymer Science 6
    • Place of Presentation
      Madrid
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 斎藤樹、山本勝宏2015

    • Author(s)
      低エネルギーX線を用いた斜入射小角X線散乱法による自ブロック共重合体薄膜中の相分離構造の配向挙動の調査
    • Organizer
      第153回東海高分子研究会
    • Place of Presentation
      サンパーク犬山
    • Year and Date
      2015-09-04
    • Related Report
      2015 Research-status Report
  • [Presentation] 斎藤樹、山本勝宏2015

    • Author(s)
      低エネルギーX線を用いた斜入射小角X線散乱によるブロック共重合体薄膜の深さ分解構造解析
    • Organizer
      第64回 高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 斎藤樹、山本勝宏2015

    • Author(s)
      低エネルギーX線を用いた微小角入射小角X線散乱法による薄膜中の相分離構造の深さ分解解析
    • Organizer
      2015年日本ゴム協会年次大会,
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2015-05-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 低エネルギーX線を用いた斜入射小角X線散乱法による高分子薄膜の深さ分解構造解析2015

    • Author(s)
      斎藤樹・山本勝宏
    • Organizer
      物構研サイエンスフェスタ2014
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2015-03-17 – 2015-03-18
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリメタクリル酸メチル-b-ポリアクリル酸アルキル薄膜における配向挙動2014

    • Author(s)
      島田大輝・山本勝宏
    • Organizer
      第26回エラストマー討論会
    • Place of Presentation
      愛知工業大学
    • Year and Date
      2014-12-04 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] ジブロック共重合体薄膜中における垂直配向化シリンダー構造の膜厚方向の深さ依存性2014

    • Author(s)
      松田明倫・大矢智士・櫻井伸一・宮崎 司・山本勝宏
    • Organizer
      第26回エラストマー討論会
    • Place of Presentation
      愛知工業大学
    • Year and Date
      2014-12-04 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 鉄イオンをドープしたポリスチレン-b-ポリ2-ビニルピリジン薄膜の自発的配向化メカニズムの考察2014

    • Author(s)
      斎藤樹, 岡本貴史, 山本 勝宏, 宮崎司, 下北啓輔
    • Organizer
      第26回エラストマー討論会
    • Place of Presentation
      愛知工業大学
    • Year and Date
      2014-12-04 – 2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 高分子(薄)膜におけるミクロ相分離構造のマクロスコピック垂直配向化2014

    • Author(s)
      山本勝宏
    • Organizer
      九州地区高分子若手研究会
    • Place of Presentation
      北九州八幡ロイヤルホテル
    • Year and Date
      2014-06-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Book] X-ray Scattering, Chapter 3 "Grazing-Incidence Small Angle X-Ray Scattering in Polymer Thin Films Utilizing Low-Energy X-Rays"2017

    • Author(s)
      Katsuhiro Yamamoto
    • Total Pages
      226
    • Publisher
      InTech
    • Related Report
      2016 Annual Research Report
  • [Remarks] 研究室HP

    • URL

      http://yamamotolab.web.nitech.ac.jp/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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