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The microstructure fabrication of ordered three-dimensional silicon films made by the electrochemical reduction of bromosilane by using the inverse- or opal template

Research Project

Project/Area Number 26550077
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Environmental conscious materials and recycle
Research InstitutionUbe National College of Technology

Principal Investigator

Tomono Kazuaki  宇部工業高等専門学校, 物質工学科, 准教授 (40516449)

Co-Investigator(Kenkyū-buntansha) Kato Yuki  宇部工業高等専門学校, 一般科, 講師 (50707130)
SHIRANE Taketo  宇部工業高等専門学校, 一般科, 講師 (70615161)
Project Period (FY) 2014-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords再資源化 / ブロモシラン / 廃シリコン / 電気化学的手法 / 幾何学シリコン膜 / 逆オパール構造 / オパール構造 / 構造色 / 逆オパールシリコン
Outline of Final Research Achievements

The inverse-opal silicon films have been prepared by using ordered polystyrene (PS) templates in an electrochemical reduction of tetrabromosilane under various conditions. Self-assembled PS colloidal crystals with different diameters were used as templates. The electrochemical process was investigated by cyclic voltammetry. Scanning electron microscopy and absolute reflectance measurement confirm the morphology and optical property of the deposited silicon films. Moreover, the invere-opal nickel template as the working electrode was subjected to the electrodeposition of opal silicon films under the optimized conditions.

Report

(3 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • Research Products

    (11 results)

All 2016 2015 2014 Other

All Presentation (10 results) (of which Int'l Joint Research: 1 results) Remarks (1 results)

  • [Presentation] Si切屑のブロモ化反応でのFe触媒の検討とブロモシランからのSi薄膜作製2016

    • Author(s)
      友野和哲,坂本遼,岡田雅広,柿原俊太,田巻義規
    • Organizer
      日本化学会第96回春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 廃棄物Si由来のブロモシランを用いたオパールSi薄膜の作製2016

    • Author(s)
      友野和哲,岡田雅広,坂本遼,八幡侑馬
    • Organizer
      第18回化学工学会学生発表会
    • Place of Presentation
      福岡大学
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electrochemical decomposition of bromosilanes made from kerf loss silicon and deposition of crystalline silicon2015

    • Author(s)
      Kazuaki Tomono, Ryo Sakamoto, Masahiro Okada, Shunta Kakihara, Yoshinori Tamaki, Yuma Yahata
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高純度Siを含む水性クーラント由来廃棄物Siの各種分析による組成解析2015

    • Author(s)
      友野和哲,岡田雅広,八幡侑馬,坂本遼
    • Organizer
      2015日本化学会中国四国支部大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-11-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水性クーラント由来の廃棄物シリコンを原料とするブロモシランの合成2015

    • Author(s)
      坂本遼,岡田雅広,八幡侑馬,友野和哲
    • Organizer
      2015日本化学会中国四国支部大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-11-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水性クーラントの使用に由来する廃シリコンの組成分析2015

    • Author(s)
      友野和哲,岡田雅広,坂本遼,八幡侑馬
    • Organizer
      日本高専学会第21回年会
    • Place of Presentation
      徳山工業高等専門学校
    • Year and Date
      2015-08-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水性クーラントを用いた廃シリコンの含有物分析2015

    • Author(s)
      友野和哲,岡田雅広,坂本遼,八幡侑馬,田畑美瑞咲,市村脩平
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2015-06-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 廃シリコンを出発物質とする3次元幾何学シリコン膜の電気化学作製2015

    • Author(s)
      友野和哲,松岡優佳,坂本遼,国光真弥,市村脩平,佐伯雅弘
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 廃Si由来のブロモシランからPS粒子を鋳型とした逆オパールSiの創製2014

    • Author(s)
      友野和哲,松岡優佳,坂本遼,国光真弥
    • Organizer
      2014年日本化学会中国四国支部大会
    • Place of Presentation
      山口大学吉田キャンパス
    • Year and Date
      2014-11-09
    • Related Report
      2014 Research-status Report
  • [Presentation] PS粒子を用いたブロモシランからの幾何学Si構造の析出2014

    • Author(s)
      友野和哲,松岡優佳,国光真弥,飯田龍也,坂口麻由美,市村脩平,中山雅晴,坂本遼
    • Organizer
      第51回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2014-06-28
    • Related Report
      2014 Research-status Report
  • [Remarks] 友野研究室

    • URL

      http://tomonolab.web.fc2.com/index.html

    • Related Report
      2015 Annual Research Report 2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2017-05-10  

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